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Waterproof agent and wool dyeing agent for chrome-free tanned Chenille leather and environment-friendly dyeing process of chrome-free tanned Chenille leather

A technology for tanning leather and water repellent, applied in the field of leather processing, can solve the problems of reduced color fullness of the board surface, high production energy consumption, and inability to guarantee safety, so as to solve the problem of poor product performance, improve waterproof performance, and waterproof great effect

Active Publication Date: 2021-02-19
隆丰革乐美时尚有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it still exists. The one-time investment in the purchase of dry cleaning equipment is huge, and special personnel are required to maintain and maintain it in the later period. Dry cleaning will cause excessive damage to the wool fiber and poor oiliness, resulting in dry and astringent hair, and the color plumpness of the board surface will also be reduced during dyeing; although the addition of chromium-containing materials in the retanning process can improve the performance of the finished product, such as fullness of the leather board Degree, softness, waterproof performance, etc., but at the same time, it also causes hidden dangers in environmental protection and safety.
One is that chromium-containing waste cannot be effectively treated, which is harmful to the environment; the other is that the finished product of chrome tanned leather contains trace amounts of hexavalent chromium, and the safety of long-term wearing cannot be guaranteed; while high-temperature dyeing of wool requires high production energy consumption, and high-temperature dyeing of wool takes a long time Maintaining the dyeing bath at 65-70°C consumes high heat energy costs, and frequently causes quality problems, the skin is easy to shrink, and the operation is difficult.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Waterproof agent and wool dyeing agent for chrome-free tanned Chenille leather and environment-friendly dyeing process of chrome-free tanned Chenille leather
  • Waterproof agent and wool dyeing agent for chrome-free tanned Chenille leather and environment-friendly dyeing process of chrome-free tanned Chenille leather
  • Waterproof agent and wool dyeing agent for chrome-free tanned Chenille leather and environment-friendly dyeing process of chrome-free tanned Chenille leather

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0187] 1 Pre-finishing: scalding, shearing, brushing the wool surface with alcohol water, scalding and shearing twice, the scalding temperature is 160-170°C, and the wool is required to be loose, smooth and free from sticking hair;

[0188] 2 Backwater: equipment drum, 1000% water, temperature 40°C, add 1% ammonia water, 2% high-efficiency environmental protection degreasing agent VLC-3, rotate for 60 minutes, add 1% Levatan L, rotate for 120 minutes , drain and rinse with cold water once;

[0189] 3 Retanning: equipment drum, 1000% water, temperature 40°C, pre-fatliquor treatment, add 1% sulfonated oil TIS, 2% synthetic fatliquor GLH, rotate for 30 minutes, add 1% formic acid, rotate For 20 minutes, adjust the pH of the bath solution to 3.8-4.0, add fatty aldehyde DC (N) 2%, rotate for 30 minutes, add cationic synthetic tanned CAT 4%, rotate for 90 minutes, add 2.5% sodium formate, rotate for 120 minutes, adjust pH4. 0±, drain and wash twice in cold water;

[0190] 4. Wool ...

Embodiment 2

[0214] 1 Pre-finishing: scalding, shearing, brushing the wool surface with alcohol water, scalding and shearing twice, the scalding temperature is 160-170°C, and the wool is required to be loose, smooth and free from sticking hair;

[0215] 2 Backwater: equipment drum, 1000% water, temperature 40°C, add 1% ammonia water, 2% high-efficiency environmental protection degreasing agent VLC-3, rotate for 60 minutes, add 1% IPF, rotate for 120 minutes, drain, Rinse once in cold water;

[0216] 3 Retanning: equipment drum, 1000% water, temperature 40°C, first do pre-fatliquor treatment, add 1% sulfonated oil TIS, 2% fatliquor CFS, rotate for 30 minutes, add 1% formic acid, rotate for 20 minutes Minutes, adjust the bath liquid pH3.8~4.0, add fatty aldehyde PF 2%, turn for 30 minutes, add cationic synthetic tanning CAT 4%, turn for 90 minutes, add sodium formate 2.5%, turn for 120 minutes, adjust pH4.0±, drain , wash twice in cold water;

[0217] 4. Wool dyeing: equipment drum, 1000% ...

Embodiment 3

[0241] 1 Pre-finishing: scalding, shearing, brushing the wool surface with alcohol water, scalding and shearing twice, the scalding temperature is 160-170°C, and the wool is required to be loose, smooth and free from sticking hair;

[0242] 2 Backwater: equipment drum, 1000% water, temperature 40°C, add 1% ammonia water, 2% high-efficiency environmental protection degreasing agent VLC-3, rotate for 60 minutes, add 1% PMB, rotate for 120 minutes, drain, Rinse once in cold water;

[0243] 3 Retanning: equipment drum, 1000% water, temperature 40°C, first do pre-fatliquor treatment, add 1% sulfonated oil ELS, 2% synthetic fatliquor WWL, rotate for 30 minutes, add 1% formic acid, rotate For 20 minutes, adjust the pH of the bath solution to 3.8-4.0, add fatty aldehyde PAL 2%, rotate for 30 minutes, add cationic synthetic tanned CAT 4%, rotate for 90 minutes, add 2.5% sodium formate, rotate for 120 minutes, adjust the pH to 4.0±, Drain and wash twice in cold water;

[0244] 4. Wool...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention provides a waterproof agent for dyeing chrome-free tanned woolen leather, the waterproof agent comprising the following components in parts by weight: 1.8-2.2 parts of a waterproof fatting agent, 1.2-1.8 parts of a metal tanning agent and 800-1200 parts of water. The invention further provides a wool dyeing agent for dyeing the chrome-free tanned wool leather and a dyeing process. According to the invention, the waterproof agent with a specific ratio is adopted, no chromium-containing material is adopted, waterproof treatment is carried out after the last time of acid pickling after plate dyeing, and the waterproof fatting agent is selected to be matched with the metal tanning agent, so that the waterproof performance is greatly improved by combining the two agents. The problems of poor quality and environmental protection during dyeing of chrome-free tanned Chenille leather and the problems of poor product performance, potential safety hazards in wearing and the like caused by conventional process treatment are effectively solved, and meanwhile, the product has the characteristics of thinness, lightness and softness, is light and comfortable to wear, good in heat retention property, excellent in leather waterproofing effect and high in shrinkage temperature, and realizes zero content of hexavalent chromium.

Description

technical field [0001] The invention belongs to the technical field of leather treatment and processing, and relates to a water repellant, a hair dyeing agent for chrome-free tanned leather and a dyeing process for chrome-free tanned leather, in particular to a chrome-free tanned sheep shearling leather Waterproofing agent, hair dyeing agent and environmentally friendly dyeing process of chrome-free tanned sheep shearling leather. Background technique [0002] Leather treatment refers to the process of turning perishable raw hide, that is, raw hide into soft and non-perishable leather after a series of processes. Usually from the raw leather to the finished leather, it is roughly divided into three stages, the preparation stage, the tanning stage and the finishing (finishing) stage, mainly including soaking, fleshing, depilation, liming, degreasing, softening, pickling, tanning and The follow-up finishing stage can be subdivided into batches--(meat removal)--weighing--preso...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P1/39D06P1/44D06P3/30C14C9/02C14C3/04C14C3/02C14C3/08
CPCD06P1/39D06P1/445D06P3/3008C14C9/02C14C3/04C14C3/02C14C3/08Y02P70/62
Inventor 仲济德段旭阳王天超杨澍马丛登黄招
Owner 隆丰革乐美时尚有限公司
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