Alkaline earth metal-containing hydrated alumina composition and molded body, preparation method and application thereof, catalyst and preparation method thereof

Abstract

The invention discloses an alkaline earth metal-containing hydrated alumina composition and molded body, a preparation method and application thereof, a catalyst and a preparation method thereof. Thecomposition contains hydrated alumina, a compound containing at least two proton acceptor sites and an alkaline earth metal-containing compound. The composition has the phi value of 5 or less shown inthe description. The invention also discloses a catalyst using the molded body of the alkaline earth metal-containing hydrated alumina composition as a carrier and having hydrogenation catalysis effects, a preparation method thereof and a hydrogenation treatment method. The high strength molded body is prepared from hydrated alumina wet gel as a starting raw material so that the hydrated aluminawet gel drying process is avoided. In molded raw material preparation, water for preparation of the molded material from pseudo-boehmite dry glue powder is avoided so that the overall processes are reduced, overall operation energy consumption is reduced, the dust pollution caused by the use of pseudo-boehmite dry glue powder as a raw material is avoided and the working environment is greatly improved.

Description

technical field [0001] The present invention relates to the technical field of alumina molding. Specifically, the present invention relates to a composition of alkaline earth metal-containing hydrated alumina and a preparation method thereof. Aluminum molded body and alumina molded body, the present invention further relates to a catalyst having hydrogenation catalysis using the molded body formed from the alkaline earth metal-containing hydrated alumina composition as a carrier, a preparation method thereof and a method using the catalyst Hydroprocessing method. Background technique [0002] In traditional methods, alumina shaped bodies, especially γ-alumina shaped bodies, are often used as adsorbents or supported catalysts because of their good pore structure, suitable specific surface area and high heat resistance stability. carrier used. This kind of alumina is usually obtained from dried hydrated alumina, such as pseudo-boehmite, which is shaped, dried, and then calci...

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Problems solved by technology

[0014] (1) Pseudo-boehmite that has not been completely dried has strong viscosity, is difficult to transfer, and easily causes secondary dust pollution;

[0015] (2) Drying starts from the surface. The drying of the wet solid product separated from the mixture obtained from the gelling reaction is incomplete drying, so there is a sandwich biscuit phenomenon, that is, the surface of part of the pseudo-boehmite is dried (that is, the dried surface is substantially free of free water), while the interior is still wet (that is, for the non-dried interior, the content of free water is basically maintained at the level before drying), since the surface is dried, Therefore, hard particles are formed. When peptizing agent and / or binder are added to this incompletely dried pseudo-boehmite and kneaded, the hard particles formed during the drying process are in the process of extrusion. It is easy to cause blockage and affect production efficiency;

[0016] (3) It is difficult to stably control the dry base of pseudo-boehmite. The instability of the dry base will cause great interference to the molding process, making the molding process very unstable, resulting in an increase in the amount of unqualified products and low production efficiency;

[0017] (4) CN103769118A adopts a conventional molding process when molding, yet because the dry basis (35%-50%) of the pseudo-boehmite it adopts is far lower than the conventional dry basis content (about 70%), that is The water content is high, and there is basically no extrusion pressure during the extrusion molding process. Therefore, the carrier obtained after the extrudate is dried and roasted has basically no mechanical strength. As long as a little external force is applied, it will be pulverized and has no possibility of industrial application. sex, which is the biggest problem facing the technology

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