Fiber-reinforced extinction flame-retardant PC/ABS alloy and preparation method thereof

A fiber-reinforced, ABS resin technology, used in the field of plastic alloys, can solve the problems of poor flame retardant performance and high gloss, and achieve the effects of good thermal stability, low gloss and good flame retardant effect.

Active Publication Date: 2019-04-23
苏州市同发塑业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The technical problem to be solved by the present invention is: in order to solve the technical problems of the existing PC / ABS alloy with poor flame retardancy, high gloss, and floating fibers on the product surface, provide a fiber-reinforced extinction flame-retardant PC / ABS alloy and its preparation method

Method used

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  • Fiber-reinforced extinction flame-retardant PC/ABS alloy and preparation method thereof

Examples

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Effect test

Embodiment 1

[0033] This embodiment provides a fiber-reinforced matte flame-retardant PC / ABS alloy, comprising the following components by weight: 45 parts of PC resin, 25 parts of ABS resin, 12 parts of DOPO-based nitrogen-phosphorus flame retardant, and 7 parts of kevlar chopped fiber , 20 parts of calcium silicate powder, 5 parts of silica matting powder, 5 parts of toughening agent, 0.7 part of hyperbranched resin, 0.5 part of antioxidant; the structural formula of the DOPO-based nitrogen and phosphorus flame retardant is as follows:

[0034] The melt index of the PC resin is 20g / 10min (300°C, 1.2kg), the melt index of the ABS resin is 20g / 10min (220°C, 10kg), and the water content of the PC resin and ABS resin is not more than 0.05 wt%; the silica matting powder is Degussa silica matting powder OK412; the calcium silicate powder is calcium silicate powder surface-treated by a silane coupling agent, and the silane coupling agent The structural formula is NH 2 (CH 2 ) 3 Si(OC 2 h ...

Embodiment 2

[0040] This embodiment provides a fiber-reinforced matte flame-retardant PC / ABS alloy, including the following components by weight: 40 parts of PC resin, 20 parts of ABS resin, 10 parts of DOPO-based nitrogen-phosphorus flame retardant, and 5 parts of kevlar chopped fiber , 15 parts of calcium silicate powder, 3 parts of silica matting powder, 3 parts of toughening agent, 0.5 part of hyperbranched resin, 0.2 part of antioxidant; the structural formula of the DOPO-based nitrogen and phosphorus flame retardant is as follows:

[0041] The melt index of the PC resin is 10g / 10min (300°C, 1.2kg), the melt index of the ABS resin is 15g / 10min (220°C, 10kg), and the water content of the PC resin and ABS resin is not more than 0.05 wt%; the silica matting powder is Degussa silica matting powder OK520; the calcium silicate powder is calcium silicate powder surface-treated by a silane coupling agent, the silane coupling agent The structural formula is NH 2 (CH 2 ) 3 Si(OC 2 h 5 ) ...

Embodiment 3

[0047] This embodiment provides a fiber-reinforced matte flame-retardant PC / ABS alloy, including the following components by weight: 50 parts of PC resin, 30 parts of ABS resin, 15 parts of DOPO-based nitrogen-phosphorus flame retardant, and 10 parts of kevlar chopped fiber , 30 parts of calcium silicate powder, 6 parts of silica matting powder, 8 parts of toughening agent, 1 part of hyperbranched resin, and 1 part of antioxidant; the structural formula of the DOPO-based nitrogen-phosphorus flame retardant is as follows:

[0048] The melt index of the PC resin is 25g / 10min (300°C, 1.2kg), the melt index of the ABS resin is 30g / 10min (220°C, 10kg), and the water content of the PC resin and ABS resin is not more than 0.05 wt%; the silica matting powder is Tosoh silica matting powder E-170; the calcium silicate powder is calcium silicate powder surface-treated by a silane coupling agent, and the silane coupling agent The structure is The length of the kevlar chopped fibers is...

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Abstract

The invention relates to a fiber-reinforced extinction flame-retardant PC / ABS alloy and a preparation method thereof. The fiber-reinforced extinction flame-retardant PC / ABS alloy comprises the following components in parts by weight: 40-50 parts of PC resin, 20-30 parts of ABS resin, 10-15 parts of a DOPO-based nitrogen-phosphorus fire retardant, 5-10 parts of Kevlar chopped fibers, 15-30 parts ofcalcium silicate powder, 3-6 parts of silicon dioxide extinction powder, 3-8 parts of a toughening agent, 0.5-1 part of hyperbranched resin, and 0.2-1 part of an antioxidant. The fiber-reinforced extinction flame-retardant PC / ABS alloy is good in mechanical property without a fiber floating phenomenon, good in flame retardant effect, wherein a flame retardant level reaches a level V0, and low inglossiness, and has the apparent matte effect.

Description

technical field [0001] The invention relates to a fiber-reinforced matte flame-retardant PC / ABS alloy and a preparation method thereof, belonging to the technical field of plastic alloys. Background technique [0002] With the sustained and rapid development of my country's economy, the demand potential of my country's plastic alloy market is huge in recent years, especially the rapid growth of electronic communications, automobiles, and construction industries, which will drive the rapid development of my country's engineering plastic alloy industry. However, both research and production of plastic alloys in my country are still in a sporadic and scattered state, and have not yet formed a scale. The overall level of the industry is low, far from the advanced level of foreign countries. my country's plastic alloy research and development and processing technology level needs to be improved. [0003] The PC / ABS plastic alloy obtained by melting blending of PC and ABS can com...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08L55/02C08L77/10C08L51/04C08K13/06C08K9/06C08K3/34C08K3/36C08K5/5313C08J5/04
CPCC08J5/046C08J2369/00C08J2455/02C08J2451/04C08K13/06C08K9/06C08K5/5313C08K3/36C08K3/34C08J2477/10
Inventor 钱秋良朱自成
Owner 苏州市同发塑业有限公司
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