Conductive antiaging ABS (acrylonitrile-butadiene-styrene) composite plastic and preparation method thereof

A composite plastic, anti-aging technology, applied in the field of polymer materials, can solve the problems of damage to precision electronic devices, static charge can not be released, electrostatic discharge and other problems, achieve good electrical conductivity and aging resistance, good market application prospects, use safe effect

Inactive Publication Date: 2016-08-17
合肥圆融新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, since the ABS molecule contains double bonds, it will be oxidatively degraded during use due to ultraviolet light, oxygen, acid, high temperature, etc., which will cause the material to change color and age, and shorten the overall service life of ABS composite plastics.
In addition, due to the insulation of the plastic material itself, it is easy to accumulate charges, resulting in the inability to release the static charge accumulated on the surface of the plastic product, thereby forming a static voltage, which is easy to absorb dirt such as dust. When the static voltage reaches a certain level, electrostatic discharge and electric shock will occur Phenomenon
In the electronics industry, precision electronic devices will be damaged or even scrapped due to electrostatic breakdown. If the accumulated static electricity is not released well, it will bring more serious consequences such as fire or explosion.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A conductive anti-aging ABS composite plastic, comprising the following components in parts by weight: 30 parts of ABS resin, 7 parts of chlorinated polyether, 11 parts of binary ethylene propylene rubber, 4 parts of nano-titanium dioxide, 3 parts of carbon fiber, and zinc sulfide powder 2 parts, 1 part of nano-bismuth powder, 3 parts of carrageenan, 3 parts of cellulose acetate-butyrate, 5 parts of dioctyl sodium sulfosuccinate, 3 parts of compatibilizer, 1 part of coupling agent, 0.2 parts of anti-aging agent share.

[0021] Wherein, the compatibilizer is composed of 40wt% methyl acrylate-butadiene-styrene copolymer and 60wt% acrylic acid-maleic anhydride copolymer. The coupling agent is γ-aminopropyltriethoxysilane coupling agent. The anti-aging agent is formed by mixing 35wt% didodecanyl thiodipropionate, 50wt% 3,3'-dioctadecyl thiodipropionate and 15wt% 2,2'-methylene Bis-(4-methyl-6-tert-butylphenol) composition.

[0022] The preparation method of the above-men...

Embodiment 2

[0028] A conductive anti-aging ABS composite plastic, comprising the following components in parts by weight: 40 parts of ABS resin, 11 parts of chlorinated polyether, 15 parts of binary ethylene propylene rubber, 6 parts of nano titanium dioxide, 4.5 parts of carbon fiber, and zinc sulfide powder 3 parts, 3 parts of nano-bismuth powder, 4.5 parts of carrageenan, 5 parts of cellulose acetate-butyrate, 7 parts of dioctyl sodium sulfosuccinate, 5 parts of compatibilizer, 3 parts of coupling agent, 1 part of anti-aging agent share.

[0029] Wherein, the compatibilizer is composed of 40wt% methyl acrylate-butadiene-styrene copolymer and 60wt% acrylic acid-maleic anhydride copolymer. The coupling agent is γ-aminopropyltriethoxysilane coupling agent. The anti-aging agent is formed by mixing 35wt% didodecanyl thiodipropionate, 50wt% 3,3'-dioctadecyl thiodipropionate and 15wt% 2,2'-methylene Bis-(4-methyl-6-tert-butylphenol) composition.

[0030] The preparation method of the above...

Embodiment 3

[0036] A conductive anti-aging ABS composite plastic, comprising the following components in parts by weight: 50 parts of ABS resin, 16 parts of chlorinated polyether, 18 parts of binary ethylene propylene rubber, 8 parts of nano titanium dioxide, 6 parts of carbon fiber, and zinc sulfide powder 5 parts, 5 parts of nano-bismuth powder, 6 parts of carrageenan, 8 parts of cellulose acetate-butyrate, 9 parts of dioctyl sodium sulfosuccinate, 6 parts of compatibilizer, 5 parts of coupling agent, 2 parts of anti-aging agent share.

[0037] Wherein, the compatibilizer is composed of 40wt% methyl acrylate-butadiene-styrene copolymer and 60wt% acrylic acid-maleic anhydride copolymer. The coupling agent is γ-(methacryloyloxy)propyltrimethoxysilane coupling agent. The anti-aging agent is formed by mixing 35wt% didodecanyl thiodipropionate, 50wt% 3,3'-dioctadecyl thiodipropionate and 15wt% 2,2'-methylene Bis-(4-methyl-6-tert-butylphenol) composition.

[0038] The preparation method of...

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Abstract

The invention discloses a conductive antiaging ABS (acrylonitrile-butadiene-styrene) composite plastic and a preparation method thereof. The ABS composite plastic comprises the following components in parts by weight: an ABS resin, chlorinated polyether, ethylene-propylene monomer, nano titanium dioxide, carbon fibers, zinc sulfide powder, nano bismuth meal, carrageenin, acetic acid-cellulose butyrate, sodium diethylhexyl sulfosuccinate, a compatilizer, a coupling agent and an antiaging agent. The ABS composite plastic disclosed by the embodiment of the invention has the advantages of favorable conductivity, favorable aging resistance, high use safety and long service life, and has market application prospects.

Description

technical field [0001] The invention belongs to the field of polymer materials, and relates to a conductive anti-aging ABS composite plastic and a preparation method thereof. Background technique [0002] Acrylonitrile-butadiene-styrene copolymer (ABS) is synthesized from three chemical monomers of acrylonitrile, butadiene and styrene. The polymerization of the three monomers produces a terpolymer with two phases. One is a continuous phase of styrene-acrylonitrile, and the other is a dispersed phase of polybutadiene rubber. ABS combines the different characteristics of each monomer. It has high strength, thermal stability and chemical stability, impact resistance, easy processing, high finish and high strength. It is easy to paint and color, and can also be used for various mechanical applications. It is widely used in automobiles, electronic appliances, machinery, instrumentation and construction, and is one of the most widely used general-purpose plastics. [0003] Howev...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08L71/00C08L23/16C08L5/00C08L1/14C08L33/08C08L33/02C08K13/06C08K9/06C08K3/22C08K7/06C08K3/30C08K3/08C08K5/42C08K5/372C08K5/13
CPCC08K2201/011C08K2201/014C08L55/02C08L2201/08C08L2205/02C08L2205/035C08L71/00C08L23/16C08L5/00C08L1/14C08L33/08C08L33/02C08K13/06C08K9/06C08K2003/2237C08K7/06C08K2003/3036C08K3/08C08K5/42C08K5/372C08K5/13
Inventor 蔡小连
Owner 合肥圆融新材料有限公司
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