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Flexible lithium ion battery cathode and manufacturing method thereof

A lithium-ion battery and a manufacturing method technology, applied in the field of designing lithium-ion batteries, can solve the problems of battery heating failure, thermal runaway explosion, slow lithium insertion kinetics, etc.

Inactive Publication Date: 2016-02-03
SHANDONG RUNSHENG POWER TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the sandwich-structured cell has brought about a sharp increase in the thickness of the negative electrode, which generally reaches more than 0.6mm, which is more than 8 times the thickness of the single-layer coating of the traditional wound electrode. Due to the slow lithium insertion kinetics of the traditional carbon negative electrode material of lithium batteries, it is difficult for For electrodes with a wound structure, the conventional charging rate becomes the high rate of the sandwich structure, and the thickening of the electrode increases the hysteresis of the reaction process. There is a phenomenon that the surface is overcharged and the interior is undercharged. When charging at a conventional rate, there is a danger of serious lithium deposition on the surface. If the lithium deposition is light, it will cause the battery to fail due to short-circuit heating, and if it is severe, there will be a risk of thermal runaway explosion, which greatly limits the sandwich structure. Applications of Li-ion Rechargeable Batteries

Method used

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  • Flexible lithium ion battery cathode and manufacturing method thereof
  • Flexible lithium ion battery cathode and manufacturing method thereof

Examples

Experimental program
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Effect test

Embodiment example 1

[0067] Add one part of superP conductive agent by mass to 15 parts by mass of low-boiling point solvent absolute ethanol, disperse with a planetary mixer at a high speed of 2000rpm for 30 minutes to form a uniform conductive paste, and then add 8.4 parts by mass of lithium-ion battery negative electrode active Material artificial graphite, continue to stir at the same stirring speed for 60 minutes to obtain the slurry containing active material and conductive agent, and then add a part of PTFE emulsion with a solid content of 60% by mass, so that the active material: conductive agent: solid of ptfe The mass ratio is 84%: 10%: 6%. Perform high-speed dispersion again for 10 minutes and then turn on the heating function of the mixer to raise the temperature of the slurry to 60°C and stir for 60 minutes before use;

[0068] Pour the prepared slurry into a flat heating plate, place it in a vacuum drying oven, slowly evacuate to -0.1MPa and heat to 80°C to completely volatilize the a...

Embodiment example 2

[0072] Add a mass of superP conductive agent to 15 mass parts of deionized water containing 50% absolute ethanol, use a planetary mixer to disperse at a high speed of 2500rpm for 30 minutes to form a uniform conductive paste, then add 8.4 mass parts of lithium-ion batteries Use the negative electrode active material mesophase carbon microsphere MCMB, continue to stir at the same stirring speed for 60 minutes, and then add a PTFE emulsion with a solid content of 60% by mass to make the active material : Conductive agent: The solid mass ratio of ptfe is 84%: 10%: 6%. Perform high-speed dispersion again for 10 minutes and then turn on the heating function of the mixer to raise the temperature of the slurry to 60°C and stir for 60 minutes before use;

[0073] Pour the prepared slurry into a flat heating plate, place it in a vacuum drying oven, slowly evacuate to -0.1MPa and heat to 110°C to completely volatilize the absolute ethanol aqueous solution in the slurry to obtain a dry po...

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Abstract

The invention relates to a flexible lithium ion battery cathode and a manufacturing method thereof. The manufacturing method is characterized in that a lithium ion battery cathode material, a conductive agent and PTFE (Polytetrafluoroethylene) are uniformly mixed with a low-boiling solvent, so as to form slurry, the slurry is dried to obtain a powdered mixture, then the powdered mixture is properly dispersed with a high-boiling solvent, so as to obtain an electrode film containing the high-boiling solvent through pressing, and then the electrode film is fully dried to obtain a flexible electrode. By taking the measures, the polarization degree and impedance of the electrode are effectively reduced, so that the intercalation process of the electrode is more uniform, and the phenomenon of lithium precipitation is effectively prevented.

Description

technical field [0001] The invention relates to the field of lithium-ion batteries, in particular to a flexible lithium-ion battery negative electrode and a manufacturing method thereof. Background technique [0002] Today, as battery raw materials are becoming more and more mature, with the continuous improvement of the market's performance requirements for lithium-ion batteries, users require higher energy density of lithium-ion batteries, especially in the field of rechargeable button-type lithium-ion batteries. According to the above customer requirements, manufacturers continue to improve technology. An effective way to improve the energy density and electrochemical performance of lithium-ion batteries is to reduce the dead space of the battery and increase the filling amount of active materials (positive and negative materials). The manufacturer changed the traditional winding structure of the inner core of the button-type rechargeable lithium-ion battery into a sandwi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M4/133H01M4/1393H01M10/0525
CPCH01M4/133H01M4/1393H01M4/62H01M4/622H01M10/0525Y02E60/10
Inventor 鞠群唐廎李青海孙杰
Owner SHANDONG RUNSHENG POWER TECH
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