Pt/g-C3N4/AC functional carbon adsorbing material and preparation method and application thereof
A g-c3n4, carbon adsorption technology, applied in separation methods, chemical instruments and methods, other chemical processes, etc., can solve the problems of harsh operating conditions, complex processes, low efficiency, etc., to improve catalytic activity, improve adsorption performance, The effect of improving dispersibility
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Embodiment 1
[0017] A preparation of Pt / g-C 3 N 4 The method for / AC functional carbon adsorption material, comprises the following steps:
[0018] In a constant temperature water bath at 50°C, dissolve the triblock copolymer Pluronic F127 and Pluronic P123 in 50 mL of ethanol with a molar ratio of 1:2, and add 2 g of melamine, stir to dissolve completely, then add resorcinol under stirring , and make it completely dissolved, add 10mL of formaldehyde solution with a mass fraction of 30%, then add 10mL of 0.1mol / L hydrochloric acid solution, stir until the solution has obvious layering phenomenon, add chloroplatinic acid, stir for 1h, and let it stand Separate the layers, remove the polymer-rich phase of the lower layer, dry it in vacuum at 65°C, transfer it into a tubular reactor, and raise the temperature to 350°C at a rate of 5°C / min under the protection of high-purity argon, keep it warm for 1h, The temperature was raised to 460°C at a rate of °C / min, kept for 2 hours, then raised to ...
Embodiment 2
[0021] A preparation of Pt / g-C 3 N 4 The method for / AC functional carbon adsorption material, comprises the following steps:
[0022] In a constant temperature water bath at 60°C, dissolve the triblock copolymers Pluronic F127 and PluronicP123 in 50 mL of ethanol with a molar ratio of 1:5, and add 4 g of melamine. After stirring to dissolve completely, add resorcinol while stirring. After completely dissolving it, add 30mL of formaldehyde solution with a mass fraction of 30%, then add 5mL of 0.1mol / L hydrochloric acid solution, stir until the solution has obvious layering phenomenon, add chloroplatinic acid, stir for 1h, and let stand to separate layer, remove the polymer-rich phase of the lower layer, dry it under vacuum at 65°C, transfer it into a tubular reactor, and under the protection of high-purity argon, raise the temperature to 350°C at a rate of 5°C / min, keep it warm for 1h, and heat it at 2°C Raise the temperature to 460°C at a rate of 0.2°C / min, keep it warm for...
Embodiment 3
[0025] A preparation of Pt / g-C 3 N 4 The method for / AC functional carbon adsorption material, comprises the following steps:
[0026] In a constant temperature water bath at 55°C, dissolve the triblock copolymers Pluronic F127 and PluronicP123 in 50 mL of ethanol with a molar ratio of 1:3, and add 3 g of melamine. After stirring to dissolve completely, add resorcinol while stirring. After completely dissolving it, add 20mL of formaldehyde solution with a mass fraction of 30%, then add 8mL of 0.1mol / L hydrochloric acid solution, stir until the solution has obvious layering phenomenon, add chloroplatinic acid, stir for 1h, and let stand to separate layer, remove the polymer-rich phase of the lower layer, dry it under vacuum at 65°C, transfer it into a tubular reactor, and under the protection of high-purity argon, raise the temperature to 350°C at a rate of 5°C / min, keep it warm for 1h, and heat it at 2°C Raise the temperature to 460°C at a rate of 0.2°C / min, keep it warm for...
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