Multi-substituted 6-aryl benzo [a] carbazole, derivatives thereof, synthesizing method of multi-substituted 6-aryl benzo [a] carbazole
An arylbenzene, multi-substitution technology, applied in the field of organic compound synthesis, can solve problems such as complex synthesis steps, achieve the effects of saving raw materials, excellent chemical properties, and reducing environmental pollution
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Embodiment 1-55
[0059] Step 1: 2-arylindole compounds (see Table 1 for specific substances) and aromatic acetylenic compounds or aromatic ketones (see Table 1 for specific substances) are added in the reaction vessel, and iodine-containing compounds (see Table 1 for specific substances) 1) the solution of adding in the reaction vessel also can contain iodine compound (see Table 1 for concrete substance) and organic solvent (see Table 1 for concrete substance) in container respectively;
[0060] Step 2: uniformly heat the reaction vessel (such as oil bath heating) to the temperature described in Table 1, 2-arylindole compound and aromatic alkyne compound or aromatic ketone compound are reacted in a solvent, and continue to show The time described in 1; the reaction that needs to be explained does not require the atmosphere environment to participate in the reaction, so the atmosphere can be air or inert gas, nitrogen, etc. It can be reacted as long as it is not in a strong oxidizing atmosphere...
Embodiment 1
[0070] The nuclear magnetic data of embodiment 1 product is as follows:
[0071] 1 H NMR (400MHz, CDCl 3 , ppm) δ8.87(s, 1H), 8.10-8.08(m, 1H), 7.99-7.96(m, 1H), 7.69-7.67(m, 2H), 7.57-7.50(m, 7H), 7.44( d, J=8.0Hz, 1H), 7.35(t, J=7.6Hz, 1H), 7.04(t, J=7.6Hz, 1H).; 13 C NMR (100MHz, ppm) δ141.2, 138.6, 136.5, 135.2, 132.0, 129.3, 128.8, 128.3, 127.6, 125.6, 125.4, 124.6, 123.8, 122.0, 120.8, 120.3, 120.1, 119.5, 110.9
Embodiment 2
[0072] The nuclear magnetic data of embodiment 2 product is as follows:
[0073] 1 H NMR (400MHz, CDCl 3 , ppm) δ8.83 (s, 1H), 8.09-8.07 (m, 1H), 7.98-7.95 (m, 1H), 7.58 (d, J=7.9 Hz, 2H), 7.54-7.50 (m, 4H) , 7.48(s, 1H), 7.37-7.34(m, 3H), 7.05(t, J=7.6Hz, 1H), 2.50(s, 3H); 13 C NMR (100MHz, CDCl 3 , ppm) δ138.6, 138.2, 137.2, 136.5, 135.2, 132.1, 129.2, 129.0, 128.8, 125.6, 125.3, 124.5, 123.9, 122.1, 120.8, 120.3, 120.1, 119.5, 116.8, 114.8,
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