Preparation and packaging method of a composite sintered silver preform
A packaging method and pre-forming technology, applied in the direction of cable/conductor manufacturing, semiconductor/solid-state device manufacturing, conductive materials dispersed in non-conductive inorganic materials, etc., can solve the problems of complicated technical process and time-consuming process, and achieve a solution The use process is complex, overcomes time-consuming, and improves the effect of cold and heat shock resistance
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Embodiment 1
[0033] Embodiment 1 A preparation and packaging method of a composite sintered silver preform, comprising:
[0034] (1) The composite silver paste is obtained by mechanically stirring nano silver particles, micron silver particles, sintering aid and organic carrier. Wherein the average particle diameter of nano-silver particles is 20nm, the surface coating layer is sodium citrate, and the mass fraction is 10%; the average particle diameter of micron silver balls is 500nm, the thickness of micron silver flakes is 20nm, and the maximum radius is 2 μm. The mass ratio is 1:3, and the mass fraction is 50%; the sintering aid is silver citrate, and the mass fraction is 5%; the leveling agent is TEGO ViscoPlus TEGO-3000, and the mass fraction is 0.5%; base siloxane, the mass fraction is 0.5%; the mixed organic solvent is n-propanol and terpineol, the volume ratio of the two is 1:3, and the mass fraction is 34%.
[0035] (2) Coating the obtained composite silver paste on the hard substr...
Embodiment 2
[0040] Embodiment 2 A preparation and packaging method of a composite sintered silver preform, comprising:
[0041] (1) The composite silver paste is obtained by mechanically stirring the nano-silver particles, the micro-silver particles, the sintering aid and the organic carrier. The average particle size of the nano-silver particles is 10 nm, the surface coating layer is sodium dodecyl sulfate, and the mass fraction is 5%; the average particle size of the micro-silver spheres is 800 nm, the thickness of the micro-silver flakes is 50 nm, and the maximum radius is 1 μm. The mass ratio of the two is 3:4, the mass fraction is 70%; the sintering aid is silver glutamate, the mass fraction is 1%; the leveling agent is ELEMENTIS Levaslip432, the mass fraction is 0.1%; the defoaming agent is polyoxygen Propylene glycerol ether, the mass fraction is 0.1%; the mixed organic solvent is n-propanol and ethylene glycol, the volume ratio of the two is 1:1, and the mass fraction is 23.8%.
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Embodiment 3
[0047] Embodiment 3 A preparation and packaging method of a composite sintered silver preform, comprising:
[0048] (1) The composite silver paste is obtained by mechanically stirring the nano-silver particles, the micro-silver particles, the sintering aid and the organic carrier. The average particle size of the nano-silver particles is 60 nm, the surface coating is polyvinylpyrrolidone, and the mass fraction is 20%; the average particle size of the micro-silver spheres is 300 nm, the thickness of the micro-silver flakes is 30 nm, and the maximum radius is 3 μm. The mass ratio is 1:4, the mass fraction is 40%; the sintering aid is silver phosphate, the mass fraction is 1%; the leveling agent is EFKA-3038, the mass fraction is 1%; the defoamer is tributyl phosphate, the mass fraction The fraction is 2%; the mixed organic solvent is n-propanol and ethylene glycol, the volume ratio of the two is 1:4, and the mass fraction is 36%.
[0049] (2) The obtained composite silver paste...
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