Method for preparing floating flax-like polyester fibers
A polyester fiber, hemp-like technology, applied in the field of polyester fiber, can solve the problems of lack of active groups, high production cost, increased process complexity, etc., to overcome the complex and uncontrollable technology, increase the free volume of voids, and shorten the dyeing process. effect of time
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Embodiment 1
[0057] A kind of preparation method of floating deep hemp-like polyester fiber, its concrete steps are as follows:
[0058] (1) prepare modified polyester;
[0059] (1.1) Preparation of 2,5,6,6-tetramethyl-2,5-heptanediol;
[0060](a) Mix KOH powder, 3-methyl-3-hydroxybutyne, 3,3-dimethyl-2-butanone and isopropyl ether at a molar ratio of 1:1:1.2:2.0, and place in an ice bath Under the conditions of reaction for 2h, cooling crystallization, centrifugation, washing, refining and drying are carried out after the reaction to obtain octyne diol;
[0061] (b) Mix octynediol, ethanol and palladium catalyst in a weight ratio of 2:10:0.01, react at a temperature of 40°C for 50 minutes, continuously feed hydrogen during the reaction, and separate and purify after the reaction to obtain 2,5,6,6-tetramethyl-2,5-heptanediol, the structural formula of 2,5,6,6-tetramethyl-2,5-heptanediol is shown in formula (I);
[0062] (1.2) Esterification reaction;
[0063] Make slurry with terephtha...
Embodiment 2
[0083] A kind of preparation method of floating deep hemp-like polyester fiber, its concrete steps are as follows:
[0084] (1) prepare modified polyester;
[0085] (1.1) Preparation of 2,5,6,6-tetramethyl-2,5-heptanediol;
[0086] (a) Mix KOH powder, 3-methyl-3-hydroxybutyne, 3,3-dimethyl-2-butanone and isopropyl ether at a molar ratio of 1.1:1:1.2:2.3, and place in an ice bath Under the conditions of reaction for 2h, cooling crystallization, centrifugation, washing, refining and drying are carried out after the reaction to obtain octyne diol;
[0087] (b) Mix octynediol, ethanol and palladium catalyst in a weight ratio of 2:10:0.01, react at a temperature of 45°C for 50 minutes, continuously feed hydrogen during the reaction, and separate and purify after the reaction to obtain 2,5,6,6-tetramethyl-2,5-heptanediol, the structural formula of 2,5,6,6-tetramethyl-2,5-heptanediol is shown in formula (I);
[0088] (1.2) Esterification reaction;
[0089] Make slurry with tereph...
Embodiment 3
[0099] A kind of preparation method of floating deep hemp-like polyester fiber, its concrete steps are as follows:
[0100] (1) prepare modified polyester;
[0101] (1.1) Preparation of 2,5,6,6-tetramethyl-2,5-heptanediol;
[0102] (a) Mix KOH powder, 3-methyl-3-hydroxybutyne, 3,3-dimethyl-2-butanone and isopropyl ether at a molar ratio of 1.2:1:1.25:2.0, and place in an ice bath Under the conditions of reaction for 3 hours, after the reaction is completed, cooling and crystallization, centrifugation, washing, refining and drying are carried out to obtain octyne diol;
[0103] (b) Mix octynediol, ethanol and palladium catalyst in a weight ratio of 3:10:0.03, react at 40°C for 50 minutes, continuously feed hydrogen during the reaction, and separate and purify after the reaction to obtain 2,5,6,6-tetramethyl-2,5-heptanediol, the structural formula of 2,5,6,6-tetramethyl-2,5-heptanediol is shown in formula (I);
[0104] (1.2) Esterification reaction;
[0105] Make slurry with...
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