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Preparation method for transparent silver nanowire conducting electrode

A technology of transparent conductive electrodes and silver nanowires, which is applied in the direction of cable/conductor manufacturing, conductive layers on insulating carriers, circuits, etc., can solve the problems of limiting the large-area application of nano-silver wires, time-consuming, and energy consumption, and achieve good results. The effect of application prospect, simple process, good light transmittance and electrical conductivity

Active Publication Date: 2015-05-27
SOUTH CHINA NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, high surface resistance and low surface adhesion limit the large-area application of silver nanowires. In order to prepare silver nanowire electrodes with excellent performance, complex post-treatment processes such as high-temperature annealing, high-intensity pulsed laser sintering and surface packaging are used. solve the above problems, but these processes are not only time-consuming but also energy-intensive

Method used

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  • Preparation method for transparent silver nanowire conducting electrode
  • Preparation method for transparent silver nanowire conducting electrode
  • Preparation method for transparent silver nanowire conducting electrode

Examples

Experimental program
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Effect test

Embodiment 1

[0042] The preparation method of the nano-silver wire transparent conductive electrode provided in this embodiment, such as figure 1 As shown, wherein (1) means that nano-silver wires are drip-coated on PET substrates: 1 means nano-silver wires, 2 means substrates, (2) means that UV glue is applied to nano-silver wire films, and 3 means UV glue , (3) represents that absolute ethanol is dropped on the UV glue, 4 represents absolute ethanol; (4) represents the silver nanowire transparent conductive film after ultraviolet exposure. It mainly includes five steps: 1. Preparation of silver nanowires with high aspect ratio by polyol method; 2. Hydrophilic treatment of the substrate; 3. Coating the prepared silver nanowire solution on the substrate, drying at room temperature, Obtain the silver nanowire transparent conductive film; four, carry out the adhesion treatment to the silver nanowire transparent conductive film and the substrate; five, the silver nanowire transparent conducti...

Embodiment 2

[0060] The preparation method of the nano-silver wire transparent conductive electrode provided in this embodiment, such as figure 1 As shown, wherein (1) means that nano-silver wire is drip-coated on the PI substrate: 1 means nano-silver wire, 2 means substrate, (2) means that UV glue is applied to nano-silver wire film, and 3 means UV glue , (3) represents that absolute ethanol is dropped on the UV glue, 4 represents absolute ethanol; (4) represents the silver nanowire transparent conductive film after ultraviolet exposure. It mainly includes five steps: 1. Preparation of silver nanowires with high aspect ratio by polyol method; 2. Hydrophilic treatment of the substrate; 3. Coating the prepared silver nanowire solution on the substrate, drying at room temperature, Obtain the silver nanowire transparent conductive film; four, carry out the adhesion treatment to the silver nanowire transparent conductive film and the substrate; five, the silver nanowire transparent conductive ...

Embodiment 3

[0079] The preparation method of the nano-silver wire transparent conductive electrode provided in this embodiment, such as figure 1 As shown, wherein (1) means that nano-silver wire is drip-coated on the PI substrate: 1 means nano-silver wire, 2 means substrate, (2) means that UV glue is applied to nano-silver wire film, and 3 means UV glue , (3) represents that absolute ethanol is dropped on the UV glue, 4 represents absolute ethanol; (4) represents the silver nanowire transparent conductive film after ultraviolet exposure. It mainly includes five steps: 1. Preparation of silver nanowires with high aspect ratio by polyol method; 2. Hydrophilic treatment of the substrate; 3. Coating the prepared silver nanowire solution on the substrate, drying at room temperature, Obtain the silver nanowire transparent conductive film; four, carry out the adhesion treatment to the silver nanowire transparent conductive film and the substrate; five, the silver nanowire transparent conductive ...

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Abstract

The invention discloses a preparation method for a transparent silver nanowire conducting electrode. The preparation method comprises the following steps: (1) preparing a high length-diameter ratio silver nanowire solution; (2) conducting hydrophilization on a substrate; (3) coating the prepared silver nanowire solution on the substrate, and carrying out drying to obtain a transparent silver nanowire conducting thin film on the substrate; (4) conducting adhesion treatment on the transparent silver nanowire conducting thin film and the substrate; (5) exposing the transparent silver nanowire conducting thin film treated with adhesion to ultraviolet light, so as to obtain the transparent silver nanowire conducting electrode, wherein the adhesive force between the transparent silver nanowire conducting electrode and the substrate is high. The transparent silver nanowire conducting electrode prepared according to the method is excellent in carrier collection efficiency and relatively high in light transmittance, can improve the conductibility of a front electrode of a solar battery, reduce reflectivity, and potentially improve battery efficiency and reduce production cost, and is high in mechanical and environmental stability, and suitable for large-area low-cost preparation.

Description

technical field [0001] The invention belongs to the technical field of transparent conductive electrodes, and in particular relates to a preparation method of silver nanowire transparent conductive electrodes. Background technique [0002] Generally speaking, a transparent conductive electrode means that the transmittance to the spectrum of the incident light wavelength range between 380nm and 780nm is greater than 80%, and the resistivity is lower than 10. -3 Ω·cm film electrode. In 1907, Badeker reported the translucent conductive CdO material for the first time. It was not until the Second World War that the transparent conductive film (Transparent conductive film, TCF) material received enough attention and application. Now, TCF materials (such as ITO (Indium tin oxide)), TFO (fluorine-doped tin oxide) have been widely used in flat panel display, energy-saving glass and solar cells. From a physical point of view, the light transmission and conductivity of materials are...

Claims

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Application Information

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IPC IPC(8): H01B13/00H01B5/14H01L31/18H01L31/0224B05D5/12
CPCY02P70/50
Inventor 高进伟李若朋韩兵彭强吴永健
Owner SOUTH CHINA NORMAL UNIVERSITY
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