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Water-based antistatic photocureable coating and preparation method thereof

A light-curing coating and antistatic technology, used in conductive coatings, polyether coatings, epoxy resin coatings, etc., can solve the problems of easy particle agglomeration system viscosity, less research, uneven particle dispersion, etc., to avoid uneven dispersion. The effect of uniformity, good dispersion and stability

Pending Publication Date: 2021-02-02
山东亿博润新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the long rigid structure and strong interaction between molecular chains, conductive polymers prepared by conventional methods are difficult to dissolve.
Directly using conductive polymer powder as a conductive filler and mixing it with UV-curable materials is also prone to uneven particle dispersion, easy agglomeration between particles and increased viscosity of the system
In addition, water-based antistatic UV-curable coatings combine water-based and antistatic properties with UV-curable materials to endow materials with unique properties such as environmental protection, antistatic and high-efficiency photocuring. There are few studies on this aspect.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] This embodiment provides a kind of waterborne antistatic type photocurable coating, and its preparation method comprises the following steps:

[0022] S1. Weigh 100g of water-based UV-curable resin, 5g of polypyrrole nanoparticle aqueous solution, 1g of water-based defoamer, 0.6g of water-based leveling agent, and 2g of photoinitiator, and set aside; wherein, the particle size of polypyrrole nanoparticle aqueous solution is 100 Within the nanometer, its preparation method can refer to the prior art, specifically the literature (Shihu Zhang, et al. UV-Catalytic Preparation of Polypyrrole Nanoparticles Induced by H 2 o 2 [J]. The Journal of Physical Chemistry C, 2015, 119, 18707-18718.); the water-based UV curable resin is water-based aliphatic urethane acrylate resin, specifically, the water-based aliphatic urethane acrylate resin can be commercially available IRR 210 resin; the water-based defoamer is commercially available BYK-066N; the water-based leveling agent is ...

Embodiment 2

[0026] This embodiment provides a kind of waterborne antistatic type photocurable coating, and its preparation method comprises the following steps:

[0027] S1. Weigh 100g of water-based UV-curable resin, 10g of polypyrrole nanoparticle aqueous solution, 1.5g of water-based defoamer, 0.8g of water-based leveling agent, and 3g of photoinitiator, and set aside; wherein, the polypyrrole nanoparticle aqueous solution and Example 1 The same; the water-based UV curable resin is water-based aliphatic urethane acrylate resin, specifically, the water-based aliphatic urethane acrylate resin can be commercially available IRR 210 resin; the water-based defoamer is commercially available BYK-028; the water-based fluid The leveling agent is commercially available BYK-375; the photoinitiator is commercially available Irgacure-1173.

[0028] S2. Place the weighed water-based UV-curable resin, water-based defoamer, water-based leveling agent, and photoinitiator at room temperature, and mix an...

Embodiment 3

[0031] This embodiment provides a kind of waterborne antistatic type photocurable coating, and its preparation method comprises the following steps:

[0032] S1. Weigh 100g of water-based UV-curable resin, 20g of polypyrrole nanoparticle aqueous solution, 2.4g of water-based defoamer, 1.2g of water-based leveling agent, and 2g of photoinitiator, and set aside; wherein, the polypyrrole nanoparticle aqueous solution and Example 1 The same; the water-based UV curable resin is water-based aliphatic urethane acrylate resin, specifically, the water-based aliphatic urethane acrylate resin can be commercially available IRR 210 resin; the water-based defoamer is commercially available BYK-024; the water-based fluid The leveling agent is commercially available BYK-375; the photoinitiator is commercially available Irgacure-184.

[0033] S2. Place the weighed water-based UV-curable resin, water-based defoamer, water-based leveling agent, and photoinitiator at room temperature, and mix and...

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Abstract

The invention is applicable to the technical field of photocureable coatings, and provides a water-based antistatic photocureable coating and a preparation method thereof. The preparation method comprises the steps that a polypyrrole nanoparticle aqueous solution serves as a conductive component and is mixed with water-based ultraviolet curing resin, a water-based defoamer, a water-based levelingagent, a photoinitiator and other components, and the preparation of the water-based antistatic photocureable coating can be completed. The method is simple, convenient and easy to implement, and theprepared antistatic photocureable coating does not contain volatile organic solvents, does not need to be heated, and is efficient and environmentally friendly, meanwhile, the conductive component polypyrrole nano-particles have good dispersity and stability in a photocuring system, ideal antistatic performance can be obtained with a small addition amount, and the situation that inorganic conductive particles or conductive polymer powder and the like are dispersed unevenly in the photocuring system after being added as conductive filler is also avoided, agglomeration and precipitation are easily caused, and the viscosity of the system is obviously increased.

Description

technical field [0001] The invention belongs to the technical field of photocurable coatings, in particular to a water-based antistatic photocurable coating and a preparation method thereof. Background technique [0002] UV-curable coatings have been widely used for many years due to their advantages such as fast curing speed, low energy consumption, high production efficiency, and good coating performance. The monomer has a certain volatility, which is not conducive to environmental protection and human health. If only non-volatile oligomers are used to prepare high-solid-content light-curing coatings, there will be a problem that the viscosity of the system is too high to affect the construction. Generally, the way to reduce the viscosity of the system is to add a certain amount of organic solvents, which will also cause solvent volatilization. pollution problems. If water is used instead of active diluent in UV-curable coatings, the above problems can be avoided. On the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D163/10C09D171/00C09D5/24
CPCC08L2201/04C08L2205/03C08L2205/035C09D5/24C09D171/00C09D175/14C08L79/04C08L63/10C08L67/06C08L71/00C08L75/14
Inventor 张士虎王超李仕胜王振强张晓娣杨化通郝德开
Owner 山东亿博润新材料科技有限公司
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