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Novel alkylation reactor and alkylation reaction method

An alkylation reactor and reactor technology, applied in chemical/physical/physical chemical nozzle reactors, chemical/physical/physical chemical mobile reactors, liquid hydrocarbon mixture production, etc., can solve the problem of increasing side reactions, It is not suitable for problems such as heat release, so as to achieve the effects of reducing side reactions, good reaction effects, and reducing acid consumption

Active Publication Date: 2015-04-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This reactor is not suitable for the sulfuric acid alkylation reaction process, because the heat exchange method adopted is the heat extraction method of circulating materials, which is not suitable for the sulfuric acid alkylation reaction with large exothermic heat. The liquid storage tank at the lower part of the reactor and The use of reaction material circulation operation mode will increase the side reaction

Method used

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  • Novel alkylation reactor and alkylation reaction method
  • Novel alkylation reactor and alkylation reaction method
  • Novel alkylation reactor and alkylation reaction method

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Embodiment 1~3

[0035] use as figure 1 In the reactor with the structure shown, the bed of the rotating bed is made of stainless steel mesh packing, the bed porosity of the stainless steel mesh packing is 0.95, and the specific surface area is 4000m 2 / m 3 , the wire diameter is 1mm, and the volume of the rotating bed accounts for 45% of the total volume of the rotating bed reactor. The axes of the inner rotating bed and the outer rotating bed are coincident and the direction of rotation is opposite. The gap between the inner rotating bed and the outer rotating bed is 50mm, and the thickness of the inner rotating bed is 0.5 times the thickness of the outer rotating bed.

[0036] The alkylation reaction is carried out using concentrated sulfuric acid with a mass concentration of 95% as a catalyst and isobutane and butene as raw materials.

[0037] The molar ratio of isobutane to butene is 1:1-300:1, preferably 3:1-50:1. The volume ratio of acid to hydrocarbon is 0.1:1~5:1, preferably 0.5:1~...

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Abstract

The invention discloses an alkylation reactor and an alkylation reaction method. The alkylation reactor comprises a reactor drum body, a sealing head, an inner rotating bed, an outer rotating bed, a feeding pipe, a fed material distributing pipe, a discharging opening, a circular cooling gas inlet and a circular cooling gas outlet, wherein the reactor drum body and the sealing head form a closed shell; the inner rotating bed is arranged in the middle in the shell; the fed material distributing pipe is arranged in a central hollow drum structure of the inner rotating bed and is communicated with the feeding pipe; a feeding mixer is arranged at the connecting position of the feeding pipe and the sealing head; the discharging opening is formed in the lower part of the shell; the inner rotating bed is connected with a driving device by the feeding pipe; the outer rotating bed is arranged at the outer side of the inner rotating bed; the upper end of the inner rotating bed and the fed material distributing pipe are connected into an integrated structure by a sealing member; the outer rotating bed and the shell are fixedly connected; and the outer rotating bed is connected with the driving device at the lower part by a rotating shaft. The alkylation reactor and the alkylation reaction method disclosed by the invention have the advantages that concentrated sulfuric acid is adopted as a catalyst, iso-butane and olefin are adopted as materials to carry out alkylation reaction, the reaction can be carried out under low temperature, the acid consumption is low and the quality of a product is high.

Description

Technical field [0001] The present invention involves a alkylated reactor and alkylated reaction method. Specifically, a alkylated reactor and alkylated reaction method that uses isoxy and C3 ~ C5 olefin olefin. Background technique [0002] With the development of the economy, especially the rapid development of the transportation industry, the emissions of vehicles are one of the main sources of air pollution. Increased gasoline quality is the most important way to reduce vehicle exhaust gas pollution.The alkyl -based oil obtained by the alkylated reactions of the isoxyane and C3 ~ C5 olefin has the characteristics of high sulfur -free, high octane value, small differences in the study of the dexane value and the mintf dexer, and is high -qualityImportant components of cleaning gasoline. [0003] The alkylated reaction is a traditional technology in the field of petroleum refining. It mainly has sulfuric acid alkylated technology and hydrofluorkexyxyxyx technology. Under the ac...

Claims

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Application Information

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IPC IPC(8): B01J19/28B01J19/26C10G50/00
CPCB01J19/26B01J19/28B01J2219/00281C10G50/00C10G2300/1081C10G2300/1088
Inventor 彭德强王璐瑶李欣齐慧敏陈建兵陈新孟凡飞王岩
Owner CHINA PETROLEUM & CHEM CORP
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