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A kind of electron beam radiation curing coating for metal heavy anticorrosion

A technology of electron beam radiation and curing coatings, which is applied in the direction of anti-corrosion coatings, coatings, etc., can solve the problems of incomplete deep curing of cured coatings, poor anti-corrosion and mechanical properties, and weak adhesion between coatings and substrates. Achieve the effects of high curing efficiency, strong anti-corrosion ability and strong adhesion

Active Publication Date: 2018-09-04
NANJING INST OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the problems of incomplete curing of the deep layer of the cured coating, low curing efficiency, weak adhesion between the coating and the substrate, poor anti-corrosion performance and mechanical properties, and cannot be used in the field of heavy metal anti-corrosion under harsh conditions, the present invention provides A kind of electron beam radiation curing coating for metal heavy anticorrosion

Method used

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  • A kind of electron beam radiation curing coating for metal heavy anticorrosion
  • A kind of electron beam radiation curing coating for metal heavy anticorrosion
  • A kind of electron beam radiation curing coating for metal heavy anticorrosion

Examples

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Effect test

Embodiment 1

[0024] An electron beam radiation-cured coating for metal heavy-duty anti-corrosion, its components are proportioned according to the following mass fractions:

[0025] Epoxy oligomer 40g

[0026] Silicone modified epoxy resin oligomer 20g

[0027] Alkoxyhexanediol diacrylate 5g

[0028] Carbon black 10g

[0029] Mica Iron Oxide 5g

[0030] Zinc phosphate 10g

[0031] Nano alumina 10g

Embodiment 2

[0033] An electron beam radiation-cured coating for metal heavy-duty anti-corrosion, its components are proportioned according to the following mass fractions:

[0034] Epoxy acrylate 35g

[0035] Silicone modified epoxy resin oligomer 35g

[0036] Tricyclodecane dimethanol diacrylate 2g

[0037] Tris(2-hydroxyethylcarboethoxy)isocyanurate triacrylate 1g

[0038] Carbon black 0.5g

[0039] Polyaniline 0.5g

[0040] Zinc phosphate 7g

[0041] Aluminum tripolyphosphate 7g

[0042] Fumed silica 4g

[0043] Nano alumina 4g

[0044] Nano calcium carbonate 4g

Embodiment 3

[0046] An electron beam radiation-cured coating for metal heavy-duty anti-corrosion, its components are proportioned according to the following mass fractions:

[0047] Acrylic Oligomer 15g

[0048] Silicone modified epoxy resin oligomer 25g

[0049] Silicone modified acrylate 30g

[0050] Alkoxyhexanediol diacrylate 0.2g

[0051] Tris(2-hydroxyethyl)isocyanurate triacrylate 0.2g

[0052] Dipentaerythritol hexaacrylate 0.1g

[0053] Graphene 4.5g

[0054] ST antirust powder 10g

[0055] Nano silicate 5g

[0056] Fumed silica 10g

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Abstract

The invention discloses an electron beam radiation curing coating for metal heavy anti-corrosion. The coating is prepared from, by mass, 50%-80% of oligomer, 0.1-0.5% of reactive diluent, 1-10% of functional filler, 5-20% of antirust dyestuff and 5-15% of auxiliary filler, and the total mass percentage of the components is 100%. The curing coating for metal heavy anti-corrosion is cured by electron beam radiation, has the advantages of high efficiency and energy conservation, environment friendship and convenient operation, cured depth of the coating is high, thickness is big, and the adhesive force between the coating and the substrate is strong. A conductive carbon material is doped in the curable coating, thus the problem of metal heavy anti-corrosion is solved while electron beam energy absorption is avoided, and it is guaranteed that cured efficiency is not affected. The electron beam radiation curing coating for metal heavy anti-corrosion has excellent wear-resistance and corrosion-resistance, can be applied to the field of metal heavy anti-corrosion anti-corrosion, and is particularly applicable to the field of maritime work heavy anti-corrosion.

Description

technical field [0001] The invention belongs to the technical field of radiation-cured coatings, in particular to an electron beam radiation-cured coating for metal heavy-duty anticorrosion. Background technique [0002] At present, with the gradual improvement of people's awareness of environmental protection, light-curing coatings are widely used as a new generation of environmentally friendly coatings. Ultraviolet (UV) light-curing coating is to cure the resin by UV light irradiation. The system does not contain volatile organic compounds (VOC), and the curing speed is fast and the efficiency is high. However, UV energy consumption is large, and there is a radiation "blind zone" for workpieces with complex shapes, which cannot be effectively cured, and the curing thickness of UV coatings is limited to 20-40 μm, and the deep curing is not complete. The adhesion of the material is not strong, and the anti-corrosion and mechanical properties are reduced. At present, it can ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D4/02C09D5/08C09D7/61
CPCC09D4/00C09D5/084C09D7/61C09D7/70
Inventor 王章忠陈朝岚杭祖圣怀旭吴玉民吴刚强彭叶郭猛
Owner NANJING INST OF TECH
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