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Fiber-reinforced ceramic matrix composite surface antioxidant/infrared stealth coating capable of resisting temperature of 1650 DEG C and preparation method thereof

A technology of fiber reinforcement and composite materials, which is applied in the coating process of metal materials, devices for coating liquid on the surface, and coatings, etc. It can solve the problems of easy migration and diffusion at high temperature, low bonding strength, and thermal mismatch of substrates. , to achieve the effects of improving high temperature oxidation resistance and high temperature stability, improving high temperature performance and service life, and reducing the difference in thermal expansion coefficient

Active Publication Date: 2020-10-02
NAT UNIV OF DEFENSE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As the thrust-to-weight ratio of the engine and the flight speed of the aircraft increase, the surface temperature of the aircraft and the temperature inside the engine exceed 1000°C or even higher. Low-emissivity fillers have low melting point, easy oxidation at high temperature, easy migration and diffusion at high temperature, and other high-temperature performance instability, which makes it impossible to use in high-temperature environments; poor compatibility between coatings and substrates, between coatings, between coatings and substrate materials Thermal mismatch, resulting in cracking or peeling of the coating; the phase instability of the coating at high temperature, phase transition, the accompanying volume change during the transition process may lead to cracking of the coating, etc.
In addition, the existing traditional physical platinum coating can withstand high temperature, but the platinum coating and the substrate mainly rely on physical bonding, the bonding strength is low, the thermal mismatch with the substrate is serious, and it is easy to fall off after repeated thermal shocks, and its performance is unstable in high temperature environments , there is also the problem of high preparation cost
[0004] As the structural materials of high-temperature parts of aircraft are advancing towards high temperature and light weight, traditional alloy materials can no longer meet the demand. Ceramic matrix composite materials with carbon fiber as the reinforcement phase have become the focus of development. This type of composite material has high temperature resistance, low density and high strength. and other advantages, can meet the requirements of high temperature and light weight, but this kind of composite material is easy to oxidize under high temperature oxygen-enriched and water vapor conditions, so that the performance of the material is seriously reduced. In order to make the composite material stable in high temperature environment, it is necessary to carry out Antioxidant treatment

Method used

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  • Fiber-reinforced ceramic matrix composite surface antioxidant/infrared stealth coating capable of resisting temperature of 1650 DEG C and preparation method thereof
  • Fiber-reinforced ceramic matrix composite surface antioxidant/infrared stealth coating capable of resisting temperature of 1650 DEG C and preparation method thereof

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Effect test

Embodiment 1

[0043] An anti-oxidation / infrared stealth coating on the surface of a fiber-reinforced ceramic matrix composite material with a temperature resistance of 1650°C. The fiber-reinforced ceramic matrix composite material is a C / SiC composite material, and the infrared stealth coating is a layered structure, which includes ceramics from bottom to top. Inner layer, ceramic middle layer, ceramic outer layer and low infrared emissivity functional layer, ceramic inner layer is mullite layer, ceramic middle layer is erbium silicate layer, ceramic outer layer is 8YSZ layer, low infrared emissivity functional layer is With Pt as the conductive phase, Bi 2 o 3 For the coating of the binder phase, the conductive phase accounts for 95% of the total mass of the conductive phase and the binder phase. The thickness of the ceramic inner layer is 60 μm, the thickness of the ceramic middle layer is 80 μm, the thickness of the ceramic outer layer is 100 μm, and the thickness of the low infrared em...

Embodiment 2

[0057] An anti-oxidation / infrared stealth coating on the surface of a fiber-reinforced ceramic matrix composite material with a temperature resistance of 1650 ° C. The fiber-reinforced ceramic matrix composite material is a C / C composite material, and the infrared stealth coating is a layered structure, which includes ceramics from bottom to top. Inner layer, ceramic middle layer, ceramic outer layer and low infrared emissivity functional layer, ceramic inner layer is mullite layer, ceramic middle layer is lutetium silicate layer, ceramic outer layer is 8YSZ layer, low infrared emissivity functional layer is With Pt as the conductive phase, Bi 2 o 3 For the coating of the binder phase, the conductive phase accounts for 98% of the total mass of the conductive phase and the binder phase. The thickness of the ceramic inner layer is 80 μm, the thickness of the ceramic middle layer is 100 μm, the thickness of the ceramic outer layer is 80 μm, and the thickness of the low infrared ...

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Abstract

The invention relates to the technical field of high-temperature infrared stealth materials and particularly discloses a fiber-reinforced ceramic matrix composite surface antioxidant / infrared stealthcoating capable of resisting the temperature of 1650 DEG C. The infrared stealth coating is of a layered structure and comprises a ceramic inner layer, a ceramic middle layer, a ceramic outer layer and a low-infrared-emissivity functional layer from bottom to top, wherein the ceramic inner layer is a mullite layer, the ceramic middle layer is a rare earth silicate layer, the ceramic outer layer isan 8YSZ layer, and the low-infrared-emissivity functional layer is a coating with Pt as a conductive phase and Bi2O3 as a binding phase. The invention further provides a preparation method of the fiber-reinforced ceramic matrix composite surface antioxidant / infrared stealth coating capable of resisting the temperature of 1650 DEG C. According to the infrared stealth coating, the oxidation resistance and the high-temperature stability of the composite material are improved, the infrared radiation intensity of a base material can be remarkably reduced, and the infrared stealth coating has excellent oxidation resistance and an infrared stealth function.

Description

technical field [0001] The invention belongs to the technical field of high-temperature infrared stealth materials, and in particular relates to an anti-oxidation / infrared stealth coating on the surface of a fiber-reinforced ceramic matrix composite material with a temperature resistance of 1650°C and a preparation method thereof. Background technique [0002] In recent years, infrared detection and tracking technology has developed rapidly, and infrared guided weapons have become the main threat in air combat. In order to improve the survival and penetration capabilities of the new generation of aircraft, it is urgent to develop advanced and effective infrared stealth technology. Infrared stealth technology is a technology that reduces the infrared radiation difference between the target and the background by controlling or reducing the infrared radiation characteristics of the target, thereby reducing the target's detection, tracking, identification, attack distance and pro...

Claims

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Application Information

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IPC IPC(8): C04B41/90C04B35/16C04B35/626C23C4/134C23C4/11C22C32/00C22C5/04
CPCB05D2203/30C04B35/16C04B35/6261C04B35/62625C04B35/62655C04B35/62675C04B41/52C04B41/90C04B2235/3224C22C5/04C22C32/0021C23C4/11C23C4/134C04B41/5027C04B41/4527C04B41/4519C04B41/5042C04B41/5049C04B41/5122C04B41/4539C04B41/0072
Inventor 刘海韬黄文质孙逊
Owner NAT UNIV OF DEFENSE TECH
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