Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of alloy electroplating material with high bonding force

An alloy electroplating and bonding force technology, applied in electrolytic coatings, surface reaction electrolytic coatings, coatings, etc., can solve problems such as unfavorable electroplating process, no open etching method, non-uniform corrosion, etc. Good detoxification and high solubility

Active Publication Date: 2020-05-08
东莞市原琦五金有限公司
View PDF7 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0051] For details, see the attached figure 1 It is stated in the relevant content of the specification that “in some cases, the oxide structure 18 can be etched to remove its part (including the barrier layer) at the bottom of the nanopore 16, thereby exposing the underlying aluminum substrate 12”, that is, the The prior art directly abandons the treatment of the shielding layer 19, or directly etches it away vaguely, and does not disclose a specific etching method at all.
[0052] In addition, methods for removing the shielding layer are also described in the prior art, including the use of oxalic acid or phosphoric acid, or other mixtures, but there are obvious technical problems as follows: (1) The porous oxide layer cannot be limitedly distinguished by acid corrosion And the shielding layer, that is, the acid solution corrodes the anodic oxide film indiscriminately, which seriously affects the array structure of the anodic oxide film channel, resulting in the collapse of the anodic oxide film array structure or non-uniform corrosion, which is not conducive to the subsequent electroplating process and seriously reduces the electroplating of the coating. Uniformity and stability of bonding force; (2) During the corrosion process, when the shielding layer is penetrated, the corrosion solution will obviously corrode the aluminum material, causing damage to the base material

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of alloy electroplating material with high bonding force
  • Preparation method of alloy electroplating material with high bonding force
  • Preparation method of alloy electroplating material with high bonding force

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0109] The pretreatment step used in embodiment 1-3 is consistent with the solution, all including mechanical polishing-degreasing-hot water washing-alkali washing-hot water washing-cold water washing-acid washing-water washing:

[0110] The mechanical polishing is sandblasting,

[0111] Described degreasing is alkaline degreasing, and degreasing liquid is the mixed aqueous solution of 23g / L sodium carbonate and 2.5g / L sodium phosphate, temperature 67 o C, soaking time 5.5min;

[0112] Described alkali washing liquid is the sodium citrate aqueous solution of 25g / LNaOH, 4g / L, and temperature is 15 o C, soaking time 17.5min;

[0113] The pickling and deashing solution is 60g / L HNO 3 and a mixed aqueous solution of 6g / LNaF at room temperature for 2.5 minutes.

[0114] (2) Anodizing: use the aluminum material treated in step (1) as the anode, graphite as the cathode, immerse in the electrolyte, and connect the power supply through wires respectively. The electrolyte is a mixtu...

Embodiment 2

[0122] (2) Anodizing: use the aluminum material treated in step (1) as the anode, graphite as the cathode, immerse in the electrolyte, and connect the power supply through wires respectively. The electrolyte is a mixture of oxalic acid, phosphoric acid and sulfosalicylic acid , the concentration of oxalic acid is 0.275M, the concentration of phosphoric acid is 0.3M, the concentration of sulfosalicylic acid is 0.1M, the electrolysis parameters are as follows, the voltage is 25V, the temperature is 30 o C, current density 2.5A / dm 2 , time 25min; after anodizing, soak and clean in ethanol, and use vacuum drying to remove the electrolyte in the oxide film. The whole process strictly avoids the aluminum after anodizing from contacting air or water to avoid sealing holes.

[0123] (3) Protective film for positioning marks: Soak the aluminum material treated in step (2) in a toluene solution of γ-chloropropyltrimethylsilane, the concentration is 15wt.%, and the amount is 1% of the we...

Embodiment 3

[0130] (2) Anodizing: use the aluminum material treated in step (1) as the anode, graphite as the cathode, immerse in the electrolyte, and connect the power supply through wires respectively. The electrolyte is a mixture of oxalic acid, phosphoric acid and sulfosalicylic acid , the concentration of oxalic acid is 0.3M, the concentration of phosphoric acid is 0.4M, the concentration of sulfosalicylic acid is 0.15M, the electrolysis parameters are as follows, the voltage is 30V, the temperature is 30 o C, current density 3A / dm 2 , time 30min; after anodizing, soak and clean in ethanol, and use vacuum drying to remove the electrolyte in the oxide film. During the whole process, strictly avoid the aluminum after anodizing from contacting air or water to avoid sealing holes.

[0131] (3) Protective film for positioning marks: Soak the aluminum material treated in step (2) in the toluene solution of γ-chloropropyltrimethylsilane, the concentration is 20wt.%, and the dosage is 1% of ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
pore sizeaaaaaaaaaa
Login to View More

Abstract

The invention provides a preparation method of an alloy electroplating material with the high bonding force. According to the preparation method, a shielding layer at the bottom of an anodic oxidationfilm is removed, an aluminum metal base material is exposed, then a zinc transition layer and a zinc-nickel electroplating layer are sequentially electroplated, and the bonding force of the base material and the plating layer is finally effectively improved.

Description

technical field [0001] The invention relates to a method for preparing a high-binding force coating using anodized aluminum as a base material, which belongs to the field of electrochemically preparing anodized aluminum materials without shielding layers, and is especially suitable for improving the bonding force between aluminum materials and electroplated metals. [0002] technical background [0003] With the rapid development of science and technology and industry, people have more and more stringent requirements on metal properties. Lightweight and high-hardness metal alloy materials are widely used in related fields. Since the output of aluminum in the world is second only to iron, light metal aluminum alloys The material gets a lot of attention. Aluminum and aluminum alloy materials have low hardness, poor wear resistance, and are prone to intergranular corrosion, and a thin oxide film is easy to form on the surface of aluminum under natural conditions, and the film is...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C25D3/22C25D3/56C25D5/18C25D5/20C25D5/44C25D11/10C25D11/16C23G1/22C23G1/12
CPCC23G1/125C23G1/22C25D3/22C25D3/56C25D5/18C25D5/20C25D5/44C25D11/10C25D11/16
Inventor 王永芝
Owner 东莞市原琦五金有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com