Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of w-wc-tic-hf-co alloy bar and its preparation method

An alloy bar, WC1%-5% technology, applied in the field of W-WC-TiC-Hf-Co alloy bar and its preparation, can solve the problem that the comprehensive mechanical properties cannot be greatly improved, and achieve low oxygen content and reduced oxygen content. requirements, the effect of good room temperature plasticity

Inactive Publication Date: 2018-11-16
XIAN HUASHAN METAL PROD CO LTD
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, traditional tungsten alloys cannot greatly improve their comprehensive mechanical properties due to their own defects and limitations of preparation processes.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of w-wc-tic-hf-co alloy bar and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0027] A preparation method of W-WC-TiC-Hf-Co alloy bar, the preparation steps are:

[0028] (1) Use wet ball milling to mix tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder uniformly, and obtain the mixed powder after vacuum drying;

[0029] (2) Press the mixed powder described in step (1) to obtain a blank, and then place the blank in a vacuum sintering furnace with a vacuum degree of not more than 5×10 -2 Pa, the temperature is 1200℃-1500℃, keep for 2h-3h for sintering treatment, and get the sintered body after cooling with the furnace;

[0030] (3) Put the sintered body described in step (2) in an electron beam melting furnace, and the vacuum degree is not more than 1×10 -2 Under the condition of Pa, electron beam smelting is carried out for 2-5 times, and after natural cooling, peeling is performed to obtain an ingot; the current of the electron beam smelting is 3A-5A, and the voltage of the electron beam smelting is 70kV-90kV;

...

Embodiment 1

[0037] Example 1: A W-WC-TiC-Hf-Co alloy bar, consisting of the following mass percentages: WC 3%, TiC 5%, Hf 3%, Co 3%, the balance being W and unavoidable 的impurities.

[0038] The preparation method of the W-WC-TiC-Hf-Co alloy bar in this embodiment includes the following steps:

[0039] (1) Put tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder in a ball mill, using anhydrous ethanol as a dispersant, at a speed of 350 rpm and a ball-to-battery ratio of 3:1. Ball milled for 5 hours and dried under vacuum conditions after ball milling to obtain mixed powder; the volume of the absolute ethanol is 2.5 times the sum of the masses of tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder. The unit is mL, the unit of mass is g, the mass purity of the tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder, and tungsten powder is not less than 99%, and the particle size...

Embodiment 2

[0046] Example 2: A W-WC-TiC-Hf-Co alloy bar, consisting of the following components by mass percentage: WC 1%, TiC 2%, Hf 1%, Co 1%, the balance being W and unavoidable 的impurities.

[0047] The preparation method of the W-WC-TiC-Hf-Co alloy bar in this embodiment includes the following steps:

[0048] (1) Put tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder in a ball mill, using anhydrous ethanol as a dispersant, at a speed of 350 rpm and a ball-to-battery ratio of 3:1. Ball milled for 5 hours and dried under vacuum conditions after ball milling to obtain mixed powder; the volume of the absolute ethanol is 2.5 times the sum of the masses of tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder. The unit is mL, the unit of mass is g, the mass purity of the tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder, and tungsten powder is not less than 99%, and the ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention discloses a W-WC-TiC-Hf-Co alloy rod and a preparation method thereof, and relates to the technical field of alloy materials. The W-WC-TiC-Hf-Co alloy rod is prepared from the following raw materials in percentage by mass: 1 to 5 percent of WC, 2 to 8 percent of TiC, 1 to 5 percent of Hf, 1 to 5 percent of Co and the balance of W and unavoidable impurities; the preparation method of the W-WC-TiC-Hf-Co alloy rod comprises the following steps: (1) uniformly mixing tungsten powder, tungsten carbide powder, titanium carbide powder, hafnium powder and cobalt powder by adopting a wet ball milling method, and performing vacuum drying to obtain mixed powder; (2) performing vacuum sintering to obtain a sintering body; (3) smelting 2 to 5 times by electron beams to obtain an ingot; (4) performing thermal extruding to obtain a semi-finished rod blank; (5) performing thermal extruding to obtain an alloy rod. The W-WC-TiC-Hf-Co alloy rod disclosed by the invention has high hardness, high strength and excellent comprehensive mechanical properties, and has wide application prospect in aerospace field, national defence industry, electronic information, energy resources and the like.

Description

Technical field [0001] The invention relates to the technical field of alloy material preparation, in particular to a W-WC-TiC-Hf-Co alloy bar and a preparation method thereof. Background technique [0002] Refractory metal tungsten alloy has a series of excellent mechanical properties such as high density and high strength. It has a wide range of uses in the fields of national defense, aerospace, electronic information, energy, metallurgy and machining industries, and plays an important role in the national economy. Status. High-density tungsten alloys generally refer to W-WC-TiC, W-WC-Cu, and W-Cu alloy systems with a tungsten content of 85%-99%. The common feature of these alloys is high density (16.5-19.0g / cm 3 ), small thermal expansion coefficient, good corrosion resistance and oxidation resistance, good electrical and thermal conductivity, and some alloys also have many other excellent properties such as high strength, good ductility, and good impact resistance. Therefor...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C22C27/04C22C32/00C22C1/02C22B9/22
CPCC22B9/228C22C1/02C22C27/04C22C32/0052
Inventor 常喜张力力王占峰翁永胜翁晓东
Owner XIAN HUASHAN METAL PROD CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products