Self-crosslinking organosilicone heat-resistant coating
A heat-resistant coating, silicone technology, applied in the direction of coating, can solve the problems of poor self-drying performance, low mechanical strength, reduced silicone content, etc., and achieve the effect of good drying performance and excellent physical and chemical properties
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Embodiment 1
[0016] The synthetic process step of modified silicone resin of the present invention is as follows:
[0017] 1) Synthesis of acrylic acid prepolymer: take 13kg of methyl methacrylate, 20kg of styrene, 8kg of butyl acrylate, 3kg of acrylic acid, 1.3kg of benzoyl peroxide, and 45kg of xylene; Add it into the reaction kettle, raise the temperature to reflux temperature (138-140°C), mix the mixture of acrylic acid monomer, methyl methacrylate, styrene, butyl acrylate and benzoyl peroxide for 2 hours (at 2- 2.5 hours) dropwise addition; reflux for 2 hours, then cool down; when the temperature drops to 80°C, discharge the material for later use;
[0018] 2) Synthesis of organosilicon intermediates: Take 15kg of phenyltrichlorosilane, 8kg of dimethyldichlorosilane, 35kg of toluene, 30kg of ethanol, and 12kg of deionized water; mix deionized water with 2 / 3 toluene is added to the hydrolysis kettle, and the mixture of phenyltrichlorosilane, dimethyldichlorosilane and the remaining 1 / ...
Embodiment 2
[0021] Synthesis of modified silicone resin of the present invention:
[0022] 1) Synthesis of acrylic acid prepolymer: Take 15kg of methyl methacrylate, 25kg of styrene, 10kg of butyl acrylate, 5kg of acrylic acid, 1.5kg of benzoyl peroxide, and 50kg of xylene; add xylene In the reaction kettle, heat up to the reflux temperature (138-140°C), and add the mixture of acrylic acid monomer, methyl methacrylate, styrene, butyl acrylate and benzoyl peroxide dropwise in 2.5 hours; reflux Keep warm for 2 hours, then cool down; when the temperature drops to 80°C, discharge the material for later use;
[0023]2) Synthesis of organosilicon intermediates: Take 20kg of phenyltrichlorosilane, 10kg of dimethyldichlorosilane, 40kg of toluene, 35kg of ethanol, and 15kg of deionized water; mix deionized water with Add 2 / 3 toluene into the hydrolysis kettle, drop the mixture of phenyltrichlorosilane, dimethyldichlorosilane and the remaining 1 / 3 toluene from the high position tank, control the f...
Embodiment 3
[0026] Synthesis of modified silicone resin of the present invention:
[0027] 1) Synthesis of acrylic acid prepolymer: Take 12kg of methyl methacrylate, 15kg of styrene, 5kg of butyl acrylate, 1kg of acrylic acid, 1kg of benzoyl peroxide, and 40kg of xylene; add xylene Into the reaction kettle, heat up to the reflux temperature (138-140°C), add the mixture of acrylic acid monomer, methyl methacrylate, styrene, butyl acrylate and benzoyl peroxide dropwise in 2.2 hours; reflux Keep warm for 2 hours, then cool down; when the temperature drops to 80°C, discharge the material for later use;
[0028] 2) Synthesis of organosilicon intermediates: take 10kg of phenyltrichlorosilane, 5kg of dimethyldichlorosilane, 20kg of toluene, 20kg of ethanol, and 5kg of deionized water; mix deionized water with 2 / 3 toluene is added to the hydrolysis kettle, and the mixture of 1-phenyltrichlorosilane, dimethyldichlorosilane and the remaining 1 / 3 toluene is added dropwise from the high position tan...
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