A kind of w-wc-tic-hf-co alloy bar and its preparation method
An alloy bar, WC1%-5% technology, applied in the field of W-WC-TiC-Hf-Co alloy bar and its preparation, can solve the problem that the comprehensive mechanical properties cannot be greatly improved, and achieve low oxygen content and reduced oxygen content. requirements, the effect of good room temperature plasticity
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[0027] A preparation method of W-WC-TiC-Hf-Co alloy bar, the preparation steps are:
[0028] (1) Use wet ball milling to mix tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder uniformly, and obtain the mixed powder after vacuum drying;
[0029] (2) Press the mixed powder described in step (1) to obtain a blank, and then place the blank in a vacuum sintering furnace with a vacuum degree of not more than 5×10 -2 Pa, the temperature is 1200℃-1500℃, keep for 2h-3h for sintering treatment, and get the sintered body after cooling with the furnace;
[0030] (3) Put the sintered body described in step (2) in an electron beam melting furnace, and the vacuum degree is not more than 1×10 -2 Under the condition of Pa, electron beam smelting is carried out for 2-5 times, and after natural cooling, peeling is performed to obtain an ingot; the current of the electron beam smelting is 3A-5A, and the voltage of the electron beam smelting is 70kV-90kV;
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Embodiment 1
[0037] Example 1: A W-WC-TiC-Hf-Co alloy bar, consisting of the following mass percentages: WC 3%, TiC 5%, Hf 3%, Co 3%, the balance being W and unavoidable 的impurities.
[0038] The preparation method of the W-WC-TiC-Hf-Co alloy bar in this embodiment includes the following steps:
[0039] (1) Put tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder in a ball mill, using anhydrous ethanol as a dispersant, at a speed of 350 rpm and a ball-to-battery ratio of 3:1. Ball milled for 5 hours and dried under vacuum conditions after ball milling to obtain mixed powder; the volume of the absolute ethanol is 2.5 times the sum of the masses of tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder. The unit is mL, the unit of mass is g, the mass purity of the tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder, and tungsten powder is not less than 99%, and the particle size...
Embodiment 2
[0046] Example 2: A W-WC-TiC-Hf-Co alloy bar, consisting of the following components by mass percentage: WC 1%, TiC 2%, Hf 1%, Co 1%, the balance being W and unavoidable 的impurities.
[0047] The preparation method of the W-WC-TiC-Hf-Co alloy bar in this embodiment includes the following steps:
[0048] (1) Put tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder in a ball mill, using anhydrous ethanol as a dispersant, at a speed of 350 rpm and a ball-to-battery ratio of 3:1. Ball milled for 5 hours and dried under vacuum conditions after ball milling to obtain mixed powder; the volume of the absolute ethanol is 2.5 times the sum of the masses of tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder and tungsten powder. The unit is mL, the unit of mass is g, the mass purity of the tungsten carbide powder, titanium carbide powder, hafnium powder, cobalt powder, and tungsten powder is not less than 99%, and the ...
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