Preparation method of orange fruit thinning agent
The technology of a fruit thinning agent and an orange is applied in the preparation field of the orange fruit thinning agent, which can solve the problems of high labor intensity, time-consuming and difficult to produce, and achieves the effects of reducing the hygroscopic performance, reducing the water-absorbing swelling ability, and reducing the release and influence.
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Embodiment 1
[0013] A preparation method for orange fruit thinner, comprising the following steps:
[0014] 1) Preparation of oligomeric chitosan: Add 25 parts of chitosan and 180 parts of deionized water into the reaction vessel, slowly raise the temperature to 65°C within 30 minutes under stirring conditions, and then add 85 parts of mass to the reaction vessel dropwise The fraction is 30% hydrogen peroxide, stop heating after constant temperature reaction for 3 hours, pour the reaction liquid into a beaker, let stand overnight and then filter, the filtrate is precipitated with 80% ethanol solution of 6 times its volume, and then filtered. The cake is washed twice with ethanol with a volume fraction of 95%, dried under vacuum at 56°C, crushed and sieved to obtain chitosan oligosaccharides; the preparation method of chitosan oligosaccharides is simple and easy to control, and its molecular weight is between 2800-3100 Not only the preparation cost is low and the output is high, but also th...
Embodiment 2
[0017] A preparation method for orange fruit thinner, comprising the following steps:
[0018] 1) Add 28 parts of chitosan and 200 parts of deionized water into the reaction vessel, and slowly raise the temperature to 68°C within 40 minutes under stirring conditions. At this time, 88 parts of hydrogen peroxide with a mass fraction of 32% are added dropwise to the reaction vessel. After 3.5 hours of constant temperature reaction, stop heating, pour the reaction solution into a beaker, let it stand overnight and then filter. The filtrate is precipitated with an ethanol solution with a volume fraction of 7 times its volume and is 90% and then filtered. The filter cake is filtered with a volume fraction of 99%. washed with ethanol for 3 times, vacuum-dried at 58°C, and then crushed and sieved to obtain chitosan oligosaccharide; 1.50 parts of 80% naphthalene acetic acid powder, 1.3 parts of dinitroformazan, 0.3 parts of 1-aminocyclopropane hydroxy acid, 0.12 parts of branched chain...
Embodiment 3
[0020] A preparation method for orange fruit thinning agent, comprising: preparing chitosan oligosaccharide, preparing fruit thinning agent, specifically comprising the following steps:
[0021] Preparation of oligomeric chitosan: 26 parts of chitosan and 185 parts of deionized water were added to the reaction vessel, and the temperature was slowly raised to 66° C. within 35 minutes under stirring conditions. At this time, 86 parts of mass fraction was added dropwise to the reaction vessel. 30% hydrogen peroxide, stop heating after constant temperature reaction for 3 hours, pour the reaction solution into a beaker, let stand overnight and then filter, the filtrate is precipitated with 88% ethanol solution of 6 times its volume and then filtered, the filter cake is used The volume fraction of 98% ethanol was washed three times, vacuum dried at 57°C, crushed and sieved to obtain chitosan oligosaccharide; the preparation method of chitosan oligosaccharide was simple and easy to co...
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