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Low-smoke flame-retardant acrylonitrile butadiene styrene (ABS) alloy material

An alloy material, a low-smoke flame-retardant technology, applied in the field of low-smoke flame-retardant ABS alloy materials, to achieve the effect of reducing the rate and amount of smoke released, significant social benefits and industrial application value, and good compatibility

Inactive Publication Date: 2012-09-19
JIANGSU AGT TECH DEV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Chinese patent CN101463177B discloses a preparation method of a high-gloss flame-retardant ABS modified resin. This method improves the flame retardancy of ABS while improving its surface gloss. The flame retardants used are brominated flame retardants and antimony The combination of white, CN102079842A discloses a preparation method of ultra-high flow flame retardant ABS modified resin, which improves the problem of poor fluidity of flame retardant ABS alloy materials due to the addition of flame retardants, and the used flame retardant The flame retardant is still a combination of brominated flame retardants and antimony white
[0004] Although the flame-retardant ABS alloy material prepared by using brominated flame retardants and antimony trioxide can meet the requirements of UL V0 according to the standard, it will release A lot of smoke, and in the course of a fire, 80-90% of the victims are suffocated by the smoke released during the burning process

Method used

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  • Low-smoke flame-retardant acrylonitrile butadiene styrene (ABS) alloy material
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  • Low-smoke flame-retardant acrylonitrile butadiene styrene (ABS) alloy material

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Embodiment Construction

[0026] The present invention will be further described below in conjunction with specific examples, and the listed examples only further illustrate the present invention, and do not thereby limit the present invention.

[0027] A preparation process of a low-smoke flame-retardant ABS alloy material has the following steps:

[0028] (1) Prepare ABS resin, brominated flame retardant, auxiliary flame retardant, toughening agent, anti-dripping agent, antioxidant and lubricant, and add the above materials into the high-speed mixer in order and mix well;

[0029] ABS resin is obtained by mixing AG12A1 by emulsion method and HR9661 by bulk method at a mass ratio of 54:18; the brominated flame retardant is tris(tribromophenyl)triazine with the brand name FR245 of Jiangsu Haohua.

[0030] The antimony-sodium-silicon composite flame retardant in the auxiliary flame retardant is T930 from United Chemical Corporation, the zinc borate is Firebrake ZB from Rio Tinto, the basic aluminum magn...

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Abstract

The invention relates to the technical field of the high polymer material, in particular to a low-smoke flame-retardant acrylonitrile butadiene styrene (ABS) alloy material. The ABS alloy material comprises the following components in percentage by weight: 50-90% of ABS resin, 0.1-30% of brominated flame retardant, 0.1-10% of auxiliary flame retardant, 0.1-20% of toughening agent, 0.01-1% of anti-dripping agent, 0.01-1% of antioxidant and 0.01-1% of lubricating agent. The auxiliary flame retardant in the low-smoke flame-retardant ABS alloy material is antimony sodium silicon composite flame retardant, zinc borate, aluminium magnesium carbonate compound and antimonous oxide or combination of several of the antimony sodium silicon composite flame retardant, the zinc borate, the aluminium magnesium carbonate compound and the antimonous oxide. According to the auxiliary flame retardant, the use amount of antimony white can be lowered, the production cost of the flame-retardant ABS alloy material is lowered, the smoke release rate and the smoke release amount in the material burning process are lowered, and the low-smoke flame-retardant ABS alloy material has the advantages of good flame-retardant effect and obvious social benefit and industrial application value.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a low-smoke flame-retardant ABS alloy material. Background technique [0002] ABS resin is a terpolymer synthesized from acrylonitrile, butadiene, and styrene as monomers. It has high impact strength, high heat resistance, chemical corrosion resistance, low temperature impact resistance, good electrical insulation performance, and excellent dimensional stability. It has excellent characteristics such as small molding shrinkage rate and excellent processing performance. The obtained product has a good appearance gloss and can be subjected to secondary processing such as electroplating and spraying. It is widely used in electronic equipment, automobile industry, household appliances, office equipment, electrical products, Communication equipment and other fields, it is a large amount of engineering plastics with a wide range of uses. [0003] The oxygen index of ABS resi...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08K13/02C08K3/34C08K3/38C08K3/26C08K3/22C08K5/3492C08F279/04
Inventor 崔晓文石明东
Owner JIANGSU AGT TECH DEV
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