Arsenic-polluted soil remediation fertilizer

A technology for soil remediation and arsenic pollution, which is applied in the direction of calcium fertilizers, inorganic fertilizers, organic fertilizers, etc., can solve the problems of excessive heavy metal content in the soil, reduce fertilizer absorption and utilization, and reduce fertilizer utilization, so as to achieve rich nutrition, reduce absorption, The effect of ensuring food safety

Inactive Publication Date: 2017-05-24
GUIZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Since crops began to use chemical fertilizers, they are rich in nutrients such as N, P, and K, such as urea phosphate, urea urea phosphate, urea nitrate phosphate, potassium urea phosphate, etc., which have a significant effect on increasing crop production. However, due to the discharge of pollution sources, the environment The deterioration of the soil caused the heavy metal content in the soil to exceed the standard, and the pollution of the soil became increasingly serious, which greatly reduced the absorption and utilization of fertilizers by crops, and reduced the utilization rate of fertilizers. At the same time, crops grown under heavy metal pollution have great food Safety, therefore, in the current high-efficiency and rapid development, it is the current trend of agricultural development to develop a nutrient-rich fertilizer that not only contains the nutrients necessary for crop growth, but also can effectively restore soil heavy metals. Planting healthy and safe crops, and at the same time, improving the soil, reducing pollution, and achieving the dual benefits of high yield and heavy metal removal have become the focus of research in the planting and fertilizer industries. For this reason, The present inventor provides a fertilizer with multiple functions of high yield and reducing arsenic content for arsenic-contaminated soil, which has extremely high economic and social significance, and provides an effective way for the repair of soil pollution and the treatment of heavy metals

Method used

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  • Arsenic-polluted soil remediation fertilizer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A fertilizer for repairing arsenic-contaminated soil, which consists of the following raw materials in parts by weight: 40kg of urea, 15kg of urea phosphate, 20kg of potassium sulfate, 14kg of sodium nitrate, 10kg of weathered coal, 6kg of tobacco, 8kg of phosphogypsum powder, and 8kg of polyaluminum chloride , Soil conditioner 25kg;

[0024] The soil conditioner is composed of the following raw materials in parts by weight: 15 kg of modified ferrous sulfate, 10 kg of modified distiller's grains, and 25 kg of arsenic enrichment agent.

[0025] Described modified ferrous sulfate, is after ferrous sulfate aqueous solution is electrolyzed by electrolytic cell 3min, cuts off power, adds the attapulgite of 1.5% of the quality of ferrous sulfate, 60KHz frequency ultrasonic treatment 20min, at 1000r / min Centrifuge for 25 minutes at a high speed, take the supernatant, add 25% hydrogen peroxide with the mass of ferrous sulfate, heat it in a constant temperature water bath to 50°...

Embodiment 2

[0036] A fertilizer for repairing arsenic-contaminated soil, consisting of the following raw materials in parts by weight: urea 50kg, urea phosphate 30kg, potassium sulfate 40kg, sodium nitrate 19kg, weathered coal 15kg, tobacco 9kg, phosphogypsum powder 12kg, polyaluminum chloride 15kg , Soil conditioner 30kg;

[0037] The soil conditioner is composed of the following raw materials in parts by weight: 20 kg of modified ferrous sulfate, 15 kg of modified distiller's grains, and 30 kg of arsenic enrichment agent.

[0038] Described modified ferrous sulfate is after the ferrous sulfate aqueous solution is electrolyzed by the electrolytic cell for 5min, power off, and 2% attapulgite of the quality of ferrous sulfate is added, and the frequency of 70KHz is ultrasonically treated for 25min, at 1200r / min Centrifuge for 30 minutes at a high speed, take the supernatant, add 30% hydrogen peroxide of the mass of ferrous sulfate, heat to 60°C in a constant temperature water bath, and sti...

Embodiment 3

[0049] A fertilizer for repairing arsenic-contaminated soil, consisting of the following raw materials in parts by weight: urea 45kg, urea phosphate 23kg, potassium sulfate 30kg, sodium nitrate 16kg, weathered coal 13kg, tobacco 8kg, phosphogypsum powder 10kg, polyaluminum chloride 13kg , Soil conditioner 28kg;

[0050] The soil conditioner is composed of the following raw materials in parts by weight: 18 kg of modified ferrous sulfate, 13 kg of modified distiller's grains, and 28 kg of arsenic enrichment agent.

[0051] The modified ferrous sulfate is to electrolyze the ferrous sulfate aqueous solution through the electrolytic cell for 4 minutes, then cut off the power, add 1.8% attapulgite of the quality of the ferrous sulfate, ultrasonically treat the ferrous sulfate for 23 minutes at a frequency of 65KHz, Centrifuge for 28 minutes at a high speed, take the supernatant, add 28% hydrogen peroxide with the mass of ferrous sulfate, heat to 55°C in a constant temperature water ...

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Abstract

The invention relates to the technical field of fertilizers and particularly relates to an arsenic-polluted soil remediation fertilizer which consists of the following raw materials in parts by weight: 40-50 parts of urea, 15-30 parts of urea phosphate, 20-40 parts of potassium sulfate, 14-19 parts of sodium nitrate, 10-15 parts of decomposed coal, 6-9 parts of tobaccos, 8-12 parts of ardealite powder, 8-15 parts of polyaluminum chloride and 25-30 parts of a soil improver. The fertilizer contains rich nutrients, and the total content of nutrients, namely nitrogen, phosphorus and potassium, is greater than or equal to 55%; the fertilizer provided by the invention can effectively reduce the activity of metal ions in soil to change the form of heavy metals in soil; and with the conversion rate of an effective state into an ineffective state as an evaluation index for soil remediation, the conversion rate of arsenic metal in soil exceeds 84.9%.

Description

technical field [0001] The invention relates to the technical field of fertilizers, in particular to a fertilizer for repairing arsenic-contaminated soil. Background technique [0002] With the rapid development of the economy and the advancement of industrial technology, the adverse impacts of industrial and agricultural production on the environment have been increasing. Due to the continuous accumulation and dumping of solid waste on the soil surface, harmful waste water has continuously penetrated into the soil, harmful gases and dust in the atmosphere It also continuously falls into the soil with rainwater, causing soil pollution, which not only reduces the yield and quality of crops, but also indirectly endangers human health. Among them, arsenic is one of the common heavy metal pollution elements in the soil. Excessive arsenic in the soil can have adverse effects on plant growth. At the same time, it can also accumulate in plants through plant roots and enter the huma...

Claims

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Application Information

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IPC IPC(8): C05G3/04C05G3/80
CPCC05B15/00C05G3/80C05C5/02C05C9/00C05D1/02C05D3/02C05D9/00C05D9/02C05F5/008C05F11/00C05F11/02
Inventor 陈肖虎金会心陈庆唐道文赵平原王丽远鲁圣军黎志英刘利
Owner GUIZHOU UNIV
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