Preparation method of liquid crystal polymer film material with low dielectric constant and low dielectric loss

A technology of liquid crystal polymer film and low dielectric constant, which can be used in flat products, applications, coatings, etc., and can solve the problem of poor dispersion uniformity of polytetrafluoroethylene, low polytetrafluoroethylene content, adverse effects of consistency, etc. problem, to achieve the effect of stable information transmission speed, uniform dielectric loss, and improved consistency of dielectric constant

Active Publication Date: 2021-01-05
江苏中际信通讯材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the above process, the mixture of polytetrafluoroethylene and liquid crystal polymer is first made into pellets, and then extruded to obtain the blended surface layer. The production process has the following defects: first, the content of polytetrafluoroethylene in the production process based on pellet blending Low, based on the sum of the mass of liquid crystal polymer and polytetrafluoroethylene as 100%, the mass percentage of polytetrafluoroethylene pellets is 5 to 25%; second, polytetrafluoroethylene in the liquid crystal polymer film obtained by co-extrusion The dispersion uniformity of vinyl fluoride is not good; third, the stretching treatment may have an adverse effect on the consistency of the dielectric constant of the liquid crystal polymer film; fourth, limited by the extrusion equipment, the maximum The large width is a fixed value

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] S1: Dissolve liquid crystal polymer (LCP) in an organic solvent by high-speed stirring to prepare a 5% liquid crystal polymer solution;

[0041] S2: Based on the sum of liquid crystal polymer and polytetrafluoroethylene powder mass as 100%, add 10% polytetrafluoroethylene powder to the mixed solution prepared in step S1, grind and disperse at high speed for 2 hours to obtain the fineness of the mixed slurry <15μm homogeneous mixed slurry;

[0042] S3: Apply the mixed slurry prepared in step S2 evenly on the surface of the copper foil through a glue applicator, dry at 150°C for 30 minutes, and melt at 280°C to form a film for 10 minutes;

[0043] S4: The copper foil was chemically etched to obtain an LCP film with uniform thickness and uniform dispersion of PTFE, with a film thickness of 30 μm.

Embodiment 2

[0045] Embodiment 2 is based on embodiment 1, difference is: the solute content of liquid crystal polymer solution is 12.5%; Based on the sum of liquid crystal polymer and polytetrafluoroethylene powder mass 100%, the mass percent of polytetrafluoroethylene powder is 15%, the film thickness of the LCP film is 50μm.

Embodiment 3

[0047] Embodiment 3 is based on embodiment 1, difference is: the solute content of liquid crystal polymer solution is 18%; Based on the sum of liquid crystal polymer and polytetrafluoroethylene powder mass 100%, the mass percent of polytetrafluoroethylene powder is 25%.

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PUM

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Abstract

The invention discloses a preparation method of a liquid crystal polymer film material with a low dielectric constant and a low dielectric loss. The preparation method comprises the following steps of: S1, dissolving a liquid crystal polymer into a solvent to obtain a liquid crystal polymer solution; S2, adding fluororesin powder into the liquid crystal polymer solution, and dispersing the mixed material; S3, coating the surface of a release base material with the mixed material obtained in the step S2, and carrying out drying and melting treatment on a coating layer to form a film; and S4, separating a film layer from the release base material to prepare the liquid crystal polymer film material. The preparation method of the liquid crystal polymer film material with the low dielectric constant and the low dielectric loss sequentially comprises the four steps of dissolving the liquid crystal polymer, dispersing the fluororesin powder, coating and drying the mixed material and forming the film to separate from the release base material, and more fluororesin is conveniently added into the liquid crystal polymer film material by adopting a liquid mixing mode; and the fluororesin powder in the liquid crystal polymer film material is dispersed more uniformly. The invention also discloses the liquid crystal polymer film material and a mobile phone antenna based on the liquid crystalpolymer film material.

Description

technical field [0001] The invention relates to the technical field of liquid crystal polymer film manufacturing, in particular to a method for preparing a liquid crystal polymer film with low dielectric constant and low dielectric loss, a liquid crystal polymer film and a mobile phone antenna. Background technique [0002] Liquid crystal polymer (LCP) materials have high strength, high modulus, outstanding heat resistance, extremely small linear expansion coefficient, excellent flame resistance, electrical insulation, chemical corrosion resistance, weather aging resistance and microwave permeability, It is an ideal high-frequency (millimeter wave) material due to its excellent molding and processing properties. With the development of the 5G industry, the industry has lower requirements for the transmission loss of materials under high-frequency conditions, and the dielectric loss of existing LCP film materials is relatively large, which can no longer meet the requirements ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29D7/01G02F1/1333C09D201/00C09D127/18
CPCB29D7/01G02F1/1333C09D201/00C08L2203/20C08L27/18
Inventor 陈怡方陈晓燕
Owner 江苏中际信通讯材料有限公司
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