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Light scattering thermoplastic polyester composition

A composition and light-scattering technology, applied in the field of light-scattering polyester resin compositions, can solve the problems of unfavorable light-scattering performance stability, energy waste, sensitivity, etc., achieve good appearance and light stability, excellent light-scattering performance, raw materials A wide range of effects

Inactive Publication Date: 2017-03-15
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] However, when inorganic particles are used as light-scattering particles, they have the following weaknesses: ① While increasing the haze of the material, the light transmittance will be greatly reduced
②Poor compatibility with matrix material, difficult to evenly disperse in matrix material
③A larger amount of inorganic particles will lead to deterioration of the mechanical properties of the material
Inorganic particles have high hardness, which will cause certain wear and tear on the equipment
⑤ Some inorganic particles have a strong absorption of light in a certain band, which is not conducive to scattering, and some particles are sensitive to heat, oxygen and ultraviolet light, which is not conducive to the stability of light scattering performance
However, the preparation cost of conventional organic scatterer particles is relatively high, and like inorganic particles, it increases the haze of the material while reducing the light transmittance. At the same time, it cannot be deformed during the molding process, and the obtained isotropic light scattering material, which wastes energy to a certain extent and limits its application

Method used

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  • Light scattering thermoplastic polyester composition
  • Light scattering thermoplastic polyester composition
  • Light scattering thermoplastic polyester composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] 100 parts by mass of polymethyl methacrylate resin, 2 parts by mass of polyethylene terephthalate and conventional additives were melt-blended by a torque rheometer to obtain a light-scattering polyester resin composition. The composite was compression-molded at 265°C to prepare a 0.60 mm thick light-scattering sheet. The light transmittance was measured to be 77.5%, and the haze was 88.90%. After the point light source passes through the light scattering sheet, the scattering effect is as follows: figure 2 shown.

Embodiment 2

[0052] 100 parts by mass of polymethyl methacrylate resin, 6 parts by mass of polyethylene terephthalate and conventional additives were melt-blended by a torque rheometer to obtain a light-scattering polyester resin composition. The composite was compression-molded at 265°C to prepare a 0.60 mm thick light-scattering sheet. The measured light transmittance is 64.2%, and the haze is 94.41%. After the point light source passes through the light scattering sheet, the scattering effect is as follows: image 3 shown.

Embodiment 3

[0054] 100 parts by mass of polymethyl methacrylate resin, 10 parts by mass of polyethylene terephthalate and conventional additives were melt-blended by a torque rheometer to obtain a light-scattering polyester resin composition. The composite was compression-molded at 265°C to prepare a 0.60 mm thick light-scattering sheet. The measured light transmittance is 58.9%, and the haze is 94.65%. After the point light source passes through the light scattering sheet, the scattering effect is as follows: Figure 4 shown.

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PUM

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Abstract

The invention provides a light scattering thermoplastic polyester resin composition. The thermoplastic resin composition comprises: (A) a transparent matrix material which is selected from polymethyl methacrylate resin and copolymers thereof, such as polymethyl methacrylate, methyl methacrylate-styrene copolymer, methyl methacrylate and methyl acrylate copolymer; and (B) a scattering body material such as polyethylene glycol terephthalate resin. Relative to 100 parts by weight of the matrix material, 1 to 50 parts by weight of polyethylene glycol terephthalate are used, and an average particle size is preferably selected at 0.03 to 20 micrometers. A light scattering plate (membrane and sheet) prepared by using the thermoplastic polyester resin composition can meet the requirements of good light transmittance and high fog scale and is applicable to the fields such as lampshades, skylights, advertising lamp boxes, signage, liquid crystal displays, and the like.

Description

technical field [0001] The invention relates to a light-scattering polyester resin composition, which can meet the requirements of high light transmittance and high haze, and is suitable for the fields of lampshades, skylights, advertising light boxes, indicator signs, liquid crystal displays, and the like. Background technique [0002] With the energy crisis and environmental pollution becoming more and more serious, the theme of energy saving and low carbon has gradually penetrated into every aspect of people's life. At present, solid-state light sources are gradually replacing traditional fluorescent lamps, tungsten lamps, energy-saving lamps and other light sources due to their higher photoelectric conversion efficiency and environmental friendliness. The main component of solid-state light source is light-emitting diode (referred to as LED). LED lights are widely welcomed due to their advantages such as low working voltage, low power consumption, rich colors, long life ...

Claims

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Application Information

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IPC IPC(8): C08L33/12C08L67/02
CPCC08L33/12C08L2201/08C08L67/02
Inventor 熊英郭少云刘晓沈佳斌
Owner SICHUAN UNIV
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