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Preparation and packaging method of a composite sintered silver preform

A packaging method and pre-forming technology, applied in the direction of cable/conductor manufacturing, semiconductor/solid-state device manufacturing, conductive materials dispersed in non-conductive inorganic materials, etc., can solve the problems of complicated technical process and time-consuming process, and achieve a solution The use process is complex, overcomes time-consuming, and improves the effect of cold and heat shock resistance

Active Publication Date: 2020-11-10
深圳市先进连接科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a composite sintered silver preform and packaging method, comprising, mixing nano-silver particles, micro-silver particles, sintering aids and organic carriers according to a certain ratio to obtain a composite silver paste, wherein the mixed silver paste The composition and mass percentage are: 5-20% of nano silver particles, 40-70% of mixed micron silver particles, 1-10% of sintering aid, 0.1-1% of leveling agent, 0.1-2% of defoamer, mixed organic solvent 10% to 50%, the sum of each component is 100%; the film forming method is spin coating, casting or screen printing and then heating and drying; the packaging method is using a hot press or dynamic embedded hot pressing sintering The equipment interconnects the packaging structure, aiming to solve the problems of the existing low-temperature sintering silver technology, such as complex process and time-consuming process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Embodiment 1 A preparation and packaging method of a composite sintered silver preform, comprising:

[0034] (1) The composite silver paste is obtained by mechanically stirring nano silver particles, micron silver particles, sintering aid and organic carrier. Wherein the average particle diameter of nano-silver particles is 20nm, the surface coating layer is sodium citrate, and the mass fraction is 10%; the average particle diameter of micron silver balls is 500nm, the thickness of micron silver flakes is 20nm, and the maximum radius is 2 μm. The mass ratio is 1:3, and the mass fraction is 50%; the sintering aid is silver citrate, and the mass fraction is 5%; the leveling agent is TEGO ViscoPlus TEGO-3000, and the mass fraction is 0.5%; base siloxane, the mass fraction is 0.5%; the mixed organic solvent is n-propanol and terpineol, the volume ratio of the two is 1:3, and the mass fraction is 34%.

[0035] (2) Coating the obtained composite silver paste on the hard substr...

Embodiment 2

[0040] Embodiment 2 A preparation and packaging method of a composite sintered silver preform, comprising:

[0041] (1) The composite silver paste is obtained by mechanically stirring the nano-silver particles, the micro-silver particles, the sintering aid and the organic carrier. The average particle size of the nano-silver particles is 10 nm, the surface coating layer is sodium dodecyl sulfate, and the mass fraction is 5%; the average particle size of the micro-silver spheres is 800 nm, the thickness of the micro-silver flakes is 50 nm, and the maximum radius is 1 μm. The mass ratio of the two is 3:4, the mass fraction is 70%; the sintering aid is silver glutamate, the mass fraction is 1%; the leveling agent is ELEMENTIS Levaslip432, the mass fraction is 0.1%; the defoaming agent is polyoxygen Propylene glycerol ether, the mass fraction is 0.1%; the mixed organic solvent is n-propanol and ethylene glycol, the volume ratio of the two is 1:1, and the mass fraction is 23.8%.

...

Embodiment 3

[0047] Embodiment 3 A preparation and packaging method of a composite sintered silver preform, comprising:

[0048] (1) The composite silver paste is obtained by mechanically stirring the nano-silver particles, the micro-silver particles, the sintering aid and the organic carrier. The average particle size of the nano-silver particles is 60 nm, the surface coating is polyvinylpyrrolidone, and the mass fraction is 20%; the average particle size of the micro-silver spheres is 300 nm, the thickness of the micro-silver flakes is 30 nm, and the maximum radius is 3 μm. The mass ratio is 1:4, the mass fraction is 40%; the sintering aid is silver phosphate, the mass fraction is 1%; the leveling agent is EFKA-3038, the mass fraction is 1%; the defoamer is tributyl phosphate, the mass fraction The fraction is 2%; the mixed organic solvent is n-propanol and ethylene glycol, the volume ratio of the two is 1:4, and the mass fraction is 36%.

[0049] (2) The obtained composite silver paste...

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Abstract

The invention provides a method for preparing a composite sintered silver preformed sheet and a method for packaging a composite sintered silver preformed sheet. The preparing method comprises the steps of: mixing nanometer silver particles, micron silver particles, a sintering aid and an organic vehicle according to a certain ratio to obtain a composite silver paste, wherein the silver paste comprises the following components: in mass percentage, 5-20% of nanometer silver particles, 40-70% of mixed micron silver particles, 1-10% of sintering aid, 0.1-1% of leveling agent, 0.1-2% of de-foaming agent, 10-50% of mixed organic solvent, with the sum of the components being 100%. A film forming method uses spin coating, casting or screen printing followed by heating and drying. The packaging method comprises interconnecting a packaging structure by a hot press or dynamic embedded hot press sintering device. The composite sintered silver preformed sheet and the packaging scheme can be applied to a large-area power chip package, can solve the long process time and the narrow process window of a conventional unpressurized and pressurized sintering processes. The interconnected solder joints have high temperature resistance, cold and thermal shock resistance, and excellent service stability.

Description

technical field [0001] The invention relates to the field of electronic packaging, and more specifically, to a method for preparing and packaging a composite sintered silver preformed sheet. Background technique [0002] Low-temperature sintered silver technology is currently the most potential solution for power chip packaging. Sintered silver has excellent thermal and electrical conductivity, mechanical properties and service reliability. In addition, due to its small size effect, the material can realize solder joint interconnection at a lower temperature, and the silver structure after sintering has the same melting point (961°C) as bulk silver, which solves the problem of high-temperature solder brazing strips. Thermal mismatch, thermal device damage and other problems. [0003] The typical process of low-temperature sintering silver technology is to print silver paste on the substrate, mount it, and perform pressure-free or pressure-assisted sintering after a specific...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B1/22H01B13/00H01L21/56
CPCH01B1/22H01B13/00H01L21/56
Inventor 杨帆胡博李明雨靳清吴昊
Owner 深圳市先进连接科技有限公司
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