Rare-earth-based light absorption material and preparation method and application thereof
A light-absorbing material, rare-earth-based technology, applied in the direction of rare-earth metal compounds, chemical instruments and methods, rare-earth metal oxides/hydroxides, etc., to achieve low cost, simple operation, and reduced damage
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Embodiment 1
[0039] The steps of preparing the cerium oxide powder material doped with lanthanum are as follows:
[0040] 1. The rare earth chloride solution is prepared according to a certain mass ratio of the lanthanum and cerium elements, so that the lanthanum elements account for 5% to 15% of the mass of the lanthanum and cerium elements. The prepared rare earth chloride solution is composed of cerium chloride and lanthanum chloride.
[0041] 2. Preparation of rare earth oxalic acid precipitate: Add the prepared saturated oxalic acid solution to the rare earth chloride solution. During the precipitation process, the liquid phase temperature is kept between 20°C and 40°C. After all the rare earth elements in the solution are precipitated , for suction filtration.
[0042] 3. The rare earth oxalate precipitate obtained after suction filtration is sintered at high temperature, the sintering temperature is between 700°C and 950°C, and the sintering time is generally between 1h and 3h.
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Embodiment 2
[0046] Specifically, lanthanum carbonate and cerium carbonate containing crystal water are used as raw materials to prepare a rare earth chloride solution. Firstly, lanthanum carbonate and cerium carbonate were dissolved in 10mol / L concentrated hydrochloric acid, and the concentration of lanthanum and cerium in the lanthanum chloride and cerium chloride solution was determined by EDTA titration.
[0047] Prepare a mixed solution of lanthanum and cerium elements according to the mass ratio of lanthanum and cerium elements of 1:10, add oxalic acid solution to the mixed rare earth chloride solution, and perform suction filtration after all the rare earth elements in the solution are precipitated.
[0048] The precipitate was sintered at 800°C for 2 hours. After sintering, the precipitate taken out is the target product.
[0049] The ultraviolet-visible light absorption spectrum of the cerium oxide doped with lanthanum element prepared in this embodiment and pure cerium oxide is ...
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