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Photosensitive material for 3D printing and preparation method thereof

A photosensitive material and 3D printing technology, applied in the field of photosensitive materials, can solve the problems of insufficient resin toughness, poor impact resistance, single variety, etc., and achieve the effects of fast curing speed, excellent bending performance, and good storage stability

Inactive Publication Date: 2020-12-04
河源然生新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there is a single variety of photosensitive resins used in 3D printers in China, mainly resins with high hardness, but this type of resin has the disadvantages of insufficient toughness, poor impact resistance, and fragility. a new research direction

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A photosensitive material for 3D printing, by parts by weight, comprising the following components:

[0019] Acrylic resin 25 parts;

[0020] 65 parts of active diluent;

[0021] 10 parts of toughening agent;

[0022] 5 parts of photoinitiator;

[0023] Auxiliary 0.1 parts.

[0024] The acrylic resin is modified epoxy acrylate.

[0025] The reactive diluent is a 3:3:1 mixture of tripropylene glycol diacrylate, trimethylolpropane triacrylate, and hydroxyethyl methacrylate.

[0026] The toughening agent is a 1:1 mixture of 3-ethyl-3-oxetanemethanol and 3-methyl-3-hydroxymethyloxetane.

[0027] The photoinitiator is 4-phenylbenzophenone.

[0028] The auxiliary agent is TEGO Airex945.

[0029] The preparation of the UV light-curable photosensitive material in this example can be carried out according to the process commonly used in the field. The above materials are weighed by weight, stirred with a disperser for 30 minutes to disperse evenly, and the temperature is ...

Embodiment 2

[0031] A photosensitive material for 3D printing, by parts by weight, comprising the following components:

[0032] Acrylic resin 15 parts;

[0033] 75 parts of active diluent;

[0034] 10 parts of toughening agent;

[0035] 4 parts of photoinitiator;

[0036] Auxiliary 0.1 parts;

[0037] The acrylic resin is polyurethane acrylate.

[0038] The reactive diluent is a mixture of tripropylene glycol diacrylate, hexanediol diacrylate, bisphenol A diacrylate, tetraethylene glycol diacrylate and trimethylolpropane triacrylate.

[0039] The toughening agent is a 2:1 mixture of 3-ethyl-3-oxetanemethanol and 3-methyl-3-hydroxymethyloxetane.

[0040] The photoinitiator is α-dimethyl-α-hydroxyacetophenone.

[0041] The auxiliary agent is TEGO Airex910.

[0042] The preparation of the UV light-curable photosensitive material in this example can be carried out according to the process commonly used in the field. The above materials are weighed by weight, stirred with a disperser fo...

Embodiment 3

[0044] A photosensitive material for 3D printing, by parts by weight, comprising the following components:

[0045] Acrylic resin 25 parts;

[0046] 60 parts of active diluent;

[0047] 15 parts of toughening agent;

[0048] 3.5 parts of photoinitiator;

[0049] Auxiliary 0.1 parts;

[0050] The acrylic resin is polyester acrylate.

[0051] The reactive diluent is a mixture of vinylpyrrolidone and diethylene glycol divinyl ether.

[0052] The toughening agent is a 3:1 mixture of 3-ethyl-3-oxetanemethanol and 3-methyl-3-hydroxymethyloxetane.

[0053] The photoinitiator is 2-thioxanthone chloride and isopropylthioxanthone.

[0054] The auxiliary agent is TEGO Airex920.

[0055] The preparation of the UV light-curable photosensitive material in this example can be carried out according to the process commonly used in this field. The above materials are weighed by weight, stirred with a disperser for 38 minutes to disperse evenly, and the temperature is controlled at 58°C t...

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PUM

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Abstract

The invention discloses a photosensitive material for 3D printing and a preparation method thereof. The photosensitive material is prepared from, by weight, 10-25 parts of acrylic resin, 60-75 parts of a reactive diluent, 10-20 parts of a flexibilizer, 1-5 parts of a photoinitiator and 0.05-0.1 part of an assistant, and the acrylic resin, the reactive diluent, the flexibilizer and the photoinitiator are weighed according to preset parts by weight, the preparation method comprises the following steps: putting the raw materials into a dispersion machine, mixing, stirring, uniformly dispersing for 20-40 minutes, and controlling the temperature to be 40-60 DEG C in the stirring process, thereby obtaining the UV light-cured photosensitive material. The photosensitive material prepared by the invention has the advantages of high curing speed, good product storage stability, difficulty in deformation of a printed large model and excellent bending performance, can be used for directly printingan elastic model, and is suitable for DLP rapid prototyping desktop-level 3D printing equipment.

Description

technical field [0001] The invention relates to a photosensitive material, in particular to a UV photocurable photosensitive material used for DLP rapid prototyping desktop-level 3D printing equipment and a preparation method thereof. Background technique [0002] The 3D printing technologies using photosensitive resin as printing materials mainly include: stereolithography (Stereolithography, SLA), DLP projection three-dimensional printing process (Digital Light Processing, DLP) and ultra-thin layer thick photosensitive resin injection molding technology (Connex500 system Objet Geometries Corporation). The printing process is to determine the three-dimensional model in the computer, and then deliver it to the 3D printer. The printing process uses ultraviolet light to irradiate the liquid photosensitive resin, and the layers are stacked and formed. [0003] The photosensitive resin used for 3D printing needs to be cured quickly under the exposure conditions of the 3D printe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/00C08F283/01C08F283/10C08F222/20C08F222/14C08F226/10C08F216/18B33Y70/00
CPCC08F283/008C08F283/01C08F283/105B33Y70/00
Inventor 欧龙生许李繁邹名超
Owner 河源然生新材料有限公司
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