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Environment-friendly ABS/PET (acrylonitrile-butadiene-styrene/polyethylene glycol terephthalate) alloy and preparation method thereof

An alloy and environmentally friendly technology, applied in the field of environmentally friendly ABS/PET alloy and its preparation

Inactive Publication Date: 2014-04-30
东莞市松燊塑料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the mechanical properties of ABS are poor. In order to make up for these deficiencies, people have carried out a series of modification work on ABS, using alloy technology, and blending ABS resin with other plastics to maintain the original excellent performance of ABS. Improve the deficiencies of ABS resin
[0003] Polyethylene terephthalate (PET) is a kind of thermoplastic semi-crystalline engineering plastics. Due to the high rigidity of the main chain, the movement of the chain segments is slow, so There are disadvantages such as slow crystallization rate and low crystallization degree, which greatly limit its application in the field of engineering plastics

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A kind of environmental protection ABS / PET alloy, it is made up of the raw material of following weight part:

[0054] ABS 40 parts

[0055] 30 copies of recycled PET

[0056] Nano calcium carbonate 1 part

[0057] 3 parts heavy calcium carbonate

[0058] Acrylate and glycidyl ester difunctional vinyl elastomer 2 parts

[0059] Methyl methacrylate-butadiene-styrene terpolymer 3 parts

[0060] 0.2 parts of pentaerythritol stearate

[0061] Dilauryl thiodipropionate 0.2 parts.

[0062] Wherein, the butadiene content in the ABS is 28wt%, and the styrene content is 25wt%.

[0063] Wherein, the particle diameter of described nano-calcium carbonate is 160 nanometers.

[0064] Wherein, the particle diameter of described ground calcium carbonate is 2600 orders.

[0065] Wherein, the melt index of the acrylate and glycidyl ester bifunctional vinyl elastomer is 2.0 g / 10 min, and the grafting rate of the acrylate and glycidyl ester bifunctional vinyl elastomer is 3.0%.

...

Embodiment 2

[0074] A kind of environmental protection ABS / PET alloy, it is made up of the raw material of following weight part:

[0075] ABS 50 parts

[0076] 40 copies of recycled PET

[0077] Nano calcium carbonate 3 parts

[0078] 5 parts heavy calcium carbonate

[0079] Acrylate and glycidyl ester difunctional vinyl elastomer 4 parts

[0080] Methyl methacrylate-butadiene-styrene terpolymer 5 parts

[0081] 0.5 parts of pentaerythritol stearate

[0082] Dilauryl thiodipropionate 0.5 parts.

[0083] Wherein, the butadiene content in the ABS is 30wt%, and the styrene content is 30wt%.

[0084] Wherein, the particle diameter of described nano calcium carbonate is 200 nanometers.

[0085] Wherein, the particle diameter of described ground calcium carbonate is 3000 orders.

[0086] Wherein, the melt index of the acrylate and glycidyl ester difunctional vinyl elastomer is 3.0 g / 10 min, and the grafting rate of the acrylate and glycidyl ester bifunctional vinyl elastomer is 4.0%.

...

Embodiment 3

[0095] A kind of environmental protection ABS / PET alloy, it is made up of the raw material of following weight part:

[0096] ABS 60 parts

[0097] 45 copies of recycled PET

[0098] Nano calcium carbonate 4 parts

[0099] 4 parts heavy calcium carbonate

[0100] Acrylate and glycidyl ester difunctional vinyl elastomer 3 parts

[0101] Methyl methacrylate-butadiene-styrene terpolymer 6 parts

[0102] 0.2 parts of pentaerythritol stearate

[0103] Dilauryl thiodipropionate 1 part.

[0104] Wherein, the butadiene content in the ABS is 32wt%, and the styrene content is 29wt%.

[0105] Wherein, the particle diameter of described nano calcium carbonate is 220 nanometers.

[0106] Wherein, the particle diameter of described ground calcium carbonate is 3300 orders.

[0107] Wherein, the melt index of the acrylate and glycidyl ester bifunctional vinyl elastomer is 3 g / 10 min, and the grafting rate of the acrylate and glycidyl ester bifunctional vinyl elastomer is 5.0%.

[010...

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Abstract

The invention relates to the technical field of PET modification, and in particular relates to an environment-friendly ABS / PET (acrylonitrile-butadiene-styrene / polyethylene glycol terephthalate) alloy and a preparation method thereof. According to the environment-friendly ABS / PET alloy and the preparation method disclosed by the invention, PET is recovered, thus the cost is low and the needs of green and environment-friendly sustainable development can be met; the adopted nanometre calcium carbonate and heavy calcium carbonate can be used as either a reinforcer or a nucleator, thus overcoming the defects of filling ABS and PET by independently using heavy calcium carbonate and nanometre calcium carbonate, and keeping good mechanical properties; acrylate and glycidyl ester bifunctional ethylene elastomers and methyl methacrylate-butadiene-styrene terpolymer are used as a composite toughener, which are complementary and exert a synergistic effect, thus improving the compatibility between ABS and PET, and then improving the mechanical properties of the ABS and PET alloy. In a word, according to the environment-friendly ABS / PET alloy and the preparation method disclosed by the invention, the mechanical properties and high temperature resistance of the ABS and PET alloy are improved through a complete formula system; the environment-friendly ABS / PET alloy and the preparation method are simple in production process and low in cost.

Description

technical field [0001] The invention relates to the technical field of PET modification, in particular to an environmentally friendly ABS / PET alloy and a preparation method thereof. Background technique [0002] ABS resin has the characteristics of chemical resistance, stable size, high surface gloss, low temperature resistance, good coloring performance and good processing performance. It is a thermoplastic engineering plastic with a wide range of uses. The main application fields are automobiles, electronic appliances and building materials. However, the mechanical properties of ABS are poor. In order to make up for these deficiencies, people have carried out a series of modification work on ABS, using alloy technology, and blending ABS resin with other plastics to maintain the original excellent performance of ABS. Improve the deficiencies of ABS resin. [0003] Polyethylene terephthalate (PET) is a thermoplastic semi-crystalline engineering plastic. Due to the high rig...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L67/02C08L51/06C08L51/04C08K13/02C08K3/26C08K5/103C08K5/372B29B9/06B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/875B29C48/911B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 刘福军
Owner 东莞市松燊塑料科技有限公司
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