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A preparation method of activated carbon catalyst for flue gas desulfurization and denitrification

A desulfurization and denitrification, activated carbon technology, applied in the direction of catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of high price, no mention of desulfurization efficiency, complicated preparation methods, etc., and achieve good removal rate Effect

Active Publication Date: 2019-07-16
山东金瑞达环保科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The preparation method of the above-mentioned carbon-based desulfurizer is relatively complicated, requiring more raw material components, and it does not mention whether the prepared catalyst also has the ability to remove nitrogen oxides
[0008] Patent CN102527369A discloses an activated carbon-supported rare earth metal oxide reduction denitration catalyst. The catalyst uses activated carbon as a denitration catalyst carrier, and uses rare earth metal cerium, or a dual component of lanthanum and cerium as a catalytic active component, to reduce nitrogen oxides. It has high denitrification efficiency, but the catalyst uses rare earth metals with high price as the catalyst active component, and it does not mention whether it also has good desulfurization efficiency

Method used

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  • A preparation method of activated carbon catalyst for flue gas desulfurization and denitrification
  • A preparation method of activated carbon catalyst for flue gas desulfurization and denitrification
  • A preparation method of activated carbon catalyst for flue gas desulfurization and denitrification

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Experimental program
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Effect test

Embodiment 1

[0025] Supported Cu-doped TiO 2 Preparation of activated carbon catalyst:

[0026] (1) Dissolve 10ml of tetrabutyl titanate in 35ml of absolute ethanol, stir magnetically for 10min, and mix well to form a yellow clear solution A. Add 1.1g of copper nitrate, 10ml of distilled water and 4ml of glacial acetic acid into 35ml of absolute ethanol, and stir vigorously To obtain solution B, slowly add solution B to solution A at a rate of 3ml / min, continue to stir for 30 minutes after the addition, heat in a water bath at 40°C for 2 hours to obtain a gel, and place it in a muffle furnace for drying at 80°C Dry for 20 hours to obtain a xerogel, grind it into a fine powder in an agate mortar, and calcinate the fine powder at 500°C for 1 hour to obtain Cu-doped TiO 2 Powder;

[0027] (2) Activated carbon supported Cu doped TiO 2 : Take the 5g Cu-doped TiO obtained in step (1) 2 Add the powder, 2ml of tetraethyl orthosilicate and 1ml of polyethylene glycol to 20ml of water to obtain a...

Embodiment 2

[0031] Supported Cu-doped TiO 2 Preparation of activated carbon catalyst:

[0032] (1) Dissolve 10ml of tetrabutyl titanate in 35ml of absolute ethanol, stir magnetically for 10min, and mix well to form a yellow clear solution A. Add 2.66g of copper nitrate, 10ml of distilled water and 4ml of glacial acetic acid into 35ml of absolute ethanol, and stir vigorously To obtain solution B, slowly add solution B to solution A at a rate of 3ml / min, continue to stir for 30 minutes after the addition, heat in a water bath at 40°C for 2 hours to obtain a gel, and place it in a muffle furnace for drying at 80°C Dry for 24 hours to obtain a xerogel, grind it into a fine powder in an agate mortar, and calcinate the fine powder at 800°C for 1.5 hours to obtain Cu-doped TiO 2 .

[0033] (2) TiO doped with Cu supported on activated carbon 2 : Take the 5g Cu-doped TiO obtained in step (1) 2 Powder, add it with 2ml tetraethyl orthosilicate and 1ml polyethylene glycol into 20ml water, soak ac...

Embodiment 3

[0037] Supported Cu-doped TiO 2 Preparation of activated carbon catalyst:

[0038] (1) Dissolve 10ml of tetrabutyl titanate in 35ml of absolute ethanol, stir magnetically for 10min, and mix well to form a yellow clear solution A. Add 1.35g of copper chloride, 10ml of distilled water and 4ml of glacial acetic acid into 35ml of absolute ethanol, and vigorously Stir to obtain solution B, slowly add solution B to solution A dropwise at a rate of 3ml / min, continue stirring for 30min after the dropwise addition, heat in a water bath at 40°C for 2h to obtain a gel, and place it in a muffle furnace at 80°C Dry for 20 hours to obtain xerogel, grind it into a fine powder in an agate mortar, and calcinate the fine powder at 600°C for 1 hour to obtain Cu-doped TiO 2 .

[0039] (2) TiO doped with Cu supported on activated carbon 2 : Take the 5g Cu-doped TiO obtained in step (1) 2 powder, add it with 2ml tetraethyl orthosilicate and 1ml polyethylene glycol to 20ml water to obtain a solu...

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Abstract

The invention discloses a preparation method of an activated carbon catalyst for flue gas desulfurization and denitrification, and belongs to the technical field of flue gas treatment. The activated carbon catalyst preparation method includes the following steps: (1) TiO 2 Doping Cu: Add copper salt to the titanium alkoxide solution, heat it in a water bath to form a gel, dry the gel and then grind and sinter it to obtain Cu-doped TiO 2 Powder; (2) Activated carbon supported Cu doped TiO 2 : Cu doped TiO 2 Add the powder, dispersant and binder to water, immerse activated carbon in it, vibrate with ultrasonic, dry and heat up to 400-450°C at a rate of 3-6°C / min, keep warm, and cool to obtain loaded Cu-doped TiO 2 of activated carbon catalyst. The desulfurization and denitrification rates of the obtained catalyst reached more than 93.2% and 88.7% respectively. After regeneration treatment, the regeneration desulfurization and denitrification rates reached more than 88.4% and 83.8%, and the obtained catalyst did not have any toxicity.

Description

technical field [0001] The invention belongs to the technical field of flue gas treatment, and specifically relates to a catalyst for flue gas desulfurization and denitrification, in particular to a method for preparing an activated carbon catalyst for flue gas desulfurization and denitrification. Background technique [0002] The flue gas emitted by coal boilers and thermal power plants contains various harmful components such as sulfur dioxide, nitrogen oxides, and dust, which pose a serious threat to my country's natural resources, ecosystems, and public health. Therefore, the corresponding environmental protection regulations require their emissions Getting stricter. [0003] Flue gas pollutant emission control technology is mainly to reduce SO in industrial flue gas 2 and NO X In order to reduce the damage to the environment caused by the pollutants emitted by industrial development, in the emission control technology of flue gas pollutants, SO 2 The removal technolog...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/72B01J35/02B01J37/02B01J37/08B01D53/86B01D53/60B01J35/00
CPCB01D53/8637B01J23/72B01J37/0201B01J37/08B01D2258/0283B01J35/00B01J35/30
Inventor 胡登卫张新利
Owner 山东金瑞达环保科技股份有限公司
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