Polymerizable compound, liquid crystal composition, and liquid crystal display element

A liquid crystal composition and compound technology, applied in liquid crystal materials, organic chemistry, nonlinear optics, etc., can solve the problems of decreased polymerization reactivity and achieve the effects of large contrast, wide temperature range, and high voltage retention

Active Publication Date: 2015-02-25
JNC CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, attempts have been made to improve the solubility of liquid crystal compositions, but when the solubility increases, the polymerization reactivity tends to decrease

Method used

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  • Polymerizable compound, liquid crystal composition, and liquid crystal display element
  • Polymerizable compound, liquid crystal composition, and liquid crystal display element
  • Polymerizable compound, liquid crystal composition, and liquid crystal display element

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0206] The preparation of the liquid crystal composition is carried out by a method such as dissolving essential components together at a temperature higher than room temperature. Depending on the application, additives may be added to the composition. Examples of additives are optically active compounds, antioxidants, ultraviolet absorbers, light stabilizers, heat stabilizers, defoamers, and the like. Such additives are well known to those skilled in the art and are described in the literature.

[0207] The optically active compound has the effect of preventing reverse twist by creating a helical structure in liquid crystal molecules and imparting a necessary twist angle. By adding optically active compounds, the helical pitch can be tuned. For the purpose of adjusting the temperature dependence of the helical pitch, two or more optically active compounds may be added. Preferable examples of the optically active compound include the following compound (Op-1) to compound (O...

Embodiment 1

[0265] [Example 1] Synthesis of Compound No.26

[0266]

[0267] Step 1

[0268] (1,1'-biphenyl)-4,4'-diol (T-1) (200g, 1.07mol) was dissolved in DMF (2000ml), and tetrabutylammonium bromide (34.49g, 0.107mol), potassium carbonate (355g, 2.57mol) and 2-bromo-1,1-diethoxyethane (506g, 2.57mol), heated to reflux for 5 hours. After cooling the reaction solution to room temperature, it was poured into water (1000ml) and extracted with toluene (500ml×3). The extract was washed with saturated brine (500 ml×3), dried over anhydrous magnesium sulfate, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (toluene:ethyl acetate=19:1 by volume ratio), and then recrystallized from heptane to obtain compound (T-2) (434g, 1.07mol , 100%).

[0269] Step 2

[0270] After compound (T-2) (434 g, 1.07 mol) was dissolved in chloroform (4000 ml), trifluoroacetic acid ((918 ml, 12.36 mol)) was added dropwise at room temperature. After 16 hou...

Embodiment 2

[0275] [Example 2] Synthesis of Compound No.1

[0276]

[0277] Compound No. 1 was obtained by using acrylic anhydride and sodium acrylate in the third step in the same manner as the method described in Example 1.

[0278] 1 H-NMR (CDCl 3 ; δppm): 7.52 (d, 4H), 7.12 (d, 4H), 6.98 (d, 2H), 6.58 (dd, 2H), 6.26 (dd, 2H), 6.19 (d, 2H), 5.97 (dd, 2H).

[0279] Melting point: 121.1°C.

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Abstract

The compound represented by formula (1). For example, the rings A1, A2, A3 and A4 are 1,4-phenylene, Z1 and Z2 are alkylene having 1 to 10 carbons in which at least one —CH2— may be replaced by —O— or —CH═CH—; L1, L2 and L3 are a single bond, —COO— or —CH═CH—; G1 and G2 are —O—; s, t and u are 0 or 1; and P1 and P2 is the group (P-1), the group (P-2) or the group (P-3). M1 and M2 are hydrogen or methyl.

Description

technical field [0001] The present invention relates to a polymerizable compound having two polymerizable groups, a polymer obtained from the polymerizable compound, a liquid crystal composition containing the polymerizable compound or the polymer, and a liquid crystal display module containing the composition. It also relates to a liquid crystal display device in which the liquid crystal composition is sealed between substrates of a device, a polymerizable compound is polymerized while a voltage is applied to the device, and the orientation of liquid crystal molecules is controlled by the effect of the generated polymer. The present invention also relates to a liquid crystal composition mainly suitable for active matrix (active matrix, AM) components and the like, and AM components containing the same. Background technique [0002] The liquid crystal display module utilizes the optical anisotropy, dielectric anisotropy, etc. of the liquid crystal molecules in the liquid cry...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C69/54C07C69/653C09K19/12C09K19/14C09K19/18C09K19/20C09K19/30C09K19/32C09K19/34C09K19/38C09K19/42G02F1/13G02F1/1337
CPCC09K19/322C09K19/12C09K19/3838C09K19/3852C09K2019/122C09K2019/123C09K2019/0448G02F1/1333C09K2323/03C09K2323/00C07C69/54C07C69/653G02F1/13
Inventor 后藤泰行后藤真由美
Owner JNC CORP
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