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Glass bead for engineering-grade reflective film and preparation method thereof

A technology of glass microbeads and reflective film, applied in glass manufacturing equipment, glass molding, optics, etc., can solve the problems of inability to meet the requirements of engineering-grade reflective film, poor compatibility and affinity, affecting the performance of reflective film, etc. Achieve the effect of improving thermal stability and mechanical strength, avoiding agglomeration, improving mechanical properties and weather resistance

Inactive Publication Date: 2015-10-28
ANHUI TIANTANG WEIGAO PLASTIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, glass microspheres are an important raw material for the manufacture of reflective films, but in actual production, due to the polar state of "hydrophilic and oleophobic" on the surface, the compatibility and affinity between them and the polymer matrix Poor, the obvious interface effect with the polymer matrix makes the glass beads agglomerate and other phenomena, which affects the performance of the reflective film and leads to a decline in quality. In addition, the existing glass beads on the market still have the disadvantage of poor overall performance , unable to meet the requirements for the use of engineering-grade reflective film

Method used

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  • Glass bead for engineering-grade reflective film and preparation method thereof

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Embodiment Construction

[0015] A glass microbead for engineering-grade reflective film, made of the following weight (kg) of raw materials: natural sea stone 45, diopside 42, tungsten tailing 27, magnesite 36, pearl clay 27, boron phosphate 11. Calcium hexaboride 8, sorbitan monopalmitate 5, monododecyl phosphate triethanolamine 7, cationic hydroxy silicone oil 7, lanolin alcohol polyoxyethylene ether 4, additive 13;

[0016] The preparation method of the additive is as follows: a. Weigh the following materials (kg): fluorite tailings 50, waste sand 40, pebble chips 34, cryolite 25, calcium tungstate 18, lanthanum nitrate 10, strontium sulfate 12, Bismuth germanate 9, calcium tetraborate 14, barium metaphosphate 15, beryllium carbonate 15; b. Mix fluorite tailings, discarded sand, pebble chips, and cryolite evenly, crush, pass through an 80 mesh sieve, and add 10 times the amount of water , Wet ball milling at 5000r / min speed for 15min, drying, calcination at 890℃ for 0.5h, continue heating to 1320℃, ca...

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Abstract

The invention discloses a glass bead for an engineering-grade reflective film and a preparation method thereof. The glass bead is composed of the following components by weight: 41-53 parts of natural sea rock, 37-49 parts of diopside, 22-33 parts of tungsten tailings, 29-43 parts of magnesite, 21-32 parts of nacrite, 7-14 parts of boron phosphate, 5-10 parts of calcium hexaboride, 4-7 parts of sorbitan monopalmitate, 6-9 parts of triethanolamine polyoxyethylene dodecyl mono phosphate, 5-10 parts of cation hydroxy silicone oil, 3-6 parts of polyoxyethylene lanolin ether and 12-14 parts of additive. The glass beam is provided with the natural sea roc, the tungsten tailings and the magnesite which match the boron phosphate and the calcium hexaboride. Not only can thermal stability and mechanical strength of the glass beam be improved, but also wear resistance, high-temperature resistance, aging resistance and solvent resistance can be improved. The prepared glass beam has an excellent comprehensive performance and can be widely applied for the engineering-grade reflective film.

Description

Technical field [0001] The invention relates to a glass microbead for engineering-grade reflective film and a preparation method thereof, and belongs to the field of glass microbead manufacturing. Background technique [0002] Reflective film is a film with a special structure that uses optical principles to retroreflect light back to the light source. Reflective film is a novel reflective material formed by combining the reflective layer formed by glass beads with PVC, PU, ​​PET, acrylic, PC and other polymer materials by using a special process. Among them, glass beads are an important raw material for the manufacture of reflective films, but in actual production, the surface is in a "hydrophilic and oleophobic" polar state, resulting in compatibility and affinity with the polymer matrix. Inferior, the obvious interface effect with the polymer matrix causes the glass beads to agglomerate, which affects the performance of the reflective film and causes the quality to decline. I...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/128C03C12/02C03B19/10
CPCG02B5/128C03B19/1005C03C12/02
Inventor 程为高
Owner ANHUI TIANTANG WEIGAO PLASTIC TECH
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