Clean production process for treating organic waste mother solution by renewable targeted adsorption
A technology of adsorption treatment and clean production, applied in the direction of adsorption water/sewage treatment, special treatment targets, water/sewage treatment, etc., can solve the problems of long treatment cycle, waste of resources, large energy consumption, etc. , save treatment cost, reduce pollution effect
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Embodiment 1
[0031] In this embodiment, a method of regenerable targeted adsorption treatment of organic waste mother liquor is applied to the clean production of bronopol waste crystallization mother liquor, including the following steps:
[0032] (1) One-step method prepares the discharge waste liquid of bronopol, and color is light yellow, and specific gravity is 1.25~1.35g / cm 3 . The waste liquid is sent to the distillation tower for distillation, concentration and crystallization, and the bronopol waste crystallization mother liquor obtained is sent to a regenerative targeted adsorption fixed bed device for targeted adsorption;
[0033] (2) Collect the flow-through liquid after being adsorbed by the renewable targeted adsorption fixed bed device and send it into the distillation tower, and distill and crystallize to obtain the finished product of sodium bromide, and the residual liquid at the bottom of the still is used as The crystallization mother liquor of hydroxymethylnitromethan...
Embodiment 2
[0041] In this embodiment, a method of regenerable targeted adsorption treatment of organic waste mother liquor is applied to the clean production of bronopol waste crystallization mother liquor, including the following steps:
[0042] (1) Two-step method prepares the discharge waste liquid of bronopol, and the color is brownish yellow, and specific gravity is 1.15~1.25g / cm 3 . Send the waste crystallization mother liquor to the renewable targeted adsorption fixed bed device for targeted adsorption;
[0043] (2) Collect the flow-through liquid after being adsorbed by the renewable targeted adsorption fixed bed device and send it into the distillation tower, and distill and crystallize to obtain the finished product of sodium bromide, and the residual liquid at the bottom of the still is used as The crystallization mother liquor of hydroxymethylnitromethane is returned to the synthesis process for reuse, and the gas phase is condensed to obtain condensed water, which is discha...
Embodiment 3
[0051] In this example, a method of regenerable targeted adsorption treatment of organic waste mother liquor is applied to the clean production of membrane separation mother liquor for treating caprolactam production wastewater, including the following steps:
[0052] (1) The organic waste water produced in the production process of caprolactam is prepared by the toluene method, and the membrane separation treatment is carried out through the reverse osmosis membrane separation device, and the waste water containing caprolactam, toluene, acetic acid and other impurities (a small amount of benzoic acid, hexahydrobenzoic acid, nitric acid) Base terephthalic acid) mother liquor is sent to the regenerative targeted adsorption fixed bed device for targeted adsorption;
[0053] (2) Return the flow-through liquid with low-concentration inorganic salts after being adsorbed by the regenerable targeted adsorption fixed-bed device to the reverse osmosis membrane separation device for reus...
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