Waterproof, breathable and bacteriostatic compound non-woven fabric and preparation method and application thereof
A waterproof, breathable, non-woven technology, applied in textiles and papermaking, non-woven fabrics, rayon manufacturing, etc. Effect
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Embodiment 1
[0042] A preparation method of a waterproof and breathable composite non-woven fabric. First, polyacrylonitrile, polyvinylidene fluoride, fillers, and water-soluble porogen are mixed and melted, and then sprayed out through a spinneret, air-drawn, formed into a web, and hot-pressed. Bonding, water immersion to remove the porogen, namely the composite non-woven fabric; wherein, the filler is prepared by the following method:
[0043] (1) earlier take zinc acetate, sodium tripolyphosphate, sodium hydroxide and porous tourmaline as raw material to make zinc oxide-tourmaline complex through solid phase reaction;
[0044] (2) Carry out epoxy modification to zinc oxide-tourmaline complex body then, then react with amino-terminated fluoropolymer, obtain modified complex body;
[0045] (3) Finally, immerse the modified complex in 1-allyl-3-methylimidazolium tetrafluoroborate for surface modification to obtain the filler.
[0046] The mass ratio of polyacrylonitrile, polyvinylidene fl...
Embodiment 2
[0063] A preparation method of a waterproof and breathable composite non-woven fabric. First, polyacrylonitrile, polyvinylidene fluoride, fillers, and water-soluble porogen are mixed and melted, and then sprayed out through a spinneret, air-drawn, formed into a web, and hot-pressed. Bonding, water immersion to remove the porogen, namely the composite non-woven fabric; wherein, the filler is prepared by the following method:
[0064] (1) earlier take zinc acetate, sodium tripolyphosphate, sodium hydroxide and porous tourmaline as raw material to make zinc oxide-tourmaline complex through solid phase reaction;
[0065] (2) Carry out epoxy modification to zinc oxide-tourmaline complex body then, then react with amino-terminated fluoropolymer, obtain modified complex body;
[0066] (3) Finally, immerse the modified complex in 1-allyl-3-methylimidazolium tetrafluoroborate for surface modification to obtain the filler.
[0067] The mass ratio of polyacrylonitrile, polyvinylidene fl...
Embodiment 3
[0084] A preparation method of a waterproof and breathable composite non-woven fabric. First, polyacrylonitrile, polyvinylidene fluoride, fillers, and water-soluble porogen are mixed and melted, and then sprayed out through a spinneret, air-drawn, formed into a web, and hot-pressed. Bonding, water immersion to remove the porogen, namely the composite non-woven fabric; wherein, the filler is prepared by the following method:
[0085] (1) earlier take zinc acetate, sodium tripolyphosphate, sodium hydroxide and porous tourmaline as raw material to make zinc oxide-tourmaline complex through solid phase reaction;
[0086] (2) Carry out epoxy modification to zinc oxide-tourmaline complex body then, then react with amino-terminated fluoropolymer, obtain modified complex body;
[0087] (3) Finally, immerse the modified complex in 1-allyl-3-methylimidazolium tetrafluoroborate for surface modification to obtain the filler.
[0088] The mass ratio of polyacrylonitrile, polyvinylidene fl...
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