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Plant oil-based polyurethane composite material and preparation method therefor

A vegetable oil-based, composite material technology, applied in the field of vegetable oil-based polyurethane composite materials and their preparation, can solve problems such as difficult operation, static electricity, air pollution, etc., and achieve the effects of stabilizing product performance, reducing air pollution, and improving comfort

Inactive Publication Date: 2015-11-18
林凯旋
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the other hand, antibacterial, anti-mite and anti-static are also a major problem for existing polyurethane products. Given the premise that cleaning is difficult, anti-bacterial and anti-mite are very necessary, and static electricity in dry areas is very troublesome.
In addition, traditional polyurethane products cannot be degraded naturally, and can only be discarded by burning when the service life expires, which will cause air pollution. Moreover, traditional polyurethane products will add a lot of amine catalysts due to the reaction. The product itself has a pungent smell and does not participate in chemical reactions. It is removed by ventilation and volatilization in the later stage of the product, which is neither environmentally friendly nor difficult to operate

Method used

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  • Plant oil-based polyurethane composite material and preparation method therefor
  • Plant oil-based polyurethane composite material and preparation method therefor
  • Plant oil-based polyurethane composite material and preparation method therefor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Weigh 40 parts by weight of castor oil-based polyether polyol, 30 parts by weight of special polyether polyol, 4 parts by weight of special metal additives, 0 parts by weight of catalyst, 2 parts by weight of crosslinking agent, 5 parts by weight of terminal amino Polyether and 1.5 parts by weight of foaming agent were stirred and mixed to obtain group A, and then 50 parts by weight of isocyanate of group A and group B were stirred and mixed, and reacted and formed at a temperature of 60°C.

[0021] Among them, castor oil-based polyether polyol has a functionality of 2.5 and a hydroxyl value of 120-140KOH / g; a special polyether polyol has a molecular weight of 4000-6000 and a functionality of 3 and a hydroxyl value of 34-42KOH / g; The agent is a silver ion additive; the amino-terminated polyether is the polyether amine of T-403 of Huntsman Company of the United States; the foaming agent is a mixture of water and fluorodichloroethane (HCFC-141B); the catalyst is Momentive ...

Embodiment 2

[0023] Weigh 80 parts by weight of castor oil-based polyether polyol, 7 parts by weight of special polyether polyol, 2 parts by weight of special metal additives, 0.5 parts by weight of catalyst, 2 parts by weight of crosslinking agent, 6 parts by weight of terminal amino Polyether and 3 parts by weight of foaming agent were stirred and mixed to obtain group A material, and then 30 parts by weight of isocyanate of group A and group B were stirred and mixed, and reacted and formed at a temperature of 40°C.

[0024] Among them, castor oil-based polyether polyol has a functionality of 2.5 and a hydroxyl value of 120-140KOH / g; a special polyether polyol has a molecular weight of 4000-6000 and a functionality of 3 and a hydroxyl value of 34-42KOH / g; The agent is a silver ion additive; the amino-terminated polyether is the polyetheramine of T-403 of Huntsman Company of the United States; the foaming agent is a fluorodichloroethane; the catalyst is the amine of NiaxA-33 or D-2000 of M...

Embodiment 3

[0026] Weigh 60 parts by weight of castor oil-based polyether polyol, 20 parts by weight of special polyether polyol, 4 parts by weight of special metal additives, 0 parts by weight of catalyst, 0 parts by weight of crosslinking agent, 5 parts by weight of terminal amino Polyether and 1.5 parts by weight of foaming agent were stirred and mixed to obtain group A material, and then 20 parts by weight of isocyanate of group A and group B were stirred and mixed, and reacted and formed at a temperature of 60°C.

[0027] Among them, castor oil-based polyether polyol has a functionality of 2.5 and a hydroxyl value of 120-140KOH / g; a special polyether polyol has a molecular weight of 4000-6000 and a functionality of 3 and a hydroxyl value of 34-42KOH / g; The agent is a silver ion additive; the amino-terminated polyether is the polyether amine of T-403 of Huntsman Company of the United States; the foaming agent is two mixtures of water and fluorodichloroethane; the catalyst is NiaxA-33 o...

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Abstract

The invention discloses a plant oil-based polyurethane composite material and a preparation method therefor. The plant oil-based polyurethane composite material comprises materials in a group A which comprises 40-80 parts of plant oil-based polyether polyhydric alcohol, 7-50 parts of special polyether polyol, 2-4 parts of a special metal auxiliary, 0-0.5 part of a catalyst, 0-2 parts of a crosslinking agent, 5-6 parts of amine-terminated polyether and 1.5-3 parts of a foaming agent; and a material in a group B which comprises 20-50 parts of isocyanate. A polyurethane product obtained can be degraded, so that air pollution can be reduced, and moreover, as the metal silver ion auxiliary is added into the product, so that not only can effects of resisting static electricity, resisting bacteria and preventing mites be achieved, but also the use level of the amine catalyst can be reduced by virtue of a catalytic function of the metal ion auxiliary. Even the catalyst is not added, so that pungent smells of the product are reduced or even avoided on the premise of a relatively good performance. In addition, the product according to the technical scheme has relatively good comfort.

Description

technical field [0001] The invention belongs to the field of polymer chemistry, and in particular relates to a vegetable oil-based polyurethane composite material and a preparation method thereof. Background technique [0002] Polyurethane is a common polymer material that is widely used in daily life. However, traditional polyurethane products have poor performance in terms of temperature balance, and usually show two extreme states in summer and winter, too soft or too hard, seriously affect comfort. Among them, the thermal conductivity of polyurethane is a problem that urgently needs to be solved for products such as polyurethane pillows and mattresses. The products produced by the prior art are usually stuffy, and users will feel hotter and hotter after prolonged use. On the other hand, antibacterial, anti-mite and anti-static are also a major problem for existing polyurethane products. It is necessary to prevent anti-bacterial and anti-mite because of the difficulty of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/50C08G18/48C08G18/32C08K3/08C08J9/08C08J9/14C08L75/08
CPCC08G18/3206C08G18/3275C08G18/4804C08G18/4829C08G18/4891C08G18/5024C08G18/6674C08G18/6688C08J9/144C08J2203/142C08J2375/08C08K3/08C08K2003/0806Y02A50/20
Inventor 林凯旋
Owner 林凯旋
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