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A kind of preparation method of environment-friendly rubber and plastic foam product not containing formamide

A rubber-plastic foaming, environmentally friendly technology, applied in the field of foaming materials, can solve the problems of unfavorable foaming process of foaming materials, affecting the absorption effect of formamide, increasing the amount of foaming agent used, etc., to achieve excellent fire resistance, improve The effect of hardness and porosity improvement

Active Publication Date: 2021-03-30
HEBEI SHENZHOU THERMAL INSULATION BUILDING MATERIAL GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at present, the commonly used chemical foaming agent for NBR-PVC blended foaming materials is AC. Although AC has the advantages of non-toxic, odorless, and large gas generation, its decomposition temperature is high, there is a strong exothermic reaction, and the decomposition rate is too high. Fast, and formamide will be produced during the thermal decomposition of AC. Formamide remains in the foam material after foaming, and formamide is harmful to the human body. Excessive residual formamide will cause PS foam material to cause harm to users. Continuous damage, the existing solution is to add a formamide remover to the foaming material at the same time, and the existing formamide remover is relatively strong alkaline, which is easy to react with azodicarbonamide and affect the absorption of formamide effect, while increasing the amount of foaming agent used, it will also have an adverse effect on the foaming process of the foaming material

Method used

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  • A kind of preparation method of environment-friendly rubber and plastic foam product not containing formamide
  • A kind of preparation method of environment-friendly rubber and plastic foam product not containing formamide
  • A kind of preparation method of environment-friendly rubber and plastic foam product not containing formamide

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preparation example Construction

[0048] In one embodiment of the present invention, the preparation method of the foaming agent composition comprises the following steps: in the aqueous dispersion medium containing the dispersion stabilizer, the mixture of the shell material, the polymerizable monomer for the shell material and the crosslinking agent is suspended and polymerized , thereby manufacturing the above-mentioned blowing agent composition.

[0049] In one embodiment of the present invention, the core also contains caffeic acid amide derivatives shown in formula (I) and cinnamic acid derivatives shown in formula (II),

[0050]

[0051] In the formula, -R is selected from one of the following: -CH 3 , -CH-(CH 3 ) 2 、-CH 2 -CH(CH 3 ) 2 、-CH(CH 3 )-CH 2 -CH 3 、-CH 2 -C 6 h 5 .

[0052] The addition of caffeic acid amide derivatives shown in formula (I) and cinnamic acid derivatives shown in formula (II) can adjust the decomposition temperature and rate of the foam shell material, release g...

Embodiment 1

[0077] A foaming agent composition, comprising a core-shell structure, which has: 100 parts by weight of the core and 3 parts by weight of the shell surrounding the core; wherein,

[0078] The core contains the blowing agent of potassium bicarbonate and 1,2-dinitroguanidine with a weight ratio of 1:1.2, and caffeic acid amide derivatives shown in (I) and cinnamic acid derivatives shown in formula (II),

[0079]

[0080] In formula (I), -R is -CH 3 ; The amount of caffeic acid amide derivatives is 4.2wt% of the amount of whipping agent, the amount of cinnamic acid derivatives is 15.5wt% of the amount of foaming agent; the particle size of potassium bicarbonate is 200-300 mesh;

[0081] The shell was a polymer comprising 63 wt% acrylonitrile and 27 wt% vinylidene chloride monomer.

[0082] The preparation method of above-mentioned whipping agent composition is:

[0083] 1) Mix 210g of 20wt% colloidal silicon dioxide, 9.8g of 50wt% diethanolamine-adipic acid condensation pro...

Embodiment 2

[0087] A foaming agent composition, comprising a core-shell structure, which has: 100 parts by weight of the core and 3 parts by weight of the shell surrounding the core; wherein,

[0088] The core contains the blowing agent of potassium bicarbonate and 1,2-dinitroguanidine with a weight ratio of 1:1.2, and caffeic acid amide derivatives shown in (I) and cinnamic acid derivatives shown in formula (II),

[0089]

[0090] In formula (I), -R is -CH-(CH 3 ) 2 ; The amount of caffeic acid amide derivatives is 4.2wt% of the amount of whipping agent, the amount of cinnamic acid derivatives is 15.5wt% of the amount of foaming agent; the particle size of potassium bicarbonate is 200-300 mesh;

[0091] The shell was a polymer comprising 63 wt% acrylonitrile and 27 wt% vinylidene chloride monomer.

[0092] The preparation method of above-mentioned blowing agent composition is the same as embodiment 1.

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Abstract

The invention provides a method for preparing an environment-friendly rubber and plastic foam product without formamide, which belongs to the technical field of foam materials and comprises the following steps: mixing, mixing nitrile rubber, polyvinyl chloride and a foaming agent composition After adding, after high-temperature mixing, it is processed into a film; compounding: adding a vulcanizing agent to the film, performing secondary compounding, and processing it into a rubber strip; foaming, extruding the rubber strip into shape, and then vulcanizing and foaming Get rubber and plastic foam products. Wherein, the blowing agent composition includes a core-shell structure, which has: a blowing agent core containing bicarbonate and nitro arc; a shell surrounding the core, wherein the softening point of the shell is higher than the temperature at which the core decomposes into gas. The rubber-plastic foamed product prepared by the preparation method of the present invention has good foaming effect, and can obtain a uniform, dense, closed-cell and independent cell structure, so that the rubber-plastic foamed product has low water absorption and thermal conductivity, and is sound-insulating. The index is higher, and it has better heat preservation, waterproof and sound insulation effects.

Description

technical field [0001] The invention belongs to the technical field of foam materials, and in particular relates to a method for preparing formamide-free environment-friendly rubber and plastic foam products. Background technique [0002] Foamed materials have the advantages of low density, light weight, large specific surface area, high specific mechanical properties, and good damping properties. They are widely used in aviation, aerospace, atomic energy, medicine, environmental protection, metallurgy, mechanical construction, electrochemistry, and petrochemical industries. , and gradually developed into an excellent engineering material. The preparation of various foaming materials is inseparable from the use of foaming agents. The properties of foaming agents not only have a very important impact on the performance of foaming materials, but also have a great impact on their processing and molding processes. Therefore, foaming agents The research has become a research hot...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J9/08C08J9/10C08J9/32C08L9/02C08L27/06C08F220/48C08F214/10C08F220/58C08F220/04
CPCC08F220/48C08J9/08C08J9/10C08J9/32C08J2203/04C08J2203/06C08J2203/20C08J2205/052C08J2309/02C08J2427/06C08F214/10C08F220/58C08F220/04
Inventor 高铁强高铁彦高景岐
Owner HEBEI SHENZHOU THERMAL INSULATION BUILDING MATERIAL GRP CO LTD
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