Ternary ferroelectric solid solution lead lutecium niobate-lead magnesium niobate-lead titanate
A technology of lead niobate lutetate and lead magnesium niobate, which is applied in the field of functional materials and can solve problems such as easy depolarization and lower piezoelectricity operating temperature range
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example 1
[0012] Example 1: Prepared by secondary synthesis method, specific steps:
[0013] a) Magnesium oxide (MgO) and niobium oxide (Nb 2 o 5 ) was weighed according to the stoichiometric ratio (in which MgO was over 2%), and calcined at 1150°C for 2h to obtain MgNb 2 o 6 Powder;
[0014] b) Lutetium oxide (Lu 2 o 3 ) and niobium oxide are weighed according to the stoichiometric ratio (where Lu 2 o 3 Excess 1%) was calcined at 1150°C for 2h to obtain LuNbO 4 Precursor;
[0015] c) MgNb 2 o 6 , LuNbO 4 , PbO and TiO 2 (wherein the PbO excess is 2%) After mixing, calcining at 850°C for 4h to obtain xPb(Lu 1 / 2 Nb 1 / 2 )O3-yPb(Mg 1 / 3 Nb 2 / 3 )O 3 - (1-x-y)PbTiO 3 pre-synthesized powder;
[0016] d) ball milling and drying the pre-synthesized powder, adding 5wt% PVA, debinding at 300-500°C for 1-3 hours;
[0017] e) Sintering at 1050°C-1100°C for 3 hours to obtain xPb(Lu 1 / 2 Nb 1 / 2 )O3-yPb(Mg 1 / 3 Nb 2 / 3 )O 3 -(1-x-y)PbTiO 3 Ceramic samples.
[0018] The samples ...
example 2
[0019] Example 2: Determination of the structure of ceramics.
[0020] The structure of the ceramics was determined by X-ray powder diffraction. The instrument used is Japan RIGAKU-DMAX2500 powder diffractometer (Cu target, λ = 0.154056 nm, graphite monochromator), the specific test conditions are at room temperature, the measurement angle range is 10-80 o , with a step size of 0.02 o (2θ), 7 per minute o .
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