Multielement-enhanced heat-resistant corrosion-resistant magnesium alloy and manufacturing method thereof

A manufacturing method and magnesium alloy technology, applied in the field of heat-resistant and corrosion-resistant magnesium alloys, heat-resistant and corrosion-resistant magnesium alloys, can solve the problems of poor corrosion resistance of heat-resistant magnesium alloys, etc., to improve creep resistance and plasticity , Improve the effect of precipitation strengthening, improve the effect of mechanical and corrosion resistance

Active Publication Date: 2017-08-22
YANGZHOU FENG MING METAL PROD +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The primary purpose of the present invention is to solve the problems in the prior art that it is necessary to add a relatively high content of Gd or Y elements in the magnesium alloy to obtain a better strengthening effect, and the problem of poor corrosion resistance of the heat-resistant magnesium alloy, and to provide a Multi-component reinforced heat-resistant and corrosion-resistant magnesium alloy with low manufacturing cost and superior performance

Method used

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  • Multielement-enhanced heat-resistant corrosion-resistant magnesium alloy and manufacturing method thereof
  • Multielement-enhanced heat-resistant corrosion-resistant magnesium alloy and manufacturing method thereof
  • Multielement-enhanced heat-resistant corrosion-resistant magnesium alloy and manufacturing method thereof

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Embodiment 1

[0027] The manufacture method of the multi-component reinforced heat-resistant and corrosion-resistant magnesium alloy of the present invention comprises the following steps in turn: (1) preparing ingredients: comprising pure magnesium ingot, pure zinc ingot, Mg-Gd alloy, Mg-Y alloy, Mg-Nd alloy, Mg- Ca alloy, Mg-Zr alloy and nano-scale NdN particles, the mass percentage content of each element in the raw material is as follows, Gd: 3.5%, Y: 1.0%, Nd: 0.5%, Zn: 0.8%, Ca: 0.3%, Zr : 0.3%, nano-scale NdN particles: 0.5%, the balance is Mg, wherein the mass percentages of the three rare earth elements Gd, Y and Nd are Gd>Y>Nd in descending order, and Gd, Y and Nd The mass fraction of the total addition of the three rare earth elements does not exceed 10%, and the particle size of the nanoscale NdN particles is 80nm.

[0028] (2) Pretreatment and coating of nano-scale NdN particles: Soak nano-scale NdN particles in a mixed acid solution made of hydrofluoric acid, hydrochloric acid...

Embodiment 2

[0040] The manufacture method of the multi-component reinforced heat-resistant and corrosion-resistant magnesium alloy of the present invention comprises the following steps in turn: (1) preparing ingredients: comprising pure magnesium ingot, pure zinc ingot, Mg-Gd alloy, Mg-Y alloy, Mg-Nd alloy, Mg- Ca alloy, Mg-Zr alloy and nano-scale NdN particles, the mass percentage content of each element in the raw material is as follows, Gd: 4.2%, Y: 2.0%, Nd: 0.7%, Zn: 1.2%, Ca: 0.5%, Zr : 0.4%, nanoscale NdN particles: 1.0%, and the balance is Mg, in which the mass percentages of the three rare earth elements Gd, Y, and Nd are in the order of Gd>Y>Nd, and Gd, Y, and Nd The mass fraction of the total addition of the three rare earth elements does not exceed 10%, and the particle size of the nanoscale NdN particles is 120 nm.

[0041] (2) Pretreatment and coating of nano-scale NdN particles: Soak nano-scale NdN particles in a mixed acid solution prepared by hydrofluoric acid, hydrochlo...

Embodiment 3

[0053] The manufacture method of the multi-component reinforced heat-resistant and corrosion-resistant magnesium alloy of the present invention comprises the following steps in turn: (1) preparing ingredients: comprising pure magnesium ingot, pure zinc ingot, Mg-Gd alloy, Mg-Y alloy, Mg-Nd alloy, Mg- Ca alloy, Mg-Zr alloy and nano-scale NdN particles, the mass percentage content of each element in the raw material is as follows, Gd: 5.0%, Y: 3.0%, Nd: 0.8%, Zn: 1.5%, Ca: 0.8%, Zr : 0.6%, nano-scale NdN particles: 1.5%, the balance is Mg, wherein the mass percentage content of the three rare earth elements Gd, Y and Nd is Gd>Y>Nd in descending order, and Gd, Y and Nd The mass fraction of the total addition of the three rare earth elements does not exceed 10%, and the particle size of the nanoscale NdN particles is 150 nm.

[0054] (2) Pretreatment and coating of nano-scale NdN particles: Soak nano-scale NdN particles in a mixed acid solution prepared by hydrofluoric acid, hydro...

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Abstract

The invention discloses a multielement-enhanced heat-resistant corrosion-resistant magnesium alloy and a manufacturing method of the multielement-enhanced heat-resistant corrosion-resistant magnesium alloy. The ingredients of the multielement-enhanced heat-resistant corrosion-resistant magnesium alloy comprise pure magnesium ingots, pure zinc ingots, Mg-Gd alloy, Mg-Y alloy, Mg-Nd alloy, Mg-Ca alloy, Mg-Zr alloy and nanometer-scale NdN particles. The elements in the raw materials comprise, by mass, 3.5-5.0% of Gd, 1.0%-3.0% of Y, 0.5%-0.8% of Nd, 0.8%-1.5% of Zn, 0.3%-0.8% of Ca, 0.3%-0.6% of Zr, 0.5%-1.5% of nanometer-scale NdN particles and the balance Mg. The sequence of the mass percentage contents of the three rare earth elements of the Gd, the Y and the Nd from large to small is Gd>Y>Nd, and the mass percentage of the total addition amount of the three rare earth elements of the Gd, the Y and the Nd does not exceed 10%. The particle size of the nanometer-scale NdN particles is 80-150 nm. The steps of pretreatment and cladding of the NdN particles, preheating of the ingredients, smelting, refining, doping, pouring, sectioned solution treatment and artificial aging treatment are sequentially conducted, and then the fine, dispersive nanometer-precipitated-phase microscopic-structure heat-resistant corrosion-resistant magnesium alloy product is obtained. By the adoption of the multielement-enhanced heat-resistant corrosion-resistant magnesium alloy and the manufacturing method of the multielement-enhanced heat-resistant corrosion-resistant magnesium alloy, the manufacturing cost is low, and the heat resistance and corrosion resistance of the magnesium alloy are excellent.

Description

technical field [0001] The invention relates to a magnesium alloy, in particular to a multi-component reinforced heat-resistant and corrosion-resistant magnesium alloy. The invention also relates to a manufacturing method of the multi-component reinforced heat-resistant and corrosion-resistant magnesium alloy. Background technique [0002] Magnesium alloys have the advantages of low density, high specific strength and specific stiffness, good shock absorption, casting performance, machinability and regeneration, and are considered to be "green engineering materials in the 21st century". Transportation and other fields have broad application prospects. However, at present, most Mg-Al alloys begin to soften and coarsen when they exceed 120 °C, and their mechanical properties are greatly reduced, which cannot meet the requirements for long-term use at higher temperatures; in addition, the corrosion potential of magnesium alloys is low. Easy to corrode, poor heat resistance an...

Claims

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Application Information

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IPC IPC(8): C22C23/06C22C32/00C22C1/10C22F1/06C22F1/02C22C1/06
CPCC22C1/06C22C1/1005C22C1/1036C22C23/06C22C32/0068C22F1/02C22F1/06C22C1/1073
Inventor 章晓波戴建伟眭怀明陈冬梅巴志新王章忠
Owner YANGZHOU FENG MING METAL PROD
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