Water-based rust transfer primer applicable to rusted steel surface and its preparation method
A primer and water-based technology, applied in anti-corrosion coatings, coatings, etc., can solve the problems of poor environmental friendliness, and achieve the effects of avoiding resin dechlorination and decomposition, improving shear stability, and small particle size
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Embodiment 1
[0029] (1) Preparation of vinylidene chloride-acrylonitrile-acrylic acid ester multiple copolymerization emulsion: the vinylidene chloride of 75 mass parts, the acrylonitrile of 5 mass parts, the acrylic acid of 2.5 mass parts, the isooctyl acrylate of 15 mass parts , the mixed surfactant of 4 mass parts (the mixture of nonylphenol polyoxyethylene base ether, methacryloyloxyethyltrimethylammonium chloride and cetyltrimethylammonium bromide, the mixture of the three The ratio is 1:1.5:1), and 100 parts by mass of water are stirred to make a monomer pre-emulsion. Take 1 / 5 of the above-mentioned mixed monomer pre-emulsion and put it into the reactor protected by nitrogen, and raise the temperature to 60°C. 0.6 parts by mass of azobisisobutylamidine hydrochloride initiator was formulated into a 10% aqueous solution, and 1 / 5 of the aqueous initiator solution was added to the reactor, and stirred for 1 hour of polymerization. The remaining mixed monomer pre-emulsion and initiator a...
Embodiment 2
[0033] (1) Preparation of vinylidene chloride-acrylonitrile-acrylate multi-component copolymer emulsion: same as Example 1.
[0034] (2) Preparation of aqueous dispersion of phosphate-modified polyacrylate: same as in Example 1.
[0035] (3) Preparation of water-based rust transfer primer: Add 0.8 parts by mass of Digao Dispers 757W wetting and dispersing agent, 0.2 parts by mass of Degussa AEROSIL 200 fumed silica, 7 parts by mass into water of 11 parts by mass under stirring. Parts by mass of iron oxide black pigment, 12 parts by mass of precipitated barium sulfate, 5 parts by mass of sericite, and 0.05 parts by mass of Dego Foamex810 defoamer were stirred and dispersed until uniform without agglomeration to obtain a slurry. Subsequently, use a sand mill to grind until the slurry fineness is less than 40 μm. Add 30 mass parts of vinylidene chloride-acrylonitrile-acrylic acid ester multi-copolymer emulsion, 30 mass parts of phosphoric acid ester modified polyacrylate aqueous...
Embodiment 3
[0044] (1) Preparation of vinylidene chloride-acrylonitrile-acrylic acid ester multiple copolymerization emulsion: the n-butyl acrylate of the vinylidene chloride of 60 mass parts, the acrylonitrile of 8 mass parts, the acrylic acid of 3 mass parts, 10 mass parts , the mixed surfactant of 3 mass parts (the mixture of nonylphenol polyoxyethylene base ether, methacryloyloxyethyltrimethylammonium chloride and cetyltrimethylammonium bromide, the mixture of the three The ratio is 1:1.5:1), and 100 parts by mass of water are stirred to make a monomer pre-emulsion. Take 1 / 5 of the above-mentioned mixed monomer pre-emulsion and put it into the reactor protected by nitrogen, and raise the temperature to 60°C. 0.4 parts by mass of azobisisobutylamidine hydrochloride initiator was formulated into a 10% aqueous solution, and 1 / 5 of the aqueous initiator solution was added to the reactor, and stirred for 1 hour of polymerization. The remaining mixed monomer pre-emulsion and initiator aque...
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