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Preparation method of fuel cell membrane electrode

A fuel cell membrane and electrode technology, applied in fuel cells, battery electrodes, circuits, etc., can solve the problems of small and complex interface resistance, and the consistency of CCM membrane electrodes cannot be effectively guaranteed, and achieve the effect of avoiding swelling and reducing dosage

Pending Publication Date: 2021-03-19
安徽枡水新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process is simple and does not require hot pressing, but for the soft proton membrane below 50 microns, the membrane transfer and packaging operation technology is difficult, which is not conducive to mass production, and the consistency of the prepared CCM membrane electrode cannot be effectively guaranteed
[0006] Patent CN CN200810204032.8 discloses a method for preparing proton exchange membrane fuel cell electrodes. First, the catalyst is sprayed on the transfer membrane, and then the anode and cathode catalyst layers are hot-pressed on the proton exchange membrane by two transfer-hot pressing methods. On the membrane, the three-in-one membrane electrode of the proton exchange membrane and the diffusion layer that has completed the catalyst transfer is finally added with a frame for sealing and insulation. This membrane electrode preparation method has the advantages of small interface resistance and large-scale production, but The method undergoes a complex process of multiple transfers

Method used

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  • Preparation method of fuel cell membrane electrode
  • Preparation method of fuel cell membrane electrode
  • Preparation method of fuel cell membrane electrode

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Membrane electrodes with an effective active area of ​​5*5cm are prepared by traditional one-time hot pressing:

[0019] Step 1. Weigh 25mg of 60% Pt / C catalyst, ultrasonically disperse it in 10mL of water, add 5mL of isopropanol and 3mL of DMF, stir thoroughly and then cool in an ice bath for ultrasonic dispersion;

[0020] Step 2. In the isopropanol of 12mL that the 5% Nafion solution that takes 0.2g is added, under ice-bath cooling ultrasonic dispersion condition, the mixed solution of Nafion and isopropanol is added dropwise to the solution prepared in the previous step, Cool in an ice bath and continue ultrasonic dispersion for 1 hour;

[0021] Step 3. Cut out the proton exchange membrane, two edge-sealing membranes, hot-melt adhesive film and gas diffusion layer respectively. Outer 9*9cm and inner square hole: 5.2*5.2cm, outer 9*9cm), gas diffusion layer (5*5cm), hot melt adhesive (inner square hole 5*5cm, outer 9*9cm);

[0022] Step 4. Put the proton exchange m...

Embodiment 2

[0026] A membrane electrode with an effective active area of ​​5*5cm is prepared by the method provided by the invention:

[0027] Step 1. First weigh 25 mg of 60% Pt / C catalyst, ultrasonically disperse it in 10 mL of water, then add 5 mL of isopropanol and 3 mL of DMF, stir thoroughly and then cool in an ice bath for ultrasonic dispersion to obtain a solution;

[0028] Step 2. In the isopropanol of 12mL that the 5% Nafion solution of taking 0.2g is added, under ice-bath cooling ultrasonic dispersion condition, to the solution gained in step 1, dropwise add the mixed solution of Nafion and isopropanol, in ice bath Cool and continue ultrasonic dispersion for 1 hour;

[0029] Step 3. Cut out the proton exchange membrane, two edge-sealing membranes, hot-melt adhesive film and gas diffusion layer respectively. Outer 9*9cm and inner square hole: 5.2*5.2cm, outer 9*9cm), gas diffusion layer (5*5cm), hot melt adhesive (inner square hole 5*5cm, outer 9*9cm);

[0030] Step 4. The fro...

Embodiment 3

[0036] A membrane electrode with an effective active area of ​​15*15cm is prepared by the method provided by the invention:

[0037] Step 1. First weigh 500mg of 40% Pt / C catalyst, ultrasonically disperse it in 100mL of water, then add 50mL of isopropanol and 30mL of DMF, stir thoroughly and then cool in an ice bath for ultrasonic dispersion to obtain a solution;

[0038] Step 2. In the isopropanol of 20mL that the 5% Nafion solution that takes 6g is added, under ice-bath cooling ultrasonic dispersion condition, to step 1 gained solution drop by drop the mixed solution of Nafion and isopropanol, in ice bath Cool and continue ultrasonic dispersion for 1 hour;

[0039] Step 3. Cut out the proton exchange membrane, two edge-sealing membranes, the hot-melt adhesive film and the gas diffusion layer respectively. Outer side 20*16cm and inner square hole: 15.5*15.5cm, outer side 20*16cm), gas diffusion layer (15*15cm), hot melt adhesive (inner square hole 15*15cm, outer side 20*16cm);...

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Abstract

A preparation method of a fuel cell membrane electrode comprises the following steps: preparing catalyst slurry: weighing a Pt-based catalyst, dispersing the Pt-based catalyst in a mixed solution of water and an organic solvent, dropwise adding a mixed solution of Nafion and isopropanol while performing ice-bath cooling ultrasonic dispersion, and performing ice-bath cooling ultrasonic dispersion for 0.5-5 hour, cutting the membrane body: cutting the proton exchange membrane and the gas diffusion membrane into required sizes according to the catalytic active area of the membrane electrode to beprepared, reserving 1-10mm for each side, cutting the edge sealing membrane according to the sizes of the cut proton exchange membrane and gas diffusion membrane, fixing the support membrane: adhering the support membrane to the front surface of the cut proton exchange membrane through glue, not performing any treatment on the back surface of the proton exchange membrane, reducing the consumptionof the proton exchange membrane, and after the first hot pressing, enabling the frame membrane and the gas diffusion layer to play a role in supporting and protecting. The problems of swelling, deformation and distortion in the processes of operation, spraying, hot pressing and the like can be effectively avoided.

Description

technical field [0001] The invention relates to the field of fuel cell membrane electrode processing, in particular to a fuel cell membrane electrode preparation method. Background technique [0002] As traditional energy gradually withdraws from the stage of history, hydrogen energy and fuel cells will become emerging energy revolutions have come. As an important part of the hydrogen energy revolution, hydrogen fuel cell technology has become a clean energy technology that countries around the world focus on developing. A fuel cell consists of a bipolar plate and a membrane electrode, where the membrane electrode is the core component of the fuel cell, accounting for about 60% of the cost of the entire fuel cell. The development of high-quality, low-cost membrane electrode preparation process is an important part of the development of hydrogen fuel cells. [0003] At present, there are two main processes for the preparation of membrane electrodes: one is to coat the catal...

Claims

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Application Information

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IPC IPC(8): H01M8/1004H01M4/88
CPCH01M8/1004H01M4/886H01M4/8896Y02E60/50
Inventor 王新磊林晨张东余子涵王凤霞
Owner 安徽枡水新能源科技有限公司
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