Electrochromism/electricity storage bifunctional material and preparation method and application thereof
A dual-functional material and electrochromic technology, applied in the direction of color-changing fluorescent materials, chemical instruments and methods, semiconductor/solid-state device manufacturing, etc., can solve the problem of less multi-functional materials, achieve fast response, low energy consumption, coloring Efficient effect
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Embodiment 1
[0036] The general structural formula of the electrochromic / electric storage dual-functional material of the present invention is as follows:
[0037]
[0038] In the general formula, for for where R is -OCH 3 or -CH 3 , R 1 for-C(CF 3 ) 2 , -CO, -SO 2 or -O-, R 2 for-OCH 3 、-CH 3 or -CF 3 , n is an integer of 2-200.
[0039] The preparation process of the electrochromic / electric storage dual-functional material is as follows:
[0040] In a three-neck flask, dissolve 0.333g (0.75mmol) dianhydride monomer and 0.04575g (0.15mmol) diamine monomer in an organic solvent, mechanically stir until completely dissolved under the protection of argon, and react for 6 hours;
[0041] Dissolve 0.2145g (0.3mmol) triamine monomer in an organic solvent, slowly add it dropwise to the above reaction solution, and continue to react for 12 hours;
[0042] Add 1mL triethylamine and 3mL acetic anhydride, heat to 80°C and react for 8 hours to obtain a long-chain hyperbranched p...
Embodiment 2
[0047] Using the electrochromic / electric storage dual-functional material prepared in Example 1, an electric storage device can be prepared, including a bottom electrode and a top electrode, a polymer active layer is arranged between the bottom electrode and the top electrode, and the polymer active The layer is the electrochromic / electric storage bifunctional material prepared in Example 1; the bottom electrode, the polymer active layer and the top electrode form a sandwich structure.
[0048] The substrate material for the bottom electrode is glass or a flexible polymer; the flexible polymer is preferably polyethylene terephthalate (PET), polyethylene naphthalate (PEN) or polymethylmethacrylate (PMMA) .
[0049] The conductive layer on the bottom electrode substrate is vapor-depositable metal, metal oxide, nano-silver or conductive polymer; the vapor-depositable metal is preferably one or more of silver, aluminum and copper; the metal oxide is preferably indium oxide Tin, t...
Embodiment 3
[0058] The electrochromic / electric storage dual-functional material prepared in Example 1 can also be used to prepare electrochromic devices, including a bottom transparent conductive electrode and a top transparent conductive electrode, and a polymer electrochromic electrode is arranged between the bottom electrode and the top electrode. The polymer electrochromic layer is the electrochromic / electric storage dual-functional material prepared in Example 1; the bottom electrode, the polymer electrochromic layer and the top electrode form a sandwich structure.
[0059] The base material of the electrodes is glass or a flexible polymer; the flexible polymer is preferably polyethylene terephthalate (PET), polyethylene naphthalate (PEN) or polymethyl methacrylate (PMMA).
[0060] The conductive layer of the electrode is metal oxide, nano-silver or conductive polymer; the metal oxide is preferably indium tin oxide, and the conductive polymer is preferably polypyrrole or polyaniline. ...
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