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Wear-resistant zirconium-aluminum composite ball and preparation method thereof

A technology of wear-resistant zirconium aluminum and composite balls, which is applied in the field of grinding media, can solve the problems of high cost, high firing temperature, and low cost, and achieve the effects of increasing toughness and strength, stable chemical properties, and reducing environmental pressure

Inactive Publication Date: 2017-10-03
山东中和金石科技集团股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Ceramic wear-resistant balls in the prior art are generally made of two raw materials, alumina powder and bauxite. Ultrafine powder is prepared by wet ball milling and spray granulation, and then formed by cold isostatic pressing under a pressure of 35-40 MPa. , and finally through high-temperature firing to prepare alumina grinding balls. The aluminum content of alumina products reaches more than 90%, and the products are at a higher level. However, this process has disadvantages such as high cost, high firing temperature, and high energy consumption; The content is low, generally around 70%. It is a low-grade wear-resistant medium. It is generally used for the grinding of ceramic blanks. The cost is low, but it has the disadvantages of yellow color, low specific gravity, large wear, and cannot be used for the grinding of glazes.

Method used

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  • Wear-resistant zirconium-aluminum composite ball and preparation method thereof
  • Wear-resistant zirconium-aluminum composite ball and preparation method thereof
  • Wear-resistant zirconium-aluminum composite ball and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] (1) Grinding: 3000kg of aluminum hydroxide balls, 2700kg of alumina powder, 300kg of zirconia, 7350kg of waste ceramic rollers, 750kg of kaolin, 450kg of dolomite, 300kg of calcined talc, 225kg of barium carbonate, 7500kg of water, and 25kg of citric acid. 1. Put water into the ball mill and grind for 25 hours until the particle size is D90<10μm. Put the mud into the primary mud pool. After the primary mud is fully stirred, put it into the secondary mill and grind until D90<5.5μm, PVA30kg, water 300kg The proportion of boiling without suspended solids, adding ball mill grinding for 1.5 hours, adding dispersant 40kg, continue grinding for 15 minutes and put it into the secondary mud pool;

[0039] (2) Milling: beat the secondary mud into the servo tank, stir and mix the mud, use the plunger pump to pump the mud into the spray tower for granulation, control the water content to less than 1%, and make granulated powder with a particle size of 0.1-0.5 ;

[0040] (3) Compre...

Embodiment 2

[0046] (1) Grinding: 20kg of aluminum hydroxide balls, 20kg of alumina powder, 2kg of zirconia, 45kg of waste ceramic rollers, 6kg of kaolin, 3kg of dolomite, 2kg of calcined talc, 2kg of barium carbonate, 0.16kg of citric acid, and 50kg of water. Put the raw materials and water into the ball mill and grind for 25 hours until the particle size is D90<10μm. Put the mud into the primary mud pool. After the primary mud is fully stirred, put it into the secondary mill and grind until D90<5.5μm, PVA0.2kg , the proportion of water 2kg boiled without suspended solids, added ball mill to grind for 1.5 hours, added dispersant 0.2kg, continued to grind for 15 minutes and then put it into the secondary mud pool;

[0047] (2) Milling: beat the secondary mud into the servo tank, stir and mix the mud, use the plunger pump to pump the mud into the spray tower for granulation, control the water content to less than 1%, and make granulated powder with a particle size of 0.1-0.5 ;

[0048] (3)...

Embodiment 3

[0053] (1) Grinding: 30kg of aluminum hydroxide balls, 10kg of alumina powder, 2kg of zirconia, 49kg of waste ceramic rollers, 4kg of kaolin, 2kg of dolomite, 1kg of calcined talc, 1kg of barium carbonate, 0.1kg of citric acid, 1.2kg of water, Put the raw materials and water into the ball mill and grind for 25 hours until the particle size is D90<10μm. Put the mud into the primary mud pool. After the primary mud is fully stirred, put it into the secondary mill and grind until D90<5.5μm, PVA0. 2kg, 2kg of water to cook without suspended solids, add ball mill to grind for 1.5 hours, add 0.1kg of dispersant, continue grinding for 15 minutes, and then put it into the secondary mud pool;

[0054] (2) Milling: beat the secondary mud into the servo tank, stir and mix the mud, use the plunger pump to pump the mud into the spray tower for granulation, control the water content to less than 1%, and make granulated powder with a particle size of 0.1-0.5 ;

[0055] (3) Compression moldin...

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Abstract

The invention belongs to the technical field of grinding media, and particularly provides a wear-resistant zirconium-aluminum composite ball and a preparation method thereof. The wear-resistant zirconium-aluminum composite ball is composed of the following components in parts by weight: 20-30 parts of aluminum hydroxide ball, 4-6 parts of kaolin, 1-2 parts of calcined talcum, 45-50 parts of waste ceramic roller, 2-3 parts of dolomite, 1-2 parts of barium carbonate, 10-20 parts of aluminum oxide powder, 0.1-0.2 part of adhesive, 0.1-0.2 part of dispersant, 2-3 parts of zirconium oxide and 0.1-0.2 part of citric acid. The invention also provides a preparation technique of the wear-resistant zirconium-aluminum composite ball. The prepared wear-resistant zirconium-aluminum composite ball has the advantages of high density, high wear resistance and stable chemical properties.

Description

technical field [0001] The invention belongs to the technical field of grinding media, and in particular relates to a wear-resistant zirconium-aluminum composite ball and a preparation method thereof. Background technique [0002] Due to its high strength, high hardness, wear resistance and corrosion resistance, grinding media balls are widely used as grinding media in ceramics, electronics, building materials, new materials and other fields. Ceramic wear-resistant balls in the prior art are generally made of two raw materials, alumina powder and bauxite. Ultrafine powder is prepared by wet ball milling and spray granulation, and then formed by cold isostatic pressing under a pressure of 35-40 MPa. , and finally through high-temperature firing to prepare alumina grinding balls. The aluminum content of alumina products reaches more than 90%, and the products are at a higher level. However, this process has disadvantages such as high cost, high firing temperature, and high ene...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/10C04B35/64C04B33/132
CPCC04B33/1324C04B35/10C04B35/64C04B2235/3206C04B2235/3208C04B2235/3244C04B2235/3418C04B2235/77C04B2235/96Y02P40/60
Inventor 王超
Owner 山东中和金石科技集团股份有限公司
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