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A kind of rubber core material and preparation method thereof

A rubber core and composite material technology, applied in the field of rubber core material and its preparation, can solve the problems of rubber core material wear resistance and heat resistance need to be improved, cracking on the upper surface, layer-like shedding, etc., to achieve good dimensional stability properties and thermal stability, improve wear resistance and heat resistance, improve toughness and hardness

Active Publication Date: 2017-01-04
宁波佳乐特橡塑机电有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the rubber core of nitrile rubber in the prior art still has many deficiencies in practical applications: it is prone to cracking and layer-like shedding on the upper surface, large degumming of the inner wall of the rubber core, and cracking of the rubber at the contact point between the bottom of the rubber core and the piston. and other phenomena, the rubber core cannot seal the high-pressure fluid at the bottom of the well, and the rubber core cannot be recovered in time, and the wear resistance and heat resistance of the rubber core material need to be improved
However, its modification process to graphene is complicated, and it promotes the uniform dispersion of other substances in the rubber material because of the large specific surface area of ​​graphene. If the graphene itself is not uniformly dispersed in the rubber material, then directly Affecting the promoting effect of graphene on the uniform dispersion of other materials

Method used

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  • A kind of rubber core material and preparation method thereof
  • A kind of rubber core material and preparation method thereof
  • A kind of rubber core material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The rubber core material of the present embodiment comprises the following components by weight:

[0032]

[0033] The preparation method of the above rubber core material comprises the following steps:

[0034] (1) Preparation of graphene composite material:

[0035] Under ultrasonic conditions, disperse 100 parts of graphene oxide powder in 150 parts of tetrahydrofuran by weight, after graphene oxide forms an amorphous suspension in tetrahydrofuran, add 100 parts of hydrogenated Styrene-butadiene-styrene system mixture, the weight ratio of hydrogenated styrene, butadiene and styrene in the mixture is 1:0.5:1.7;

[0036] After reacting for 1.5h, carry out vacuum distillation, remove the organic solvent and dry to obtain graphene / hydrogenated styrene-butadiene-styrene composite;

[0037] The graphene / hydrogenated styrene-butadiene-styrene composite was melt-blended at 220°C, and the in-situ reduction reaction was carried out for 25 minutes, and the graphene composi...

Embodiment 2

[0043] The rubber core material of the present embodiment comprises the following components by weight:

[0044]

[0045] The preparation method of the above rubber core material comprises the following steps:

[0046] (1) Preparation of graphene composite material:

[0047] Under ultrasonic conditions, disperse 100 parts of graphene oxide powder in 160 parts of tetrahydrofuran by weight, after graphene oxide forms an amorphous suspension in tetrahydrofuran, add 110 parts of hydrogenation powder to the above suspension under stirring conditions. Styrene-butadiene-styrene system mixture, the weight ratio of hydrogenated styrene, butadiene and styrene in the mixture is 1:0.8:1.7;

[0048] After reacting for 1.8h, carry out vacuum distillation, remove the organic solvent and dry to obtain graphene / hydrogenated styrene-butadiene-styrene composite;

[0049] The graphene / hydrogenated styrene-butadiene-styrene composite was melt-blended at 225°C, and the in-situ reduction reacti...

Embodiment 3

[0055] The rubber core material of the present embodiment comprises the following components by weight:

[0056]

[0057] The preparation method of the above rubber core material comprises the following steps:

[0058] (1) Preparation of graphene composite material:

[0059] Under ultrasonic conditions, disperse 100 parts of graphene oxide powder in 180 parts of tetrahydrofuran by weight, after graphene oxide forms an amorphous suspension in tetrahydrofuran, add 120 parts of hydrogenated Styrene-butadiene-styrene system mixture, the weight ratio of hydrogenated styrene, butadiene and styrene in the mixture is 1:0.8:2;

[0060] After reacting for 2 hours, carry out vacuum distillation, remove the organic solvent and dry to obtain graphene / hydrogenated styrene-butadiene-styrene composite;

[0061] Melt and blend the graphene / hydrogenated styrene-butadiene-styrene composite at 230°C, perform an in-situ reduction reaction for 50 minutes, and obtain the graphene composite mate...

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Abstract

The invention relates to a rubber core material. The rubber core material comprises, by weight, 80-120 parts of nitrile rubber, 15-20 parts of high-abrasion-resisting furnace blacks, 20-30 parts of semi-reinforcement furnace blacks, 10-30 parts of graphene composite materials, 20-40 parts of superfine vulcanized powder PVC, 0.8-1.5 parts of stearic acid, 1.2-2 parts of dioctyl phthalate, 1-1.8 parts of dibutyl phthalate, 1-4 parts of accelerants TT, 0.5-3 parts of accelerants CZ and 1-3 parts of anti-aging agents RD. The invention further relates to a manufacturing method of the rubber core material. The graphene composite materials have good affinity, the graphene of a honeycomb-shaped lattice structure is beneficial to dispersion of other components, meanwhile, the superfine vulcanized powder PVC also can promote even dispersion of the graphene composite materials and other components, in this way, a cooperative effect is achieved between the graphene composite materials and the superfine vulcanized powder PVC, the effects of all the components are brought into full play, and the useful performance of the rubber core material is comprehensively improved.

Description

technical field [0001] The invention relates to the technical field of rubber core materials for blowout preventers, in particular to a rubber core material and a preparation method thereof. Background technique [0002] The rubber core is the key part of the oil well universal annular blowout preventer. It is a device used to close the wellhead to avoid blowout during workover and completion. Its structure is relatively simple, but its function is extremely important. [0003] As a standard elastomer for oil-resistant rubber products, nitrile rubber is widely used in automobiles, textiles, aerospace, crude oil extraction, petrochemicals, wires, etc. due to its excellent physical and mechanical properties such as oil resistance, aging resistance, benzene resistance, and heat resistance. Cables, printing and dyeing and food packaging and other fields. With the increase of acrylonitrile content, the oil resistance, fuel oil resistance, benzene resistance, tensile strength, ha...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L9/02C08L27/06C08L53/02C08K13/02C08K3/04C08K5/09C08K5/12C08K5/3437C08K5/47
CPCC08J3/226C08J2327/06C08J2409/02C08K2201/003C08K2201/006C08K2201/014C08L9/02C08L2201/08C08L2205/03C08L27/06C08L53/025C08K13/02C08K3/04C08K5/09C08K5/12C08K5/3437C08K5/47
Inventor 朱双夫
Owner 宁波佳乐特橡塑机电有限公司
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