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A kind of preparation method of fuel cell membrane electrode catalytic layer

A technology of electrode catalytic layer and fuel cell membrane, which is applied to battery electrodes, circuits, electrical components, etc., can solve the problems of increasing the complexity and production cost of membrane electrode preparation process, and being unfavorable for efficient production of membrane electrodes.

Active Publication Date: 2021-07-06
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above method also increases the complexity and production cost of the membrane electrode preparation process. At the same time, the processing time for vacuum removal of solvent is as long as several hours, which is not conducive to the efficient production of membrane electrodes.

Method used

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  • A kind of preparation method of fuel cell membrane electrode catalytic layer
  • A kind of preparation method of fuel cell membrane electrode catalytic layer
  • A kind of preparation method of fuel cell membrane electrode catalytic layer

Examples

Experimental program
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Embodiment 1

[0041] This embodiment provides a kind of preparation method of fuel cell membrane electrode catalytic layer, and makes the catalytic layer / ion exchange membrane module (Catalyst Coated Membrane, CCM) with uniform catalytic layer structure such as figure 2 As shown, the magnetic field control process device diagram of the catalytic layer drying process is shown in figure 1 Shown, the preparation method of CCM specifically comprises the following steps:

[0042] Step 1: get the mass fraction of 20g platinum (Pt) and be the PtCo / C catalyst of 50%, add 22g deionized water, 28g isopropanol and 50g mass fraction and be the Nafion solution of 20%, after magnetic stirring 4 hours, transfer to high pressure homogenization Carry out secondary dispersion in the homogenizer, the valve pressure of the high-pressure homogenizer is 300-500bar, the nozzle pressure is 400-600bar, disperse for 1 hour, and obtain the catalytic layer slurry; wherein, the atomic ratio of Pt and Co in the PtCo / C ...

Embodiment 2

[0048] The present embodiment provides a kind of preparation method of fuel cell membrane electrode catalytic layer, and makes the catalytic layer / ion exchange membrane assembly (CCM) that has three-layer structure cathode catalytic layer such as image 3 As shown, the CCM specifically includes the following steps:

[0049] Step 1: get 20g platinum (Pt) mass fraction and be 50% PtCo / C catalyst, add 200g deionized water and 350g isopropanol, add 200g mass fraction after ultrasonic dispersion 5 minutes and be 5% Nafion solution, ultrasonic dispersion 20 minutes, then stirred for 1 hour to prepare catalyst slurry; wherein, the atomic ratio of Pt and Co in the PtCo / C catalyst was 3:1;

[0050] Step 2: Use an ultrasonic sprayer to spray the cathode catalytic layer: set the temperature of the bottom plate of the sprayer to 60°C, set the slurry flow rate and travel speed of the nozzle so that the single-layer Pt loading is 0.1mg / cm 2 ;An electromagnet is placed behind the nozzle thr...

Embodiment 3

[0056] This embodiment provides a method for preparing a catalytic layer of a fuel cell membrane electrode, which specifically includes the following steps:

[0057] Step 1: Take 15g of Pt / C catalyst with a mass fraction of platinum of 50%, 5g of PtCo / C catalyst with a mass fraction of platinum of 50%, add 200g of deionized water and 350g of isopropanol, and add after ultrasonic dispersion for 5 minutes 200g of Nafion solution with a mass fraction of 5%, ultrasonically dispersed for 20 minutes, and then stirred for 1 hour to prepare a catalyst slurry; wherein, the atomic ratio of Pt to Co in the PtCo / C catalyst was 3:1;

[0058] Step 2: Use an ultrasonic sprayer to spray the catalyst slurry on both sides of the Gore-select proton exchange membrane 602, set the temperature of the bottom plate heated by the sprayer to 60°C, and control the Pt loading by setting the slurry flow rate and travel speed of the sprayer. CCM was obtained after drying, wherein the Pt loading of the cath...

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Abstract

The invention provides a method for preparing a fuel cell membrane electrode catalyst layer. The fuel cell membrane electrode catalyst layer includes a cathode catalyst layer and an anode catalyst layer prepared on both sides of a substrate, and both the cathode catalyst layer and the anode catalyst layer are the catalyst layer slurry Coated on the surface of the substrate, dried and post-treated on the catalytic layer, the catalytic layer slurry of the cathode catalytic layer includes a catalyst containing ferromagnetic elements, and a magnetic field is applied during the post-treatment of the catalytic layer of the cathode catalytic layer, so that the slurry containing ferromagnetic The catalyst of the element moves in the cathode catalytic layer to realize the in-situ regulation of the pore structure of the cathode catalytic layer, increase the porosity of the catalytic layer, and promote the mass transfer of the reaction gas in the catalytic layer; in addition, there are many controllable parameters in the magnetic field adjustment process, and the process is simple , will not cause pollution to the catalytic layer, and in commercial application, it only needs to be equipped with an additional magnetic field adjustment device on the existing production line, and the modification to the existing process system is small, and it is easy to promote.

Description

technical field [0001] The invention belongs to the field of proton exchange membrane fuel cells, and in particular relates to a method for preparing a catalytic layer of a fuel cell membrane electrode. Background technique [0002] Proton Exchange Membrane Fuel Cells (PEMFC) have outstanding advantages such as low operating temperature, high power density, fast start-up speed, and zero emissions. The application prospect is an important direction for the sustainable development of energy in the future. [0003] In the PEMFC cell stack, the membrane electrode (Membrane Electrode Assembly, MEA) is the core component of the system for external energy output, consisting of a proton exchange membrane, a catalytic layer (Catalyst Layer, CL) coated on both sides of the proton exchange membrane surface gas diffusion layer. Among them, the catalytic layer is the place where the electrochemical reaction of the fuel cell occurs, and is composed of an ionic polymer, a catalyst and a ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/88H01M4/92
CPCH01M4/8828H01M4/8878H01M4/8882H01M4/921H01M4/926Y02E60/50
Inventor 高艳汤浩乔泽敏殷聪李凯
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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