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Blend of thermoplastic starch and polypropylene and preparation method thereof

A thermoplastic starch and polypropylene technology, applied in the field of thermoplastic starch and polypropylene blends and their production, can solve the problems of reduced mechanical properties of the system, transfer, poor starch dispersibility, etc., and achieve the effect of excellent mechanical properties

Active Publication Date: 2012-04-11
优势生物材料科技(湖州)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the development of the plastics industry, some of its own problems have gradually emerged: (1) The raw materials are limited, and the resources are becoming more and more scarce
According to research, the world's conventional oil resources can only be used until 2070. The emergence of the "oil crisis" will inevitably lead to a decline in plastic production, and at the same time, the price of plastic will gradually rise, affecting social stability.
(2) Seriously pollute the environment
[0004] Due to the hydrophilicity of starch and the hydrophobicity of general-purpose plastics such as polypropylene and polyethylene, the compatibility between starch and matrix materials is very poor, which easily leads to poor dispersion of starch in the system, and the stress cannot pass through both sides under the action of external force. The effective transfer at the phase interface will eventually lead to a great decrease in the mechanical properties of the system

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] Corn starch: 56kg; isotactic polypropylene: 11kg; glycerin: 16 kg; stearic acid: 2.4 kg; aluminate coupling agent: 0.6 kg; decaglycerol dioleate: 4 kg; talcum powder: 10 kg .

[0047] Add 56kg of cornstarch and 16kg of glycerin into a high-speed mixer, and stir at a high speed for 8-10 minutes at 110-120 degrees Celsius, then seal the mixture and let it stand at room temperature for twelve hours to allow the small molecule plasticizer to penetrate completely into the starch molecules, so that the starch can be better plasticized to form thermoplastic starch; then 11kg isotactic polypropylene, 2.4kg stearic acid, 0.6kg aluminate coupling agent, 4kg decaglycerol dioleic acid Ester, 10kg talcum powder (1200 mesh) and thermoplastic starch are added to high-speed stirring and mixed evenly to form a blend of thermoplastic starch and polypropylene, which can be used to make disposable tableware, plastic bags, etc.

Embodiment 2

[0049] Corn starch: 50kg; isotactic polypropylene: 25kg; glycerin: 12 kg; stearic acid: 2.4 kg; aluminate coupling agent: 0.6 kg; decaglycerol dioleate: 3 kg; talcum powder: 7kg.

[0050] Add 50kg of cornstarch and 12kg of glycerin into a high-speed mixer, and stir at a high speed of 110-120 degrees Celsius for 8-10 minutes, then seal the mixture and let it stand at room temperature for 12 hours to allow the small molecule plasticizer to penetrate completely Into the starch molecules, so that the starch can be better plasticized to form thermoplastic starch; then 25kg isotactic polypropylene, 2.4kg stearic acid, 0.6kg aluminate coupling agent, 3kg decaglycerol dioleic acid Ester, 7kg talcum powder (1200 mesh) and thermoplastic starch are added to high-speed stirring and mixed evenly to form a blend of thermoplastic starch and polypropylene, which can be used to make disposable tableware, plastic bags, etc.

Embodiment 3

[0052]Corn starch: 65kg; isotactic polypropylene: 10kg; glycerin: 12 kg; stearic acid: 2.4 kg; aluminate coupling agent: 0.6 kg; decaglycerol dioleate: 3 kg; talcum powder: 7kg.

[0053] Add 65kg of cornstarch and 12kg of glycerin into a high-speed mixer, and stir at a high speed of 110-120 degrees Celsius for 8-10 minutes, then seal the mixture and let it stand at room temperature for twelve hours to allow the small molecule plasticizer to penetrate completely into the starch molecules, so that the starch can be better plasticized to form thermoplastic starch; then 10kg isotactic polypropylene, 2.4kg stearic acid, 0.6kg aluminate coupling agent, 3kg decaglycerol dioleic acid Ester, 7kg talcum powder (1200 mesh) and thermoplastic starch are added to high-speed stirring and mixed evenly to form a blend of thermoplastic starch and polypropylene, which can be used to make disposable tableware, plastic bags, etc.

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PUM

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Abstract

The invention discloses a blend of thermoplastic starch and polypropylene, comprising the following materials based on parts by weight: 50-65 parts of starch, 10-25 parts of polypropylene, 12-25 parts of glycerol, 1-3 parts of stearic acid, 0.5-2 parts of aluminate coupling agent, 3-5 parts of deca-poly diolein, 7-12 parts of talc powder. A preparation method for the blend of thermoplastic starchand polypropylene, comprising the following steps: a), pouring starch and glycerol, which are weighed according to the percentages, into a high-speed blender, and mixing them at 100-120 degrees centigrade for 8-10 min, and taking the mixture out and standing it for twelve hours to form thermoplastic starch; b), adding the polypropylene, stearic acid, aluminate coupling agent, deca-poly diolein and talc powder, which are weighed according to the percentages, and the thermoplastic starch formed in the step a) into the high-speed blender, and uniformly stirring them to form a blend. The blend ofthermoplastic starch and polypropylene disclosed in the invention has excellent mechanical property.

Description

technical field [0001] The invention relates to the technical field of polymer material modification, in particular to a blend of thermoplastic starch and polypropylene and a preparation method thereof. Background technique [0002] Since the 20th century, the material revolution has played an extremely important role in the profound changes in human society. Especially in the last 50 years, the progress of polymer synthesis technology has greatly promoted the development of synthetic resin industry. Due to the characteristics of light weight, good mechanical properties, water resistance, chemical corrosion resistance, beautiful appearance, convenient manufacturing and installation, and low price, plastic products have rapidly replaced metal, wood, glass and even paper products to a large extent. It is widely used in various sectors of the national economy, promoting the sustainable development of industry and agriculture and the rise of contemporary high technology. Howev...

Claims

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Application Information

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IPC IPC(8): C08L3/02C08L23/12C08K13/02C08K5/053C08K5/09C08K3/34
Inventor 郭永超赵彦生
Owner 优势生物材料科技(湖州)有限公司
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