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Solar cell packaging rubber film and preparation method thereof

A solar cell and encapsulation adhesive film technology, which is applied in circuits, adhesives, photovoltaic power generation, etc., can solve the problems of reduced photoelectric conversion efficiency of solar cells, damage of solar cell components, and corrosion of metal electrodes of cells, so as to prolong the outdoor service life, The effect of reducing permanent deformation and reducing damage

Active Publication Date: 2013-01-09
宁波威克丽特功能塑料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Before the 1980s, liquid silicone resin and polyvinyl butyral resin sheet (PVB) were tried at home and abroad, but they were all eliminated due to high price, harsh construction conditions, and poor physical properties.
The most widely used packaging material in the market is ethylene-vinyl acetate polymer (EVA). However, EVA material is easy to degrade under the action of light and heat to produce acidic substances, which will corrode the metal electrodes in the battery sheet, and may cause short circuits or Open circuit, so that the solar cell module is damaged
More importantly, the EVA material will produce C=C double bonds due to degradation, which will make the film yellow. Some data show that the yellow film will greatly reduce the photoelectric conversion efficiency of solar cells.

Method used

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  • Solar cell packaging rubber film and preparation method thereof
  • Solar cell packaging rubber film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] Add 5 parts by mass of polar resin polyethylene grafted maleic anhydride copolymer, 1 mass part of crosslinking curing agent tert-butyl peroxide 2-ethylene glycol in 100 parts by mass of polymer resin ethylene-butene copolymer raw material Hexyl carbonate, 0.1 parts by mass of crosslinking curing accelerator triallyl isocyanurate, 0.5 parts by mass of tackifier r-glycidyl ether oxypropyl tertiary oxysilane, 0.2 parts by mass of antioxidant Agent bis(2,4-dicumylphenyl)pentaerythritol diphosphite, 0.1 parts by mass of UV light stabilizer polysuccinic acid (4-hydroxy-2,2,6,6-tetramethyl-1- 1 piperidine ethyl alcohol) ester and 0.1 parts by mass of UV absorber 2-hydroxyl-4-methoxybenzophenone are mixed evenly and put into an extruder for mixing and plasticizing, and the temperature of the extruder is controlled at 83°C. The obtained extrudate was cast and calendered to form a film, cooled and drawn to shape, and finally a solar cell encapsulating adhesive film F-1 with a th...

Embodiment 2

[0072] Add 2 parts by mass of polar resin polybutene grafted maleic anhydride copolymer, 1 mass part of crosslinking curing agent tert-butyl peroxide 2-ethylene glycol to 100 parts by mass of polymer resin ethylene-propylene copolymer raw material Hexyl carbonate, 0.1 parts by mass of crosslinking curing accelerator triallyl isocyanurate, 0.5 parts by mass of tackifier r-glycidyl ether oxypropyl tertiary oxysilane, 0.2 parts by mass of antioxidant Agent bis(2,4-dicumylphenyl)pentaerythritol diphosphite, 0.1 parts by mass of UV light stabilizer polysuccinic acid (4-hydroxy-2,2,6,6-tetramethyl-1- 1 piperidine ethyl alcohol) ester and 0.1 parts by mass of ultraviolet light absorber 2-hydroxyl-4-methoxyl-5-sulfonic acid benzophenone, after mixing evenly, drop into an extruder for mixing and plasticizing, and extrude The temperature of the machine was controlled at 82°C, and the obtained extrudate was cast and calendered to form a film, cooled and pulled to shape, and finally a sol...

Embodiment 3

[0074] Add 10 parts by mass of polar resin POE grafted acrylate copolymer, 1 mass part of crosslinking curing agent tert-butyl peroxide 2-ethylhexyl in 100 parts by mass of polymer resin ethylene-butene copolymer raw material Carbonate, 0.1 parts by mass of crosslinking curing accelerator triallyl isocyanurate, 0.5 parts by mass of tackifier r-glycidyl ether oxypropyl tertiary oxysilane, 0.2 parts by mass of antioxidant three (2,4-di-tert-butylphenyl) phosphite, 0.1 parts by mass of UV light stabilizer polysuccinic acid (4-hydroxy-2,2,6,6-tetramethyl-1-1 piperidine Ethanol) ester and 0.1 parts by mass of UV absorber N-(ethoxycarbonylphenyl)-N'-methyl-N'-phenylmethyl ether are mixed evenly and then put into the extruder for mixing and plasticization, extruding The exit temperature was controlled at 88°C, and the obtained extrudate was cast and calendered to form a film, cooled and pulled to shape, and finally a solar cell encapsulating adhesive film F-3 with a thickness of 0.5 ...

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Abstract

The invention relates to a solar cell packaging rubber film and a preparation method thereof. The solar cell packaging rubber film comprises the following components in parts by mass: 100 parts of polymer resin, 1-50 parts of polar resin, 0.5-2 parts of cross-linking curing agent, 0.05-0.2 part of cross-linking curing accelerator, 0.2-0.6 part of tackifier, 0.1-0.5 part of antioxidant, 0.05-0.25 part of ultraviolet stabilizer and 0.05-0.25 part of ultraviolet absorber. The preparation method of the solar cell packaging rubber film comprises the following steps of: 1) evenly mixing the raw materials according to proportions to obtain mixture; and 2) pouring the mixture into an extruder for mixing and plasticizing to obtain extruded materials, casting and calendaring the extruded materials to form a film, shaping through cooling and drawing, and finally winding the film. The solar cell packaging rubber film provided by the invention has the advantages that the light transmittance is higher, the film can effectively resist aging and the electric insulating performance is not changed fundamentally after the film is used for a long time; and the preparation method provided by the invention has the advantages that the processing efficiency is high, the cost is low and the large-scale production can be realized.

Description

technical field [0001] The invention belongs to the field of solar cell packaging materials and preparation thereof, in particular to a solar cell packaging adhesive film and a preparation method thereof. Background technique [0002] When non-renewable energy sources such as electricity, coal, and oil are running out frequently, and energy issues have increasingly become a bottleneck restricting the development of the international society and economy, more and more countries have begun to implement the "Sunshine Plan" to develop solar energy resources and seek new impetus for economic development. Some high-level nuclear research institutions in Europe have also begun to turn to renewable energy. Driven by the huge potential of the international photovoltaic market, the solar cell manufacturing industries of various countries are scrambling to invest huge sums of money and expand production in order to compete for a place. [0003] Solar photovoltaic power generation will...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J7/00C09J123/08C09J123/16C09J123/20C09J151/06C09J11/06H01L31/048B29C69/02B29C47/92B29L7/00B29C48/92
CPCY02E10/50B29C48/08
Inventor 张发饶
Owner 宁波威克丽特功能塑料有限公司
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