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Enhanced fully biodegradable material and preparation method thereof

A degradable material and all-biological technology, which is applied in the field of enhanced fully biodegradable materials and their preparation, can solve the problems of low tensile strength and elongation, and achieve high tensile strength and elongation, high elongation, and low The effect of production costs

Active Publication Date: 2017-06-23
LANZHOU XINYINHUAN RUBBER & PLASTIC PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although this type of biodegradable has good physical and mechanical properties, compared with films made of ordinary polyethylene materials of the same thickness, its tensile strength and elongation are relatively small; in order to meet different actual needs, people The method of increasing the thickness of degradable materials is generally used to improve its mechanical properties

Method used

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  • Enhanced fully biodegradable material and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0032] The invention provides a fully biodegradable material. The raw material components include 68.5 parts by weight of polybutylene adipate terephthalate, 29 parts by weight of polylactic acid 6201D, and hydroxylated carbon nanotubes with a length of 30 nm. 0.5 parts by weight, 1 part by weight of vinyltriethoxysilane, and 1 part by weight of isopropyltris(dioctylpyrophosphate acyloxy) titanate.

[0033] According to the above-mentioned raw material components, adopt the preparation method of the composite fully degradable material provided by the present invention to prepare the composite fully degradable material:

[0034] S101: Dry polybutylene adipate terephthalate and polylactic acid for 100 min under the conditions of a vacuum degree of 0.08 MPa and a temperature of 55° C.

[0035]S102: Combine hydroxylated carbon nanotubes, vinyl triethoxysilane, isopropyl tris(dioctyl pyrophosphate acyloxy) titanate with dried polybutylene adipate terephthalate The mixing time is 1...

Embodiment 2

[0038] The invention provides a fully biodegradable material. The raw material components include 65 parts by weight of polybutylene adipate terephthalate, 27 parts by weight of polylactic acid 4032D, and hydroxylated carbon nanotubes with a length of 50 nm. 1 part by weight, 5 parts by weight of vinyl triethoxysilane, and 2 parts by weight of isopropyl tris(dioctyl pyrophosphate acyloxy) titanate.

[0039] According to the above-mentioned raw material components, adopt the preparation method of the composite fully degradable material provided by the present invention to prepare the composite fully degradable material:

[0040] S101: Dry polybutylene adipate terephthalate and polylactic acid for 200 minutes under the conditions of a vacuum degree of 0.06 MPa and a temperature of 65° C.

[0041] S102: Combine hydroxylated carbon nanotubes, vinyl triethoxysilane, isopropyl tris(dioctyl pyrophosphate acyloxy) titanate with dried polybutylene adipate terephthalate The mixing time...

Embodiment 3

[0044] The invention provides a fully biodegradable material. The raw material components include 65 parts by weight of polybutylene adipate terephthalate, 26 parts by weight of polylactic acid 3251D, and hydroxylated carbon nanotubes with a length of 40 nm. 1 part by weight, 5 parts by weight of vinyltriethoxysilane, and 3 parts by weight of isopropyltris(dioctylpyrophosphate acyloxy) titanate.

[0045] According to the above-mentioned raw material components, adopt the preparation method of the composite fully degradable material provided by the present invention to prepare the composite fully degradable material:

[0046] S101: Dry polybutylene adipate terephthalate and polylactic acid for 300 min under the conditions of a vacuum degree of 0.07 MPa and a temperature of 60° C.

[0047] S102: Combine hydroxylated carbon nanotubes, vinyl triethoxysilane, isopropyl tris(dioctyl pyrophosphate acyloxy) titanate with dried polybutylene adipate terephthalate In a high-speed mixer ...

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Abstract

The invention relates to an enhanced fully biodegradable material and a preparation method thereof. The enhanced fully biodegradable material is prepared from the following raw materials in parts by weight: 61-69.5 parts of polyhexamethylene terephthalate, 27-30 polylactic acid, 0.5-1 part of a carbon nano tube and 2-8 parts of a coupling reagent. According to the fully biodegradable material, through adding a proper amount of the carbon nano tube, a prepared fully biodegradable material has excellent mechanical properties, and is good in film-forming property; a prepared film has high tensile strength and high elongation rate; compared with a film prepared from a common fully biodegradable material, the tensile strength and the elongation rate of the film prepared from the fully biodegradable material provided by the invention can be improved by over 50%. In addition, the fully biodegradable material can be quickly degraded into carbon dioxide, water, humus and the like, and does not cause pollution to the environment.

Description

technical field [0001] The invention relates to the technical field of degradable materials, in particular to an enhanced fully biodegradable material and a preparation method thereof. Background technique [0002] As a cheap and high-quality material, plastic is widely used in packaging materials and disposable products. However, the long-term use of plastic products in large quantities has seriously polluted the environment and caused severe white pollution. As we all know, the ecological disaster caused by white pollution has become one of the major problems plaguing the survival and development of human beings in the 21st century. [0003] In order to reduce white pollution and protect the ecological environment, the research, development and use of degradable materials are particularly important. At present, the commonly used biodegradable plastics are polylactic acid, polybutylene succinate, polybutylene adipate terephthalate, polybutylene adipate succinate, polycapr...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08L67/04C08K5/5425C08K5/057C08K7/24
CPCC08J5/18C08J2367/02C08J2467/04C08K2201/003C08K2201/004C08L67/02C08L2201/06C08L2203/16C08L2205/02C08L67/04C08K5/5425C08K5/057C08K7/24
Inventor 秦文生陆海荣秦体文
Owner LANZHOU XINYINHUAN RUBBER & PLASTIC PROD CO LTD
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