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Low-shrinkage acrylic ester type vacuum impregnation agent for sealing reinforcement

A low-shrinkage acrylate and vacuum impregnation technology, which is applied in other chemical processes, chemical instruments and methods, etc., can solve the problems of labor, raw materials, energy waste, large contact area, corrosion, etc., and improve industrial production efficiency and volume Effect of low shrinkage and low viscosity

Inactive Publication Date: 2015-02-18
NANJING AIBUNA SEALING TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These defects are generally not easy to detect, and can only be found after pressure testing after machining, resulting in a serious waste of labor, raw materials, and energy; Into the pores, resulting in internal corrosion, shortening the service life, or bubbles or unevenness in surface treatment processes such as electroplating and painting due to the existence of micropores, resulting in product quality defects
Such a gap will reduce the airtightness of the casting, cannot improve the situation of point leakage and line leakage, weaken the effect of the impregnation process, and cannot fully meet the needs of industrial production; the solvent is also easy to enter the gap between the glue column and the pore wall due to capillary action. In the gap, compared with when the solvent is completely blocked, the solvent can only contact the casting wall from the end face. In this case, the contact area is larger, which is more likely to accelerate the corrosion of small holes in the casting, reduce the service life of the casting and bury safety hazards

Method used

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  • Low-shrinkage acrylic ester type vacuum impregnation agent for sealing reinforcement

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Taking a representative acrylate impregnating agent formula as an example, its composition is 69 parts by weight of lauryl methacrylate, 16 parts of 1,6 hexanediol diacrylate, 8 parts of trimethylolpropane triacrylate Parts, modified alkylphenol polyoxyethylene ether 12 parts, dimethacrylate modified polyethylene glycol (400) 10 parts, silane coupling agent KH550 modified nano-silica 2 parts, azobisisobutyl 2 parts of nitrile, 0.04 part of hydroquinone. The specific steps are as follows:

[0020] (1) Add lauryl methacrylate, 1,6 hexanediol diacrylate, trimethylolpropane triacrylate, modified alkylphenol polyoxyethylene ether, modified nano-silica, modified polyethylene Diol, hydroquinone, stirring speed 300-600 rpm, stirring for 10-30 minutes;

[0021] (2) Add azobisisobutyronitrile, stir at a speed of 600-800 rpm, and stir for 20-40 minutes;

[0022] (3) Stand for 10-60 minutes.

[0023] The physical properties of the acrylate impregnating agent obtained by Example...

Embodiment 2

[0026] Taking a representative acrylate impregnating agent formula as an example, its composition is 66 parts by weight of isodecyl methacrylate, 9 parts of diethylene glycol dimethacrylate, trimethylolpropane three 7 parts of acrylate, 2 parts of fatty acid polyoxyethylene ester, 2 parts of silane coupling agent KH550 modified nano-silica, 7 parts of dimethacrylate modified polyethylene glycol (200), azobisisobutyronitrile 3.5 parts, 0.08 parts of 2,5-di-tert-butylhydroquinone. The specific steps are as follows:

[0027] (1) Add isodecyl methacrylate, ethylene glycol diacrylate, trimethylolpropane triacrylate, polyoxyethylene fatty acid ester, modified nano-silica, modified polyethylene glycol, 2,5-di-tert-butylhydroquinone, stirring speed 300-600 rpm, stirring for 10-30 minutes;

[0028] (2) Add azobisisobutyronitrile, stir at a speed of 600-800 rpm, and stir for 20-40 minutes;

[0029] (3) Stand for 10-60 minutes.

[0030] The physical properties of the acrylate impregn...

Embodiment 3

[0033] Taking a representative acrylate impregnating agent formula as an example, its composition is 64 parts by weight of stearyl methacrylate, 6 parts of triethylene glycol dimethacrylate, glycerol trimethacrylate 8 parts of ester, 2 parts of modified alkylphenol polyoxyethylene ether, 3 parts of nano-silica modified by silane coupling agent KH550, 8 parts of dimethacrylate modified polyethylene glycol (200), azobis 2 parts of isobutyronitrile, 0.08 parts of 2,5-di-tert-butylhydroquinone. The specific steps are as follows:

[0034] (1) Add stearyl methacrylate, triethylene glycol dimethacrylate, glycerol trimethacrylate, modified alkylphenol polyoxyethylene ether, modified nano-silica, modified Polyethylene glycol, 2,5-di-tert-butylhydroquinone, stirring speed 300-600 rpm, stirring for 10-30 minutes;

[0035] (2) Add azobisisobutyronitrile, stir at a speed of 600-800 rpm, and stir for 20-40 minutes;

[0036](3) Stand for 10-60 minutes.

[0037] The physical properties of...

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Abstract

The invention discloses a low-shrinkage acrylic ester type vacuum impregnation agent for sealing reinforcement. The impregnation agent is prepared by uniformly mixing a mono-functionality acrylate monomer, a bifunctionality acrylate monomer, a reactive emulsifier, inorganic rigid particles, an organic anti-shrinkage agent, an initiator and a polymerization inhibitor. The appearance of the impregnation agent is colorless and transparent oily liquid; the specific gravity is 0.950-1.100kg / m<3>; the gelation time lasts for 240-360 seconds; the viscosity is smaller than 10.03mPa.s; the hardness of cured gel bar is greater than 85Shore A; the volume shrinkage rate before and after curing is less than or equal to 9.00%. The impregnation agent is low in viscosity and low in toxicity; the gelation time and hardness of the cured gel bar can meet the requirements of industrial production; the impregnation agent is low in volume shrinkage rate, and large micropores can be efficiently plugged by the impregnation agent; the impregnation agent is high in efficiency of plugging the micropores at one time; the impregnation agent is an ideal impregnation agent for metal sealing reinforcement.

Description

technical field [0001] The invention relates to a low-shrinkage acrylate type vacuum impregnating agent for sealing reinforcement. Background technique [0002] In industrial production, pressure-bearing sealing castings occupy a relatively large proportion. During the casting process of metal castings, defects such as internal looseness, pores and inclusions are prone to occur, resulting in products being scrapped due to leakage and air tightness that do not meet the requirements for use. According to statistics, the rejection rate of castings can be as high as 6 to 20%, and the rejection rate of some castings that are subjected to gas and hydraulic pressure, such as cylinder heads and valve bodies, can reach more than 30%. These defects are generally not easy to detect, and can only be found after pressure testing after machining, resulting in a serious waste of labor, raw materials, and energy; If it enters the pores, it will cause internal corrosion and shorten the ser...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/12C08F220/18C08F222/14C08F222/20C08F222/16C08F2/24
Inventor 王博
Owner NANJING AIBUNA SEALING TECH CO LTD
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