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Chemical agent capable of completely recycling power plant wastewater into circulating cooling water and preparation method of chemical agent

A technology for circulating cooling water and power plant wastewater, applied in chemical instruments and methods, water/sludge/sewage treatment, descaling and water softening, etc., can solve problems such as high operating costs, large heat consumption, and large investment, and achieve Does not require investment and does not increase the effect of facilities

Inactive Publication Date: 2015-02-04
董升
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] ① None of the thermal power plants (except the users using this agent and technology) is an enterprise that reuses all waste water for circulating cooling water to achieve zero discharge and the equipment does not scale or corrode for many years
[0004] ② There are four treatment methods for reverse osmosis concentrated water. One is to carry out high-pressure membrane treatment, recycle the produced water, and discharge 30-50% of the concentrated water, which belongs to the method of high energy consumption and emission reduction; the other is to carry out multi-effect evaporation, which will The waste water is heated into steam, then cooled into distilled water for recycling, the concentrated liquid is discharged or the crystallization is solidified by dosing, the investment is large, the operating cost is high, and the heat consumption is huge, so few users adopt it; the third is to discharge into the evaporation pond, evaporate or Formation leakage causes groundwater pollution; the fourth is direct discharge of natural rivers, lakes and seas
[0005] ③The treatment of desulfurized water is quite difficult. Some enterprises discharge it disorderly or discharge it to urban sewage plants for treatment, and some enterprises mix it with coal and incinerate it, forming a vicious circle
Although it has achieved the effect of zero discharge in the circulating water system, it still needs to increase investment in facilities during the implementation process

Method used

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  • Chemical agent capable of completely recycling power plant wastewater into circulating cooling water and preparation method of chemical agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] The self-provided power plant of an enterprise in Ningxia fills the circulating water system with waste water, reverse osmosis concentrated water, and acid-base wastewater regenerated by ion exchange resins. The amount of water added per day is 50-100PPM), Cl - Reached 7682mg / l, 11 times as much as the national standard. The conductance is 21000us / cm, the hardness is 4263mg / l, and the alkalinity is 450mg / l. It has been running for half a year for a long time. During this period, the heat exchanger has been opened many times for inspection. Not only is there no scaling and corrosion, but the old scale has been removed. The membrane has been installed, and the zero discharge of the circulating water system has been realized.

Embodiment 2

[0047]After adding the medicament of the present invention in the circulating water system of another enterprise's self-provided power plant in Ningxia (according to different water quality and the amount of water retained in the circulating water system, the amount added every day is 50-100PPM) the water quality on May 30, 2014 is:

[0048]

[0049] The circulating water system has not discharged a drop of water in the past six months of operation, and the equipment has no scale, corrosion, or mud, and calcium scale and rust scale have been removed.

Embodiment 3

[0051] There are two self-provided power plants of iron and steel enterprises in Handan. Desulfurization waste water, reverse osmosis concentrated water, ion exchange resin acid-base regeneration waste water are all used as supplementary water for circulating water. After adding medicament of the present invention in circulating water system (according to different water quality and the circulating water system retains water of 50-100PPM per day), and its wastewater quality is: alkalinity 8.5mmol / l, hardness 20mmol / l, Cl - 200mg / l, turbidity 60NTU. Industrial water is used when it is insufficient. Under the condition of zero discharge of circulating water, the equipment can operate safely for more than one year.

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Abstract

The invention discloses a chemical agent capable of completely recycling power plant wastewater into circulating cooling water. The chemical agent is characterized by comprising the following components in percentage by mass: 20-50% of a scale inhibitor, 15-60% of a dispersant, 10-40% of a sludge modifier, 5-10% of a pre-filming agent, 5-10% of a corrosion inhibitor, 5-10% of an anti-settling agent and the balance of water. The chemical agent meets the standard specified by DL / T806-2002 Corrosion Inhibitor for Power Plant Circulating Cooling water. Compared with the prior art, the circulating cooling water is directly injected into a circulating water system with no addition of facilities, no need of investment and no energy consumption, the circulating water system is not scaled or corroded for many years, inorganic solids and sludge formed in the running process can be cleared in the overhaul or pumped by a sludge pump and dried in air for filling pit or paving the road and thus the zero emission of the power plant circulating water system is achieved.

Description

technical field [0001] The invention relates to a medicament and a preparation method thereof, in particular to a medicament capable of recycling all power plant wastewater for circulating cooling water and a preparation method thereof. All the waste water from the power plant is used for circulating cooling water of the power plant. After using this agent, the circulating water system equipment can achieve no scaling and no corrosion for many years, and achieve true zero discharge. Background technique [0002] As we all know, the wastewater generated by power plants includes boiler blowdown water, reverse osmosis concentrated water, desulfurized water, acid-base wastewater from ion exchange resin regeneration, domestic water, etc. At present, the methods for treating the above wastewater in power plants are as follows: [0003] ① None of the thermal power plants (except for the users using this agent and technology) is an enterprise that reuses all waste water for circulat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14C02F5/08
CPCC02F5/08C02F5/145C02F2303/08C02F2303/22
Inventor 董升董兆祥
Owner 董升
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