Aquatic product formaldehyde rapid detection device and method based on visual olfactory fingerprint technology
A detection device and a technology for aquatic products, which are applied to measurement devices, material analysis and instruments by observing the impact on chemical indicators, and can solve problems such as complex operations, cumbersome steps, and difficulty in rapid on-site detection.
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[0028] The preparation method of the color-sensitive sensor 7 is as follows: select a color-sensitive material sensitive to formaldehyde in aquatic products, such as 5, 10, 15, 20-Tetraphenyl-21H, 23H-porphine zinc (ZnTPP, tetraphenylporphyrin zinc ), 5, 10,15, 20-Tetraphenyl-21H, 23H-porphine manganese (MnTPP, manganese tetraphenyl porphyrin), 5, 10, 15,20-Tetraphenyl-21H, 23H-porphine copper (CuTPP, tetraphenyl base porphyrin copper), 5, 10, 15, 20-Tetraphenyl-21H, 23H-porphine nickel (NiTPP, tetraphenyl porphine nickel) and 5, 10, 15, 20-Tetraphenyl-21H, 23H-porphine cobalt ( CoTPP, cobalt tetraphenylporphyrin); also include indicators such as neutral red, genol blue, bromocresol green, and methyl red. Dissolve ZnTPP, MnTPP, CuTPP, NiTPP and CoTPP in chloroform solvent respectively, and dissolve neutral red, genol blue, bromocresol green and methyl red in ethanol to obtain the concentration of each color-sensitive material is 1 mg / mL The color-sensitive material solution i...
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[0038] The rapid detection process of formaldehyde in squid based on visual olfactory fingerprint technology, the specific operation is as follows:
[0039] 1) A total of 60 pieces of fresh squid were randomly selected in a local supermarket;
[0040] 2) Each squid was sampled and randomly divided into 6 groups, one of which was set as the blank group, and the squid samples could be separated without washing with water, which was marked as S-0; the remaining 5 groups of squid samples were soaked in different concentrations of formaldehyde solution (1%, 2%, 4%, 6%, 8%) for 12 hours, labeled as S-1, S-2, S-3, S-4 and S-5, 10 samples for each concentration ;
[0041] 3) Dissolve ZnTPP, MnTPP, CuTPP, NiTPP and CoTPP in chloroform solvent, dissolve neutral red, genol blue, bromocresol green and methyl red in ethanol, and mix to obtain a concentration of 1 mg for each color-sensitive material / mL solution, absorb the above solution through the spotting capillary and print it on th...
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