Bicontinuous phase micro-emulsion, preparation method thereof, drilling fluid containing micro-emulsion and preparation method thereof
A dual-continuous phase and microemulsion technology is applied to drilling fluid and its preparation, and its preparation, in the field of dual-continuous phase microemulsion, can solve the problems of complicated procedures, increased cost, increased environmental pollution, etc., and achieves good inhibition and easy removal. , Easy to remove oil effect
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Embodiment 1
[0034] Embodiment 1: a kind of double continuous phase microemulsion provided by the present invention, raw material comprises emulsifier, water-soluble acid, oil phase, and water phase, and emulsifier is amine nonionic emulsifier, and water-soluble acid is hydrochloric acid, acetic acid , propionic acid mixture, the oil phase is a mixture of mineral oil and diesel oil, and the water phase is a mixture of seawater, organic salt brine such as ammonium salt;
[0035] The hydrophilic-lipophilic balance value of the amine nonionic emulsifier is 4 to 6, and has the general molecular structure formula shown in Formula 1;
[0036]
[0037] In formula 1, R is a hydrophobic carbon chain with a chain length of C8-C20, containing at least one unsaturated bond, R' is H, C 1 、C 2 or C 3 , A is O or NH, 1≤m+n≤3.
[0038] For example, the emulsifier is an ethoxylated higher fatty alkylamine, which has a general molecular structure formula shown in Formula 2;
[0039]
[0040] In fo...
Embodiment 2
[0048] Embodiment two: a kind of bicontinuous phase microemulsion provided by the present invention, raw material comprises emulsifier, water-soluble acid, oily phase, and water phase, and emulsifier is amine nonionic emulsifier, and water-soluble acid is lactic acid, halogen Acetic acid and glycolic acid are mixed, the oil phase is a mixture of gas oil and synthetic base liquid, the water phase is a mixture of inorganic salt brine such as sodium chloride, and a water phase containing water-soluble organics such as glycerol;
[0049] The hydrophilic-lipophilic balance value of the amine nonionic emulsifier is 4 to 6, and has the general molecular structure formula shown in Formula 1;
[0050]
[0051] In formula 1, R is a hydrophobic carbon chain with a chain length of C8-C20, containing at least one unsaturated bond, R' is H, C 1 、C 2 or C 3 , A is O or NH, 1≤m+n≤3.
[0052] For example, the emulsifier is aliphatic propylene diamine, which has a molecular structure gene...
Embodiment 3
[0061] Embodiment three: a kind of dual continuous phase microemulsion provided by the present invention, raw material comprises emulsifier, water-soluble acid, oil phase and water phase, emulsifier is amine nonionic emulsifier, water-soluble acid is tartaric acid, oil The phase is mineral oil, and the water phase is a mixture of inorganic salt brine such as calcium chloride and sea water;
[0062] The hydrophilic-lipophilic balance value of the amine nonionic emulsifier is 4 to 6, and has the general molecular structure formula shown in Formula 1;
[0063]
[0064] In formula 1, R is a hydrophobic carbon chain with a chain length of C8-C20, containing at least one unsaturated bond, R' is H, C 1 、C 2 or C 3 , A is O or NH, 1≤m+n≤3.
[0065] For example, the emulsifier is an ethoxylated higher fatty alkylamine, which has a general molecular structure formula shown in Formula 2;
[0066]
[0067] In formula 2, R is a hydrophobic carbon chain, containing at least one un...
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