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Starch-polyethylene resin blended fully-degradable garbage bag and production method thereof

A polyethylene resin, fully degradable technology, applied in the field of plastic films, can solve the problems that hinder the wide application of starch plastics, the decline of film mechanical properties, and processing difficulties, and achieve the effect of large-scale industrial production, easy promotion, and easy mastery

Inactive Publication Date: 2016-12-21
ANHUI MEIXIANG PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, while starch improves the degradability of plastics, on the one hand, it will cause a decrease in its physical and mechanical properties, making it difficult to process. On the other hand, it is also too hydrophilic, which is not compatible with most general-purpose resins. Poor, resulting in a significant decline in the mechanical properties of the film, poor water resistance, thus hindering the wide application of starch plastics in the process of industrialization
Polyethylene resin is a widely used high molecular polymer, its performance is between plastic and rubber, it contains a large number of polar hydroxyl groups, its toxicity is very low, its molecular chain structure is symmetrical and regular, and it has unique strong adhesion, Film flexibility, smoothness, oil resistance, solvent resistance, protective colloid, gas barrier and water resistance after special treatment, but also has a certain degree of biodegradability, in the presence of bacteria in a wet environment 6 It can be completely decomposed into water and carbon dioxide within one month. It is a completely biodegradable material, but the degradation process has high requirements on the degradation environment, so the degradation rate is still relatively slow.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A starch-polyethylene resin blended fully degradable garbage bag, weighing the following components by weight: 50kg of polyethylene resin, 8kg of calcium carbonate, 1kg of nano-titanium dioxide, 10kg of benzoin ether, 7kg of nano-montmorillonite, Tetrabutyl titanate 1.2kg, ramie bone 12kg, corn starch 60kg, gelatin 2kg, magnesium stearate 1kg, acetyl tributyl citrate 13kg, 2,6-di-tert-butyl-4- ,Methyl phenol 1kg, 3-hydroxybenzoic acid 4kg, lauryl sulfate 1kg, plant saponin 4kg.

[0018] Made with the following specific steps:

[0019] (1) Mix cornstarch and nano-montmorillonite evenly and put them in an oven, dry them at 130°C for 120 minutes, take them out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath to 30°C, ultrasonic power is 100W), then transfer the mixed powder to a stirring tank, add tetrabutyl titanate, control the temperature at 75°C, stir at 1500 rpm for 15 minutes, then continue to add tetrabutyl...

Embodiment 2

[0024] A starch-polyethylene resin blended fully degradable garbage bag, weighing the following components: polyethylene resin 60kg, calcium carbonate 15kg, nano-titanium dioxide 4kg, benzoin ether 20kg, nano-montmorillonite 9kg , tetrabutyl titanate 1.4kg, ramie bone 14kg, corn starch 65kg, gelatin 3kg, magnesium stearate 2kg, acetyl tributyl citrate 15kg, 2,6-di-tert-butyl-4 -, methylphenol 1.5kg, 3-hydroxybenzoic acid 6kg, lauryl sulfate 2kg, plant saponin 6kg.

[0025] Made with the following specific steps:

[0026] (1) Mix cornstarch and nano-montmorillonite evenly and put them in an oven, dry them at 130°C for 120 minutes, take them out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath to 30°C, ultrasonic power is 100W), then transfer the mixed powder to a stirring tank, add tetrabutyl titanate, control the temperature at 75°C, stir at 1500 rpm for 15 minutes, then continue to add tetrabutyl titanate Esters, st...

Embodiment 3

[0031] A starch-polyethylene resin blended fully degradable garbage bag, weighing the following components: polyethylene resin 55kg, calcium carbonate 10kg, nano-titanium dioxide 3kg, benzoin ether 15kg, nano-montmorillonite 8kg , tetrabutyl titanate 1.3kg, ramie bone 13kg, corn starch 63kg, gelatin 2kg, magnesium stearate 2kg, acetyl tributyl citrate 13kg, 2,6-di-tert-butyl-4 -, methylphenol 1kg, 3-hydroxybenzoic acid 5kg, lauryl sulfate 1kg, plant saponin 5kg.

[0032] Made with the following specific steps:

[0033](1) Mix cornstarch and nano-montmorillonite evenly and put it in an oven, dry it at 130°C for 120 minutes, take it out, and cool the mixed powder to room temperature for 30-40 minutes (control the temperature of the water bath to 30°C, ultrasonic power is 100W), then transfer the mixed powder to a stirring tank, add tetrabutyl titanate, control the temperature at 75°C, stir at 1500 rpm for 15 minutes, then continue to add tetrabutyl titanate Esters, stirred for...

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Abstract

The invention discloses a starch-polyethylene resin blended fully-degradable garbage bag and a production method thereof. The garbage bag comprises, by weight, 50-60 parts of polyethylene resin, 8-15 parts of calcium carbonate, 1-4 parts of nanometer titanium dioxide, 10-20 parts of benzoin ethyl ether, 7-9 parts of nanometer montmorillonite, 1.2-1.4 parts of tetrabutyl titanate, 12-14 parts of ramie bones, 60-65 parts of corn starch, 2-3 parts of gelatin, 1-2 parts of magnesium stearate, 13-15 parts of acetyl tributyl citrate, 1-1.5 parts of 2,6-di-tert-butyl-4-methylphenol, 4-6 parts of 3-hydroxybenzoic acid, 1-2 parts of lauryl sulfate and 4-6 parts of plant saponin. The garbage bag is produced according to a safe formula, can be used for manufacturing food packaging bags, and has the advantages of realization of large strength, good water resistance, good oil resistance and good durability in use, facilitation of realization of large-scale industrial production, easiness in knowing, and convenience in promotion; and the garbage bag automatically decomposes under the action of rich oxygen and microbes after being wasted in order to finally generate carbon dioxide and water, so the garbage bag is ecologic and environmentally-friendly.

Description

technical field [0001] The invention relates to the technical field of plastic films, in particular to a starch-polyethylene resin blended fully degradable garbage bag and a preparation method thereof. Background technique [0002] In recent years, due to the increasingly serious "white pollution" caused by waste plastics that are difficult to degrade, it has attracted widespread attention from all over the world. Countries around the world have successively issued relevant laws and regulations restricting or prohibiting the use of non-degradable plastic packaging. On the other hand, because petroleum, the raw material for making traditional plastics, is a non-renewable resource, it will be exhausted with the massive use of human beings. Therefore, it is imminent to develop environmentally friendly plastics that use renewable resources as raw materials and are degradable. [0003] The use of biodegradable starch materials to prepare degradable packaging films has become a re...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L1/02C08L3/02C08L89/00C08K13/02C08K3/26C08K3/22C08K3/34C08K5/10C08K5/098C08K5/134
CPCC08L23/06C08K2201/011C08K2201/014C08L2201/06C08L2203/16C08L2205/035
Inventor 杨雪梅王维佳
Owner ANHUI MEIXIANG PLASTIC
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