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A kind of antiwear drag reducing agent for drilling fluid and preparation method thereof

A drag reducing agent and drilling fluid technology, applied in chemical instruments and methods, drilling compositions, etc., can solve problems such as economic losses, casualties, reduction in ROP, lubrication, and drag reduction efficiency, and achieve reduced Extreme pressure lubrication coefficient and mud cake adhesion coefficient, reduction of surface friction and wear, excellent effect of extreme pressure lubricity

Active Publication Date: 2017-03-15
四川康克石油科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the deepening of oil and gas exploration and development, there are more and more deep wells, highly deviated wells, and horizontal wells. In the construction process of such wells, due to the long construction period or the high degree of dogleg of the wellbore trajectory, the gap between the drilling tool and the casing Due to the mutual friction between them, the drill pipe is worn, and the casing is partially worn or worn out, so that the wellbore cannot meet the pressure-bearing requirements, which brings serious hidden dangers to drilling production or causes major accidents, reduces the production life of oil and gas wells, and is likely to cause major damage. economic losses and casualties
In the process of drilling for oil and gas production, under the conditions of high temperature, high density, high solid phase, and strong alkali, ordinary lubricants lose their activity due to factors such as cross-linking, degradation, volatilization, and demulsification, and their lubrication and drag reduction performance are greatly reduced.
In addition, during the drilling process of the highly deviated well section, the contact area between the drill string and the borehole wall increases, the frictional resistance increases, the wellbore cleaning is not effective, and the borehole wall is unstable, which is likely to cause diameter shrinkage, collapse and cuttings. bed formation, increasing torque and friction during drilling
If the lubricity and drag reduction are not well controlled, it is easy to cause complex accidents such as sticking and mud bagging, which will increase the flow resistance and reduce the ROP

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0028] A preparation method of an anti-wear drag reducing agent for drilling fluid, the method comprising the following steps:

[0029] (1) Under the sulfonation reaction conditions, according to the formula ratio in claim 2, the cottonseed oil and the sulfur powder mixture are reacted to obtain a sulfonated cottonseed oil compound with a sulfonated fatty acid salt content of ≥75%;

[0030] (2) Under the sulfonation reaction conditions, according to the formula ratio in claim 2, the vegetable oleic acid and the sulfur powder mixture are reacted to obtain a sulfonated oleic acid compound with a sulfonated fatty acid salt content of ≥75%;

[0031] (3) Under amidation reaction conditions, mixing and reacting the sulfonated oleic acid compound obtained in step (2) with diethanolamine to obtain a drag reducer main compound;

[0032] (4) Under the conditions of the neutralization reaction, combine the sulfonated cottonseed oil compound obtained in step (1), the drag reducer main compound obt...

Embodiment 1

[0041] Under the sulfonation reaction conditions at a temperature of 160°C, 28 parts by weight of cottonseed oil was reacted with 9 parts by weight of sulfur powder for 190 minutes to obtain a sulfonated cottonseed oil compound with a sulfonated fatty acid salt content of 77%. Parts of vegetable oleic acid reacted with 7 parts by weight of sulfur powder for 180 minutes to obtain a sulfonated oleic acid compound with a sulfonated fatty acid salt content of 75%; then under the conditions of amidation reaction, 35 parts by weight of sulfonated oleic acid were compounded And 3 parts by weight of diethanolamine at 145°C for 170 min amidation reaction to obtain the main drag reducer complex; finally, 36 parts by weight of the sulfonated cottonseed oil complex and 21 parts by weight of the drag reducer main complex Compound, 28 parts of kerosene, 15 parts of auxiliary materials and other materials are mixed for 130 minutes under normal temperature conditions to obtain the finished prod...

Embodiment 2

[0043] Under the condition of the sulfonation reaction at a temperature of 160°C, 29 parts by weight of cottonseed oil was reacted with 10 parts by weight of sulfur powder for 200 minutes to obtain a sulfonated cottonseed oil compound with a sulfonated fatty acid salt content of 79%. Parts of vegetable oleic acid was reacted with 8 parts by weight of sulfur powder for 190 minutes to obtain a sulfonated oleic acid compound with a sulfonated fatty acid salt content of 74%; then under the conditions of amidation reaction, 38 parts by weight of sulfonated oleic acid were compounded And 4 parts by weight of diethanolamine at 150°C for 210 min amidation reaction to obtain the main drag reducer complex; finally, 38 parts by weight of the sulfonated cottonseed oil complex and 20 parts by weight of the drag reducer main complex Compound, 26 parts of kerosene, 16 parts of auxiliary materials and other materials were mixed for 140 minutes under normal temperature conditions to obtain the f...

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Abstract

The invention relates to a wear-resistant drag reducer for drilling fluid and a preparation method thereof. The wear-resistant drag reducer is characterized in that a formula of the wear-resistant drag reducer is prepared from the following main raw materials: vegetable oil acid, cotton seed oil, sulfur powder, diethanol amine and kerosene; the auxiliary raw materials comprise tributyl phosphate, organic soil and T323 anti-wear reagent at extreme pressure. The wear-resistant drag reducer for drilling fluid comprises the following components in percentage by weight based on the total amount of the drag reducer: 7-13 percent of vegetable oil acid, 26-31 percent of cotton seed oil, 6-11 percent of sulfur powder, 3-5 percent of diethanol amine, 27-29 percent of kerosene and 12-17 percent of auxiliary materials and other materials. The method for preparing the wear-resistant drag reducer for drilling fluid comprises a sulfonation reaction, an amidation reaction and a mixed reaction. When the wear-resistant drag reducer is used for drilling, the drag reducer can be adsorbed to the surface of a drilling tool preferentially, a dense high-strength protective film is generated, the lubricating property of the drilling fluid is reduced, the friction and wear of the metal surface are reduced, an extreme pressure lubrication coefficient and a mud cake adhesion coefficient of the drilling fluid are effectively reduced, blockage and other accidents in the drilling process are reduced.

Description

Technical field [0001] The invention relates to the technical field of petroleum exploitation chemistry, in particular to an anti-wear drag reducer for drilling fluid and a preparation method thereof. Background technique [0002] With the deepening of oil and gas exploration and development, there are more and more deep wells, highly deviated wells, and horizontal wells. During the construction of such wells, due to the long construction period or the high degree of borehole trajectory, the difference between drilling tools and casing Due to mutual friction, the drill pipe is worn out, and the casing is locally thinned or worn, which causes the wellbore to fail to meet the pressure requirements, which brings serious hidden dangers or major accidents to the drilling production, reduces the life of the oil and gas wells, and is very likely to cause major Economic losses and casualties. In the process of oil and gas exploitation and drilling, ordinary lubricants lose their activit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/03
CPCC09K8/03C09K2208/28
Inventor 江玉文杨威江春华
Owner 四川康克石油科技有限公司
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