A hydrocracking catalyst and a preparing method thereof

Abstract

A hydrocracking catalyst and a preparing method thereof are disclosed. The catalyst comprises metal components with hydrogenation activity and a carrier comprising a beta molecular sieve, amorphous silicon aluminum and aluminum oxide, wherein properties of the beta molecular sieve are as follows: the specific surface area is 400-800 m2 / g, the total pore volume is 0.4-0.55 mL / g, the SiO2 / Al2O3 mole ratio is 30-60, the relative crystallinity is 120-140%, the infrared acid content is 0.55-1.0 mmol / g, the non-framework aluminum accounts for less than 1% of the total aluminum, the amount of medium-strong acids which is measured by a NH3-TPD method accounts for 70-85% of the total acid amount, and the percent of Na2O is not more than 0.15 wt%. The preparing method includes mixing the beta molecular sieve, the amorphous silicon aluminum and the aluminum oxide, kneading and forming to prepare the carrier; and loading the metal components with hydrogenation activity by a conventional method. The beta molecular sieve which is proper in silicon aluminum ratio, large in specific surface area, proper in acidity, reasonable in pore structure and low in content of non-framework aluminum, and the amorphous silicon aluminum are adopted as cracking components of the catalyst. The prepared catalyst is characterized by producing a clean diesel oil product with a low condensation point with the highest yield, improving properties of hydrogenation tail oil, and the like.

Description

technical field [0001] The invention relates to a hydrocracking catalyst and a preparation method thereof, in particular to a hydrocracking catalyst with high activity and maximum mass production of low-condensation-point diesel oil and a preparation method thereof. Background technique [0002] Hydrocracking technology has the characteristics of strong adaptability of raw materials, great flexibility of product schemes, high selectivity of target products, good product quality, and high added value. It can directly convert various heavy and low-quality raw materials into clean fuel oil and high-quality chemical raw materials. It has become one of the most important heavy oil deep processing techniques in modern oil refining and petrochemical industries, and has been increasingly widely used in countries all over the world. As the quality of crude oil is deteriorating year by year, high-sulfur crude oil has increased significantly, and environmental protection has increasing...

AI Technical Summary

Problems solved by technology

Although the activity and medium oil selectivity of this catalyst are significantly improved compared with the previous amorphous silica-alumina catalysts, and it has the characteristics of producing the most low-point diesel oil, but the reaction temperature is still high, and the operation flexibility is poor, which is difficult to meet the production requirements. The manufacturer needs to increase the processing capacity of the device and further increase the production of diesel oil

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